The homogeneous incorporation of heteroatoms into two-dimensional C nanostructures, which leads to an increased chemical reactivity and electrical conductivity as well as enhanced synergistic catalysis as a conductive matrix to disperse and encapsulate active nanocatalysts, is highly attractive and quite challenging. In this study, by using the natural and cheap hydrotropic amino acid proline—which has remarkably high solubility in water and a desirable N content of ~12.2 wt.%—as a C precursor pyrolyzed in the presence of a cubic KCl template, we developed a facile protocol for the large-scale production of N-doped C nanosheets with a hierarchically porous structure in a homogeneous dispersion. With concomitantly encapsulated and evenly spread Fe2O3 nanoparticles surrounded by two protective ultrathin layers of inner Fe3C and outer onion-like C, the resulting N-doped graphitic C nanosheet hybrids (Fe2O3@Fe3C-NGCNs) exhibited a very high Li-storage capacity and excellent rate capability with a reliable and prolonged cycle life. A reversible capacity as high as 857 mAh•g–1 at a current density of 100 mA•g–1 was observed even after 100 cycles. The capacity retention at a current density 10 times higher—1,000 mA•g–1—reached 680 mAh•g–1, which is 79% of that at 100 mA•g–1, indicating that the hybrids are promising as anodes for advanced Li-ion batteries. The results highlight the importance of the heteroatomic dopant modification of the NGCNs host with tailored electronic and crystalline structures for competitive Li-storage features.
The asphalt community seeks a solvent-free method to determine the properties of RAP binder and those of its blends with virgin binders. A promising approach is to test mortars composed of fine fractions of RAP and a virgin binder, and to calculate grade change rate (GCR) to predict blended binder true grade at any binder replacement rate (BRR). However, the existing mortar approach underestimates the effect of RAP on binder grade, particularly at high temperatures. This study identified the use of a shift factor in the existing method as the source of underestimations. An alternative data analysis method was developed, which eliminates the shift factor by using the relationship between binder and mortar properties. Dynamic shear rheometer tests were conducted on a total of 12 mortar combinations, including 4 virgin binders and 3 RAP sources at a BRR of 15%, and then, RAP GCR values were determined by following both the existing and the alternative methods. Satisfactory comparisons were only observed between grades predicted with the alternative method and measured values of manual RAP binder blends: the average difference was lower than 1 °C for BRR of 15 and 30%, and < 4 °C for BRR of 100%. This not only validated the alternative method but also substantiated that RAP GCR is constant, i.e., the grade of RAP blends linearly increased with BRR. Further evaluation of the enhanced mortar approach is recommended at intermediate and low temperatures as well as with blends including recycled asphalt shingles. 相似文献
Laser shock forming (LSF) technology employs shock waves to form sheet metal into three-dimensional complex parts, and has application potential in manufacturing sheet metal parts. In this paper, the forming of 2024 aluminum alloy sheet with LSF was investigated through numerical and experimental methods. The numerical model was established with the commercial code ABAQUS/Explicit. The formed conical cup was obtained from the simulation, and validated by the experiment. With the verified numerical model, the deformation behaviors, including deformation velocity, sheet thickness variation and strain distribution, were studied. In addition, the influence of different shock wave pressures on the forming precision was also investigated. The experimental and numerical results show that the metal sheet loaded by shock wave can take the shape of the mold, and the non-uniform thickness is distributed in the formed cup. The investigations also display that there exists reverse deformation at the central region of deforming sheet owing to severe collision during LSF. In order to obtain formed part with better quality, an appropriate pressure of applied shock waves is required. 相似文献