High-power operation of highly reliable narrow stripe pseudomorphicsingle quantum well lasers emitting at 980 nm

Ridge waveguide pseudomorphic InGaAs/GaAs/AlGaAs single-quantum-well lasers exhibiting record high quantum efficiencies and high output power densities (105 mW per facet from a 6 μm wide stripe) at a lasing wavelength of 980 nm are discussed that were fabricated from a graded index separate confinement heterostructure grown by molecular beam epitaxy. Life testing at an output power of 30 mW per uncoated facet reveals a slow gradual degradation during the initial 500 h of operation after which the operating characteristics of the lasers become stable. The emission wavelength, the high output power, and the fundamental lateral mode operation render these lasers suitable for pumping Er³⁺-doped fiber amplifiers     

Design and evaluation of fundamental-mode and polarization-stabilized VCSELs with a subwavelength surface grating

We demonstrate 850-nm oxide-confined vertical-cavity surface-emitting lasers (VCSELs) with a locally etched subwavelength surface grating that are single-mode and polarization stable from threshold up to thermal roll-over, reaching /spl sim/4 mW of output power. The side-mode suppression ratio (SMSR) is >30 dB and the orthogonal polarization suppression ratio (OPSR) is /spl sim/20 dB. Moreover, no distortion of the far-field beam profile is observed as a result of the surface grating. Our numerical calculations show that a carefully designed VCSEL can have a high simultaneous mode and polarization selectivity without a significant increase in loss for the favored fundamental mode with polarization state perpendicular to the grating lines. This indicates characteristics such as threshold current and resonance frequency will not be notably degraded. The calculations also show a low sensitivity to variations in grating etch depth and duty cycle, which relaxes fabrication tolerances. In our experimental parametric study, where the oxide aperture diameter, surface grating diameter, and grating duty cycle were varied, the combined mode and polarization selection was investigated. For an optimum combination of oxide aperture and surface grating diameters of 4.5 and 2.5 /spl mu/m, respectively, the device is found to be single-mode and polarization stable for a broad range of grating duty cycles, from 55% to 75%, with only a small variation in other laser performances, which is in line with theory.     

Demodulation of space-time codes in the presence of interference

Two interesting space-time coding schemes for communication systems are the recently proposed differential space-time modulation (DSTM) scheme and the differential space-code modulation (DSCM) scheme. DSCM gives better performance than DSTM by exploiting the spatial degree-of-freedom to suppress interference. We show that, for DSCM, a maximum-likelihood (ML) demodulation approach, based on a deterministic channel model, improves the performance significantly compared to a previously proposed stochastic channel model based method     

Über die Säuren HOOCCH(SX)CH(SX)COOH (X  CH2COOH,C6H5) und ihre Methylester

The Acids HOOCCH(SX)CH(SX)COOH (X  CH₂COOH, C₆H₅) and their Methyl Esters The acids HOOCCH(SX)CH(SX)COOH with X  CH₂COOH and C₆H₅ and their methyl esters have been prepared by addition of thiols to acetylene dicarboxylic acid as salt and methyl ester. The structures and configurations have been discussed.     

Synthesis of branched 'nanotrees' by controlled seeding of multiple branching events

The formation of nanostructures with controlled size and morphology has been the focus of intensive research in recent years. Such nanostructures are important in the development of nanoscale devices and in the exploitation of the properties of nanomaterials. Here we show how tree-like nanostructures ('nanotrees') can be formed in a highly controlled way. The process involves the self-assembled growth of semiconductor nanowires via the vapour-liquid-solid growth mode. This bottom-up method uses initial seeding by catalytic nanoparticles to form the trunk, followed by the sequential seeding of branching structures. Each level of branching is controlled in terms of branch length, diameter and number, as well as chemical composition. We show, by high-resolution transmission electron microscopy, that the branching mechanism gives continuous crystalline (monolithic) structures throughout the extended and complex tree-like structures. The controlled seeding method that we report here has potential as a generic means of forming complex branching structures, and may also offer opportunities for applications, such as the mimicking of photosynthesis in nanotrees.     

Two‐scale finite element modelling of reinforced concrete structures: Effective response and subscale fracture development

A two‐scale model is derived from a fully resolved model where the response of concrete, steel reinforcement, and bond between them are considered. The pertinent “effective” large‐scale problem is derived from selective homogenisation in terms of the equilibrium of reinforced concrete considered as a single‐phase solid. Variational formulations of the representative volume element problem are established in terms of the subscale displacement fields for the plain concrete continuum and the reinforcement bars. Dirichlet and Neumann boundary conditions (BCs) are imposed on the concrete (pertaining to uniform boundary displacement and constant boundary traction, respectively) and on the reinforcement bars (pertaining to prescribed boundary displacement and vanishing sectional forces, respectively). Different representative volume element sizes and combinations of BCs were used in FE² analyses of a deep beam subjected to four‐point bending. Results were compared with those of full resolution (single‐scale). The most reliable response was obtained for the case of Dirichlet‐Dirichlet BCs, with a good match between the models in terms of the deformed shape, force‐deflection relation, and average strain. Even though the maximum crack widths were underestimated, the Dirichlet‐Dirichlet combination provided an approximate upper bound on the structural stiffness.     

Single fundamental-mode output power exceeding 6 mW from VCSELs with a shallow surface relief

A single fundamental-mode output power of 6.5 mW was achieved from an 850-nm vertical-cavity surface-emitting laser (VCSEL) with a shallow surface relief, the highest single-mode power ever reported using this technique. The VCSELs were fabricated from epitaxial material grown to yield an antiphase reflection from the topmost layer. A circular surface relief, acting as a mode discriminator, was etched in the center to reduce the mirror loss for the fundamental mode. This "inverted" surface-relief technique offers relaxed etch depth control and, therefore, improves reproducibility and yield.     

Mass flow limitations in reactive sputtering

Reactive sputtering may be accomplished by mixing the inert gas argon with some reactive gas during sputtering. To form ZrN, sputtered zirconium atoms must react with nitrogen. At a specific deposition rate, a certain number F_N0 of nitrogen atoms must arrive at the substrate. This requirement is fulfilled at the partial pressure P_N = P_N0. The minimum partial pressure P_N0 to obtain a nitride is often detected by a sharp decrease in sputtering rate at a specific N₂ partial pressure. However, during reactive sputtering of for example ZrN we found that the value of P_N0 was strongly dependent on the total gas throughout in the vacuum system. An increase in total gas throughput causes a decrease in the value of P_N0.

The decrease in sputtering rate has indirectly been measured by optical emission spectroscopy from the sputtering plasma.     

Space-time finite elements for a simplified thermo-metallurgical problem relevant to casting

The non-linear thermo-metallurgical problem, relevant for the cooling of a molten metal including the macro-segregation that occurs during the cooling process, is studied here. Due to the strong non-linearities involved in phase transformations, it is necessary to use a fine resolution in space-time in a finite element approximation in order to meet accuracy requirements. We derive space-time FE-methods based on the discontinuous and continuous Galerkin method in time for the energy equation. This formulation integrates the stored energy exactly for a given heat flux. When macro-segregation is incorporated into the model, the problem can be formulated in such a way that the phase-transition drives a flow of species. In addition, diffusion is possible throughout the domain. The model can be further rewritten using a potential approach. By this approach for modelling macro-segregation, we are able to obtain discretizations that guarantee that the balance equations are satisfied, and it is possible to solve the phase-transition problem either as a field problem or as a local problem (defined by a local evolution rule).     

Effect of geometry and green density on the anisotropic sintering shrinkage of axisymmetric iron parts

Sintering shrinkage of prior cold compacted iron rings with different geometry (height to wall thickness ratio) and green density in the 6.5–7.3?g/cm³ range was investigated. It displays a minimum at an intermediate green density. Axial, tangential and radial shrinkages are different, due to the gradients of green density along the axial and the radial directions. Therefore, the effect of height on shrinkage and its anisotropy is the result of their effect on the stress distribution in the green parts during cold compaction, and the resulting green density and deformation experienced by the powder. Anisotropy decreases on increasing shrinkage.