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91.
Jatuporn Wittayakun Pongtanawat Khemthong Sanchai Prayoonpokarach 《Korean Journal of Chemical Engineering》2008,25(4):861-864
Rice husk silica (RHS) in amorphous phase with 98% purity was prepared from a waste rice husk from rice milling by leaching
with hydrochloric acid and calcination. The RHS was used effectively as a silica source for the synthesis of zeolite Y in
sodium form (NaY). The zeolite in pure phase was obtained from a two-step synthetic route in which the starting gels were
mixed, aged for 24 h at room temperature and crystallized for 24 h at 90 °C. The diameter of single crystal particles from
a scanning electron microscope was approximately 1.0 μm, whereas the average particle diameter from laser diffraction particle
size analyzer was approximately 10 μm because of the agglomeration of small crystals. Longer crystallization time in this
route resulted in a mixed phase containing NaY and zeolite P in sodium form (NaP). In addition, a one-step synthetic route
(no aging) was studied and the product was also a mixed phase zeolite. 相似文献
92.
A novel method for the fabrication of highly ordered nanopore arrays with very small diameter of 14 nm was demonstrated by
using low-temperature anodization. Two-step anodization was carried out at 25 V, sulfuric acid concentration of 0.3 M, and
electrolyte temperature of −15 °C. After anodization, a regular pore array with mean diameter of 14 nm and interpore distance
of 65 nm was formed. The pore diameter and regular arrangement were confirmed by scanning electron microscopy (SEM) and fast
Fourier transformation (FFT), respectively. The present results strongly suggest that the diameter of pores in a highly ordered
alumina template can be reduced by lowering the anodization temperature. 相似文献
93.
In this work, the kinetics and mechanism of free-radical polymerisation of glycidyl methacrylate (GMA) using potassium peroxydisulphate
(PDS) as water soluble initiator in the presence of synthesized 1, 4-Bis (tributyl methyl ammonium) benzene dichloride (TBMABDC)
as multi-site phase transfer catalyst (MPTC) was studied. The polymerisation reactions were carried out under inert and unstirred
conditions at constant temperature of 60 ± 1°C in cyclohexane/water biphase media. The role of concentrations of monomer,
initiator, catalyst and volume fraction of aqueous phase, solvent polarity and temperature on the rate of polymerisation (Rp)
was ascertained. The order with respect to monomer and initiator was found to be unity. The order with respect to catalyst
was found to be 0.51. The rate of polymerisation is independent of ionic strength and pH of the medium. However, an increase
in the polarity of solvent has slightly increased the Rp value. Based on the results obtained, a suitable kinetic scheme has
been proposed to account for the experimental observations and its significance discussed. 相似文献
94.
储层压力与天然气分布关系——以鄂北塔巴庙地区上古生界储层为例 总被引:2,自引:0,他引:2
通过分析塔巴庙地区储层压力的分布特征,建立了研究区泥岩压实曲线,并对影响和控制该区储层压力的主要因素和机理进行了探讨,对“欠压实”剩余压力、生气增压、抬升引起的降压进行了定量计算。分析结果表明,晚三叠-早白垩世末“欠压实”作用和晚侏罗-早白垩世末烃源岩大量生烃作用使塔巴庙地区上古生界形成异常高压;晚白垩系构造抬升降压,使得现今储层为正常-低异常压力。同时证实了“欠压实”对天然气有压力封盖作用,天然气都分布在最大“欠压实”幅度以下的储层当中。烃源岩生气高峰为晚侏罗-早白垩世末,但天然气大规模运移是在晚白垩世,方向以沿过剩压力梯度降低较快的方向(太原-山西组至下石盒子组)垂向运移,通道主要为裂缝,运移的动力主要为异常高压。由于储层致密,聚集成藏能量有限,造成天然气充注不足、气水分异不好、含气饱和度低。 相似文献
95.
The effect of pressure on combustion and heat transfer is analyzed. The research is based on the basic combustion and heat
transfer theorem. A correction for the heat calculation method for pressurized furnace is made on the basis of the normal
pressure case. The correction takes the effect of pressurizing into account. The results show that the correction is reasonable
and the method is applicable to combustion and heat transfer of the marine supercharged boiler. 相似文献
96.
Florian Matthes 《Informatik-Spektrum》2008,31(6):527-536
Zusammenfassung Anwendungslandschaften in Unternehmen sind langlebige hoch-komplexe Strukturen bestehend aus hunderten bis tausenden von miteinander
vernetzten betrieblichen Informationssystemen, die von Personen mit sehr unterschiedlichen Interessen und Erfahrungshintergrund
konzipiert, erstellt, modifiziert, betrieben, genutzt und finanziert werden. Die Softwarekartographie zielt darauf ab, die
Kommunikation zwischen diesen Personen durch zielgruppenspezifische verst?ndliche graphische Visualisierungen zu unterstützen,
die Gesch?fts- und Informatik-Aspekte gleicherma?en berücksichtigen, und die speziell für langfristige und strategische Management-Betrachtungen
geeignet sind.
In diesem Beitrag fassen wir zun?chst die in der betrieblichen Praxis wohlbekannten Probleme beim Management von Anwendungslandschaften
zusammen und diagnostizieren erhebliche Kommunikationsdefizite. Da Anwendungslandschaften als Systeme von Systemen mit Menschen
als integrale Systembestandteile zu verstehen sind, werden Karten als attraktiver L?sungsansatz identifiziert und die wesentlichen
Konzepte der Softwarekartographie anhand von Beispielen vorgestellt. Dabei werden Querbezüge zu anderen Fachgebieten der Informatik
und Wirtschaftsinformatik hergestellt, und die bisherige Nutzung der Forschungsergebnisse in der Praxis gezeigt. 相似文献
97.
Dong Zhang 《Korean Journal of Chemical Engineering》2008,25(5):1205-1207
Ceria-zirconia solid particles have been recognized as a key material of the automotive exhaust catalysts since they can release
and uptake oxygen owing to the rapid reversible oxidation states of cerium between Ce3+ and Ce4+. Several methods have recently been described to prepare the CeO2-ZrO2 solid particles used in the catalysts. In this paper, a new coprecipitation method is used to prepare the CeO2-ZrO2 solid particles. The Ce-Zr alcogel is dried and calcined in flowing N2 not in flowing air under atmospheric pressure. The results show that the ceria-zirconia sample calcined at 650 °C has high
surface area over 90 m2g−1, which drops to 40 m2g−1 following treatment at 900°C. 相似文献
98.
Phenylbutazone was recrystallized from its solutions by using a supercritical fluid antisolvent process. It was dissolved
in acetone and supercritical carbon dioxide was injected into the solution, thereby inducing supersaturation and particle
formation. Variation in the physical properties of the recrystallized phenylbutazone was investigated as a function of the
crystallizing temperature and the carbon dioxide injection rate. The recrystallized particles showed cleaner surfaces and
more ordered morphology compared to the particles obtained by other methods such as solvent evaporation. X-ray diffraction
patterns indicated that the crystallinity of the particles had been modified upon the recrystallization. Differential scanning
calorimetry measurement revealed that the crystallizing temperature influenced the thermal stability of the resulting crystals.
Larger crystals were produced when the carbon dioxide injection rate was reduced. 相似文献
99.
100.
The catalysts of CeO2 and the mixture of CeO2 and CuO were prepared, and the activities of these catalysts for completely oxidizing benzene were studied.The results show that the optimal proportion of CeO2/CuO is 6: 4.The highest temperature at which benzene was completely oxidized on these catalysts at different airspeed was measured.Compared these catalysts with the noble metal used, our catalysts had superiority in the resources and the industrial cost besides good activities. 相似文献