Effect of additives on formation of natural gas hydrate

The formation of natural gas hydrate (NGH) is studied in this work. Kinetics data of hydrate formation with no agitation were collected at various concentrations of the aqueous solutions with different additives such as alkylpolyglucside, sodium dodecyl benzene sulfonate and potassium oxalate monohydrate. Various kinds of additive increased the formation rates of NGH and its storage capacity and reduced the induction time of NGH formation. Moreover, the storage capacity, the induction time and the hydrate formation rate were influenced by the concentration of the aqueous solution.     

常压合成防老剂4020的工业生产工艺

以小试和中试条件为依据，研究了防老荆4020[N-(1，3-二甲基丁基)-N′-苯基对苯二胺]的工业生产新工艺。以对氨基苯酚、甲基异丁基酮、甲酸和苯胺为原料，用三步法在常压下合成了防老荆4020。优化的工艺是用3台反应釜并联，差时1／3个生产周期分别开工，用1台同客积的蒸馏釜与之配套，并在4台釜中都装有冷却蛇管。该工艺设备投资低，生产用时短，产物收率达90.1％。     

用纯氧化铕模拟基体AES法测定氧化铥中的钬、饵、镱、镥和钇

用于发射光谱分析的氧化铥基体不但难于寻找,而且价格昂贵.本文用氧化铕模拟氧化标基体的办法,其测定结果与别的方法基本符合.为寻找代替氧化铥基体提供了一条途径.     

青岗钾肥厂试车小结

为满足农业生产上对硫酸钾的需求，化工部上海化工研究院复肥所着重开发了硫铵转化法的生产工艺，并在推广过程中，针对操作工艺和设备上所存在的问题，继续探索，取得了新的结果。该技术已用于青岗钾肥厂万吨级硫酸钾生产装置。本文着重介绍了该装置在试车过程中所发生的问题及处理方法。     

Rheology and Consolidation of Colloidal Alumina-Coated Silicon Nitride Suspensions

In an attempt to improve the colloidal processing of Si₃N₄ ceramics, we studied the rheology and consolidation of colloidal suspensions of Si₃N₄ particles (average particle size 0.7 μm) with small Al₂O₃ particles (average particle size 20 nm). It was found that at pH >7, the viscosity of the mixtures increased and then decreased with an increasing concentration of Al₂O₃. λpotential measurements, optical micrographs, and visible light absorptance measurement suggest that such viscosity behavior is due to clustering of Si₃N₄ particles bridged by the small Al₂O₃ particles. This is also supported by the Derjaquin-Landau-Verwey-Overbeek (DLVO) potential calculations that show the barrier height in the DLVO potential between Al₂O₃ and Si₃N₄ is small. The small barrier height under current experimental conditions stems from the small size of the Al₂O₃ particles. The small barrier height allows the thermal motion of the two kinds of particles to overcome the barrier and attach to each other. The adsorption of small Al₂O₃ particles on Si₃N₄ can occur even when both Al₂O₃ and Si₃N₄ carry the same sign of charges. The adsorption of Al₂O₃ on Si₃N₄ also increases the density of consolidated compacts.     

Surface modification of a biomedical poly(ester)urethane by several low‐powered gas plasmas

Several low‐powered gas plasmas were employed to treat a biomedical poly(ester)urethane using the treatment gases of CO₂, O₂, NH₃, and SO₂ with different treatment time (2, 5, 10, and 15 min). The changes of the physical and chemical characteristics of the biopolymer surface were studied. Surface morphology was evaluated by scanning probe microscopy, which showed increased roughness of the surface after plasma treatment. The wettability of the surface was examined by static water contact angle (SCA) measurements, which presented that there was a decrease of SCA in all plasma treatments compared with the untreated surface and that each gas plasma had an optimum treatment time accompanied by a minimum contact angle. X‐ray photoelectron spectroscopy indicated the changes of the surface functional groups. The data demonstrated that CO₂ and O₂ plasmas resulted in the incorporation of oxygen‐containing groups, while NH₃ plasma resulted in the combination of nitrogen‐containing groups, and SO₂ plasma resulted in the formation of sulfur‐containing groups. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 1273–1282, 2006     

用弯曲模型推导二组元复合材料杨氏模量新公式

用弯曲模型推导了适用于悬丝耦合弯曲共振法检测金属第二组元的杨氏模量的理论公式。通过实验数据计算。结果表明在两组元h2/h1≈1时与文献[2]的计算结果几乎接近，为用悬丝耦合弯曲共振法检测各种减振材料，陶瓷材料杨氏模量提供了理论公式；同时用改进后的弯曲模型推导出了适用于纤维复合材料横向杨氏模量的预测公式。     

PH敏感性水凝胶的分子热力学模型

本工作是在非离子凝胶的分子热力学模型基础，引入Ｄｏｎｎａｎ平衡项和大分子离子链的静电排斥项对凝胶自由能的贡献，建立了一个新的离子凝胶的分子热力学模型。该模型在解释离子凝胶的ＰＨ敏感性及其各种影响因素，以及预测ＰＨ溶胀曲线方面都取得了较好的效果。     

国外过氧化氢在化学合成中应用研究进展

介绍了近期国外过氧化氢在部分化学品合成中应用研究新进展 ,产品包括过碳酸钠、过碳酰胺、4Na2 SO4·2H2 O2 ·NaCl加合物、叔胺氧化物、水合肼、二羟基苯、季铵盐过氧化氢和甲乙酮肟。内容涉及产品质量 (纯度、安定性、溶解速率、外观等 )、产品收率、催化剂、工艺过程等方面改进。主要介绍专利技术。     

玻纤增强PA66／PP合金的特性及应用

介绍玻纤增强ＰＡ６６／ＰＰ合金的制备工艺及特性，与纯尼龙６６树脂相比，加工性能好，综合性能优异。该材料适用于中小型油浸式变压器的分接开关及其它绝缘部件。