Hydrogenation of phenylacetylene and 3-phenylpropyne using Rh(diene) complexes under homogeneous and heterogeneous conditions

Hydrogenation of phenylacetylene (PA) and 3-phenylpropyne (PP) was carried out using [Rh(diene)Cl]₂ complexes (diene is hexadiene (HD), cycloocta-1,5-diene (COD), norborna-2,5-diene (NBD)) in their immobilized forms and compared with hydrogenation in homogeneous arrangement. Immobilization brings significant increase of the catalytic activity and product selectivity in the step-wise hydrogenation to corresponding vinyl-resp. allyl-benzenes. Diene-ligand effect was apparent in PA hydrogenation; the product selectivity decreased in order Rh(HD) > Rh(NBD) > Rh(COD) and catalytic activity decreased in order Rh(HD) > Rh(COD) > Rh(NBD).     

Gas‐Liquid Mass Transfer Rates and Impeller Power Consumptions for Industrial Vessel Design

Volumetric mass transfer coefficients (k_La) and power input (P) are often the key parameters in the design of gas‐liquid contactors. However, due to the limitations of most measurement methods, there is a lack of reliable data for predicting k_La for non‐coalescent batches under high energy dissipation rates. Accurate k_La and P correlations are proposed. The reliability of the correlations is ensured by using experimental data from a wide range of process conditions conducted in multiple‐impeller vessels of both laboratory scale and pilot scale, and including both non‐coalescent and coalescent batches. Applying the proposed correlations, the scale‐up and optimization of industrial vessels can be performed more accurately.     

Eco-Friendly Natural Clay: Montmorillonite Modified with Nickel or Ruthenium as an Effective Catalyst in Gamma-Valerolactone Synthesis

Catalysis Letters - Ni/Ru metals supported on cheap and available support montmorillonite K10 were used for the selective hydrogenation of levulinic acid to γ-valerolactone. Different loadings...     

Influence of storing time and temperature on the viscosity of an egg yolk

The influence of storing time and temperature on rheological behavior of egg yolk was investigated. The eggs of two brown egg-laying breeds (Bar Plymouth Rock and Rhode Island Red) were stored for 1, 2, 3, 4, and 8 weeks at constant temperatures: 4 °C, 8 °C, 12 °C, and 16 °C. The apparent viscosity was measured by a rotational viscometer as a function of shear rate. It was found that yolk samples exhibited shear-thinning (pseudoplastic) behavior. The shear-thinning behavior was fitted well into Herschel–Bulkley model (with a satisfying correlation of R² > 0.95). For the selected shearing rate, viscosity was measured in relation to shearing time. The time-dependant viscosity decreased rapidly with time and, at lower share rates, reached an equilibrium state. The time-dependant viscosity was also found to decrease with storage time. The value of pH changed (increased) during storing. No clear dependence between pH value and viscosity was confirmed.     

Hopkinson Tensile Tests of Flat Specimens

The SHTBT （split Hopkinson tensile bar test） is used for the determination of mechanical material properties at high strain rates, in this case within 10^2-10^3 s^-1. The duration of impact loading is within the range of 40-100 μS. The principle of SHTBT is based on the measurement and evaluation of impact loading that is common in high strain rate processes. Strain gauges are usually used to record impact loading. In this case, cylindrical capacitance detectors were used. Plastic deformation of metallic materials and alloys is a complex process that depends on a number of factors with the effect of strain rate being of particular importance. Dynamical tests are used for determination of mechanical properties; therefore, SHTBT is often used for these experiments. The present paper deals with possibilities of testing device for flat bars adapted at Hopkinson test. The aim of this work is concentrated on strain rate influence on 1.4301 austenitic steel, too.     

Improvement of abrasive water jet machining accuracy for titanium and TiNb alloy

The International Journal of Advanced Manufacturing Technology - The paper is dealing with abrasive water jet (AWJ) cutting of titanium and titanium–niobium alloy. It contains comparison of...     

Case study on distributed and fault tolerant system modeling based on timed automata

This article presents the modeling of a distributed fault-tolerant real-time application by timed automata. The application under consideration consists of several processors communicating via a Controller Area Network (CAN); each processor executes an application that consists of fault-tolerant tasks running on top of an operating system (e.g. OSEK/VDX compliant) and using inter-task synchronization primitives. For such a system, a model checking tool (e.g. UPPAAL) can be used to verify the complex time and logical properties formalized as safety or bounded liveness properties (e.g. end-to-end response time considering an occurrence of a fault). The proposed model reduces the size of the state-space by sharing clocks measuring the execution time of the tasks.     

Dihedral Angle Mesh Error: a fast perception correlated distortion measure for fixed connectivity triangle meshes

In computer graphics, triangle meshes are ubiquitous as a representation of surface models. Processing of this kind of data, such as compression or watermarking, often involves an unwanted distortion of the surface geometry. Advanced processing algorithms are continuously being proposed, aiming at improving performance (compression ratio, watermark robustness and capacity), while minimizing the introduced distortion. In most cases, the final resulting mesh is intended to be viewed by a human observer, and it is therefore necessary to minimise the amount of distortion perceived by the human visual system. However, only recently there have been studies published on subjective experiments in this field, showing that previously used objective error measures exhibit rather poor correlation with the results of subjective experiments. In this paper, we present results of our own large subjective testing aimed at human perception of triangle mesh distortion. We provide an independent confirmation of the previous result by Lavoué et al. that most current metrics perform poorly, with the exception of the MSDM/MSDM2 metrics. We propose a novel metric based on measuring the distortion of dihedral angles, which provides even higher correlation with the results of our experiments and experiments performed by other researchers. Our metric is about two orders of magnitude faster than MSDM/MSDM2, which makes it much more suitable for usage in iterative optimisation algorithms.