Effect of barium oxide on the formation and coexistence of tricalcium silicate and calcium sulphoaluminate

Formation and coexistence of tricalcium silicate (C₃S) and calcium sulphoaluminate (C₄A₃ ) minerals in Portland cement clinker containing calcium sulphoaluminate were investigated. The f-CaO content, mineral composite and formation of mineral in the clinker were analyzed respectively by chemical analysis, differential scanning calorimetry(DSC) and X-ray diffraction. The results show that, adding a suitable amount of BaO can improve the burnability of raw meal and promote the f-CaO absorption. Tricalcium silicate and calcium sulphoaluminate minerals can form and coexist in clinkers at 1 234–1 317 °C by the addition of BaO to the raw meal. A suitable amount of BaO expanded the coexistence temperature of two minerals by 58 °. Funded by the National Basic Research Program of China (No. 2009CB623100), National Eleven Five-Year Scientific and Technical Support Plans (No. 2006BAF02A24), the Natural Science Fund for Colleges and Universities in Jiangsu Province(No. 08KJB430006), the Open Fund for the Key Laboratory of Inorganical and Composite Materials in Jiangsu Province(No. wjjqfhxc1200801) and the Innovation Fund of Doctoral Dissertation of Nanjing University of Technology (No. BSCX200705)     

Strength of limestone-based non-calcined cement and its properties

A new type of cement was prepared with ground limestone powder, blastfurnace slag, steel slag and gypsum without calcination. The fraction of ground limestone powder in the cement was as high as 40 wt%–60 wt% without Portland clinker. All of its physical properties can meet the requirements of masonry cement standards. The impact of limestone content on physical properties of the cement and determined its impact on law was investigated. The steel slag can excit the aquation activity of this cement effectively, and the influence of its quantity on the strength of the materials was studied, which shows that the optimum quantity of mixing is 10%. By way of changing the different content of the lime stone by quartzy sample, the law of the compression strength and the PH value was determined, confirming that the lime stone can promote the early aquation of the slag and improve the early strength. The main hydration product of this cement is calcium aluminate hydrate, ettringite and calcium silicate hydrate, as indicated by XRD and SEM analysis.     

基坑加固扰动引起地铁隧道隆起变形

针对如何控制上方基坑底部加固扰动引起下卧地铁隧道的变形、确保地铁安全运营的问题.结合上海市浦东新区东方路-张扬路地下立交工程,在考虑隧道等效刚度、施工卸荷以及加固抑制回弹的效果等因素的基础上,对上方搅拌桩施工扰动引起正在运营地铁隧道的竖向隆起变形进行了机理分析,推导出基于Winkler模型计算隧道竖向位移的方法并进行了理论计算.结果表明:上层加固扰动引起隧道的竖向位移是非常可观的,需引起足够重视.并将计算结果和实测数据进行了对比.在此研究基础上提出了一系列控制上层搅拌桩施工引起运营地铁隧道位移的施工方法.     

桩海 10潜山油藏小波多尺度边缘检测技术研究

由于裂缝具有多尺度的特点,不同级别的裂缝对地震传播速度和波的振幅、频率所产生的影响不同,利用潜山储层裂缝检测与图像分析中的边缘检测具有许多相似之处的特点,根据Canny边缘检测定义,对三维地震数据的层切片f(x,y)进行多尺度边缘检测,等价于寻找小波变换模的局部极值,利用这些模局部最大值点就可以确定f(x,y)的剧烈变化点或边缘点.将小波多尺度边缘检测理论与地震波场对裂缝的多尺度特性相结合,形成了反映地震记录的多尺度边缘检测方法.桩海10潜山应用效果表明,小波多尺度边缘检测方法储层预测结果与钻井资料吻合较好,是解决潜山油藏储层预测的一种有效手段,对潜山油藏的勘探开发有一定指导意义.     

非均相催化湿式氧化活性红2BF的研究

以Fe/AC为催化剂、O2为氧化剂的非均相催化氧化体系处理偶氮染料活性红2BF,考察了反应温度、氧分压、废水pH、催化剂投加量等因素对降解效果的影响。结果表明,染料初始质量浓度为400 mg/L时,在温度150℃、氧分压0.5 MPa、pH=3、反应时间60 min、催化剂投加量为4 g/L的最佳条件下,活性红2BF色度几乎完全去除,TOC去除率达94.21%。     

Effect of SiO2 addition on the dielectric properties and microstructure of BaTiO3-based ceramics in reducing sintering

The effect of SiO2 doping on the sintering behavior,microstructure,and dielectric properties of BaTiO3-based ceramics has been investigated.Silica was added to the BaTiO3-based powder prepared by the solid state method with 0.075mo1%,0.15mo1%,and 0.3mo1%,respectively.The SiO2-doped BaTiO3-based ceramic with high density and uniform grain size were obtained,which were sintered in reducing atmosphere.A scanning electron microscope,X-ray diffraction,and LCR meter were used to determine the microstructure as well as the dielectric properties.SiO2 can form a liquid phase belonging to the ternary system of BaO-TiO2-SiO2,leading to the formation of BaTiO3 ceramics with high density at a lower sintering temperature.The SiO2-doped BaTiO3-based ce-ramics can be sintered to a theoretical density higher than 95% at 1220℃ with a soaking time of 2 h.The dielectric constants of the sample with 0.15mo1% SiO2 addition sintered at 1220℃ is about 9000.Doping with a small amount of silica can improve the sinter-ing and dielectric properties of BaTiO3-based ceramics.     

An improvement to the simulation of phase-change heat-transfer during soil freezing and thawing

A new variable time step method, which is called the backwards calculating time step method, is presented in this paper. It allows numerical simulation of soil freezing and thawing while avoiding "phase change missing and overflowing". A sensitive heat capacity model is introduced through which the calculation errors are analyzed. Then the equation using the self-adjusted time step is presented and solved using finite differences. Through this equation, the time needed for a space cell to reach the phase change point temperature is calculated. Using this time allows the time step to be adjusted so that errors caused by "phase change missing and overflowing" are successfully eliminated. Above all, the obvious features of this method are an accelerated rate for adjusting the time step and simplifing the computations. An actual example proves that this method can accurately calculate the temperature fields during soil freezing and thawing. It is an improvement over traditional methods and can be widely used on com- plicated multi-dimensional phase change problems.     

朴素贝叶斯与全贝叶斯在DFI的应用比较研究

P2P应用软件检测技术主要是深度包检测法和深度流量检测法.深度包检测法不能检测出加密的和未知的对等网络流应用,深度流量检测方法可以克服深度包检测法这个缺点.将模糊识别领域里比较成熟的贝叶斯分类技术应用到对等网络深度流检测中.结合实际项目,对贝叶斯的两个分类器-朴素贝叶斯和全贝叶斯的算法、训练结果、运行结果进行研究,实验研究表明朴素贝叶斯和全贝叶斯分类器能够快速准确地找到P2P流应用,朴素贝叶斯分类器准确度占据优势,全贝叶斯运行时间占据优势.     

数理统计方法在安全管理中的研究与应用

以某钢铁集团机械制造有限责任公司的安全管理为例,用数理统计的方法对该公司的工伤事故进行整理、调查、归纳、统计、分析,并针对具有典型代表的事故作出相应的安全教育整改措施,使整个机制公司的安全事故大幅下降,从而使公司的效益上升.     

高校自动排考系统设计与实现

针对目前高校考务管理的现状,分析了自动排考系统所面临的必要和优化问题.以图论为理论依据,设计了一种能够高效解决这些问题的自动排考算法,并将该算法实现,得到了较好的效果.