Patterned growth of carbon nanotubes over vertically aligned silicon nanowire bundles for achieving uniform field emission

A fabrication strategy is proposed to enable precise coverage of as-grown carbon nanotube (CNT) mats atop vertically aligned silicon nanowire (VA-SiNW) bundles in order to realize a uniform bundle array of CNT-SiNW heterojunctions over a large sample area. No obvious electrical degradation of as-fabricated SiNWs is observed according to the measured current-voltage characteristic of a two-terminal single-nanowire device. Bundle arrangement of CNT-SiNW heterojunctions is optimized to relax the electrostatic screening effect and to maximize the field enhancement factor. As a result, superior field emission performance and relatively stable emission current over 12 h is obtained. A bright and uniform fluorescent radiation is observed from CNT-SiNW-based field emitters regardless of its bundle periodicity, verifying the existence of high-density and efficient field emitters on the proposed CNT-SiNW bundle arrays.     

Enhanced microwave absorption of La0.7Sr0.3MnO3−δ based composites with added carbon black

Composites consisting of carbon black (CB) particles, La_0.7Sr_0.3MnO_3−δ (LSMO) powder, and epoxy resin were prepared for development of a high performance microwave absorber. This study investigated the influence of adding amounts of LSMO powder (60, 70, and 80 wt%) on complex permittivity, complex permeability, and reflection loss for CB (5 wt%)-epoxy composites. The variation of complex permittivity and complex permeability with frequency of the composites was measured by the cavity perturbation technique in the range of 7–14 GHz. It was found that the real part of the complex permittivity increased with increasing LSMO addition and the imaginary part of the complex permeability decreased with increasing frequency. The microwave absorption results indicated that the composite filled with 5 wt% CB particles and 80 wt% LSMO powder had the best absorption performance. The maximum reflection loss was −23.63 dB at 7.87 GHz and the absorbing bandwidth at −10 dB was 1.75 GHz with a matching thickness of 5 mm.     

A study on the characteristics and pervaporation performance of polyamide thin‐film composite membranes with modified polyacrylonitrile as substrate for bioethanol dehydration

To improve the pervaporation performance in separating an aqueous ethanol solution, polyamide thin‐film composite (TFC) membranes (m‐tolidine‐H‐TMC/mPAN) were prepared through the interfacial polymerization reaction between trimesoyl chloride (TMC) and 2,2'‐dimethylbenzidine hydrochloride (m‐tolidine‐H) on the surface of a modified polyacrylonitrile (mPAN) membrane. The effects of the feed ethanol concentration on the pervaporation performance and the durability of m‐tolidine‐H‐TMC/mPAN TFC membranes were investigated. To choose the optimal mPAN membrane as the TFC substrate, the effect of hydrolysis time on the chemical properties and separation performance of an mPAN substrate was also studied. An appropriate hydrolysis time of 15 min was chosen to obtain the mPAN substrate due to the corresponding high permeation flux. The m‐tolidine‐H‐TMC/mPAN TFC membrane exhibited a high pervaporation performance for ethanol dehydration. A positron annihilation lifetime spectroscopy experiment was used to estimate the mean free‐volume radius of the m‐tolidine‐H‐TMC polyamide selective layer, which lay between the radii of the water and ethanol molecules. © 2013 Society of Chemical Industry     

抗磨耐腐蚀化工流程泵叶轮制造工艺研究

针对在磨损、腐蚀作业条件使用的离心式化工流程泵叶轮使用寿命短的现状,讨论了抗磨耐腐蚀叶轮材料的选用及其熔炼工艺;研究了Cr20Mo2Cu1高铬铸铁材料制造化工流程泵叶轮的铸造工艺、热处理工艺以及机械加工工艺。     

An investigation into superficial embedment in mirror-like machining using abrasive jet polishing

This study performs experimental investigation into the application of abrasive jet polishing (AJP) to the surface finishing of electrical-discharge-machined SKD61 mold steel workpieces. The results indicate that the AJP processing conditions which optimize the surface quality of the SKD61 workpiece when polishing using #2000SiC abrasives are as follows: an abrasive material to additive ratio of 1:2, an impact angle of 30°, a gas pressure of 4 kg/cm² (0.4 MPa), a nozzle-to-workpiece height of 10 mm, a platform rotational velocity of 200 rpm, and a platform travel speed of 150 mm/s. Under these processing conditions, a polishing time of 20 min is sufficient to reduce the surface roughness from an initial value of Ra?=?1.7 μm to a final value of Ra?=?0.27 μm, corresponding to an improvement of 84.12%. The experimental results demonstrate that the maximum attainable improvement in the surface quality of the polished workpiece is limited by a surface-hardening effect caused by the ball-impact phenomenon and the embedment of #2000SiC fragments in the workpiece surface.     

Ultrasonic vibration-assisted optical glass hot embossing process

A homemade apparatus was used to apply ultrasonic-vibration to assist the glass hot embossing processes. To operate at high temperatures for glass hot embossing, the ultrasonic vibration system was appropriately designed with an embedded cooling system, and an ultrasonic horn was specifically modified for high-temperature use. Molds with both V-groove and Fresnel structures were manufactured for hot embossing experiments on PSK-100 glass. The heights of the molded structures were increased significantly with the assistance of ultrasonic vibration. This technology demonstrates the capability to upgrade the performance of the glass hot embossing process.     

Temperature dependence dynamical permeability characterization of magnetic thin film using near-field microwave microscopy

A temperature dependence characterization system of microwave permeability of magnetic thin film up to 5 GHz in the temperature range from room temperature up to 423 K is designed and fabricated as a prototype measurement fixture. It is based on the near field microwave microscopy technique (NFMM). The scaling coefficient of the fixture can be determined by (i) calibrating the NFMM with a standard sample whose permeability is known; (ii) by calibrating the NFMM with an established dynamic permeability measurement technique such as shorted microstrip transmission line perturbation method; (iii) adjusting the real part of the complex permeability at low frequency to fit the value of initial permeability. The algorithms for calculating the complex permeability of magnetic thin films are analyzed. A 100 nm thick FeTaN thin film deposited on Si substrate by sputtering method is characterized using the fixture. The room temperature permeability results of the FeTaN film agree well with results obtained from the established short-circuited microstrip perturbation method. Temperature dependence permeability results fit well with the Landau-Lifshitz-Gilbert equation. The temperature dependence of the static magnetic anisotropy H(K)(sta), the dynamic magnetic anisotropy H(K)(dyn), the rotational anisotropy H(rot), together with the effective damping coefficient α(eff), ferromagnetic resonance f(FMR), and frequency linewidth Δf of the thin film are investigated. These temperature dependent magnetic properties of the magnetic thin film are important to the high frequency applications of magnetic devices at high temperatures.     

Effect of Ag‐promotion on Pd catalysts by XANES

Pd L₃ near‐edge absorption measurements (XANES) were performed on four commercial acetylene hydrogenation catalyst samples, with and without the Ag promoter. The Pd L₃ edge XANES spectra showed that the Ag‐promoted catalysts have relatively weaker absorption peaks and they follow the same order as the relative commercial performances of the four catalysts studied in terms of selectivity in ethylene purification, which indicates that there are increases in the Pd d‐band electron densities due to the addition of Ag. These results provide a reasonable explanation for the observed improvement in selectivity of the Ag‐promoted acetylene hydrogenation catalysts. The Ag L₃ XANES spectra of the supported Pd–Ag catalysts indicate the absence of a white‐line feature which seems to suggest that the charge transferred from Ag to Pd may not be the d‐type. This revised version was published online in July 2006 with corrections to the Cover Date.     

Formation and crosslinking of latex films through the reaction of acetoacetoxy groups with diamines under ambient conditions

We investigated the processes of film formation, polymer diffusion, and crosslinking of latex films at ambient temperature, using low T_g methacrylate latex bearing acetoacetoxy groups, and curing the systems with 1,6-hexanediamine as the crosslinker. The addition of diamine induces floc formation, which modifies the rheological properties of the dispersion and increases its drying rate when coated onto a substrate. The crosslinking reaction between diamine and acetoacetoxy groups occurs at a rapid rate, even in the dispersed state. Although the crosslinking reaction precedes polymer diffusion in the two systems we examined, latex films with relatively good solvent resistance are obtained. Department of Chemistry, Toronto, Ontario, Canada M5S 3H6. Department of Polymer Chemistry, P. O. Box 513, 5600 MB Eindhoven, The Netherlands.     

Degree reduction of NURBS curves

Higher degree curves are used in applications because they are easier to manipulate interactively but require heavy computation. Most of the equations for curves used popularly in CAD software are of degree 2 and 3, because two curves of degree 3 can guarantee 2nd derivative continuity at the connection point. This study proposes a different but simpler method than any put forward before to deal with degree reduction of free-form curves. The reduced curves use the simplest knot vector type, i.e., the open uniform knot vector. Unlike other methods, this study does not modify or refine the knot vectors but perturb the control points globally. After obtaining an initial condition, a radiating web-like search algorithm is applied to detect the optimum positions. These NURBS curve formats reach basic industrial standards for CAD/CAM/CNC applications. By defining a global bound error function, this algorithm can achieve an optimum solution not only for NURBS curves but also Bézier/B-spline curves.