An NMR study of the dissociation of N,N′-(2-propyloximino)-4,4′-methylenebis(phenylcarbamate) and its crosslinking of polymers containing labile hydrogens. II

Nuclear magnetic resonance spectroscopy has been used to study the dissociation and reaction of N,N′-(2-propyloximino)-4,4′-methylenebis(phenylcarbamate), as a crosslinking agent for polymers containing labile hydrogens. The crosslinking of poly(acrylic acid), polyacrylamide, and poly(vinyl alcohol) was found to result upon heating each to 150°C for 10 min with this component at 2–10 wt %.     

Highly moisture-proof polysilsesquioxane coating prepared via facile sol-gel process

A highly moisture-proof polysilsesquioxane coating was obtained from a new bis-silylated precursor, which was synthesized from 3-aminopropyltriethoxysilane (APTES) and m-xylylene diisocyanate (m-XDI) in tetrahydrofuran (THF) and verified by ¹H MAS NMR. For direct comparison purposes, an SiO₂ coating was also prepared by the Stöber method using tetraethoxysilane (TEOS) as the reactant. Interestingly, the coating obtained from the polysilsesquioxane sol exhibited a much higher moisture resistance capability than its counterpart, which was attributed to its more compact feature between nanoparticles as characterized by N₂ absorption experiment and transmission electron microscopy (TEM). Furthermore, its high transparency of about 92% showed potential for application in the protection of optical crystals.     

Microstructure and Properties of Co2+: ZnAl2O4/SiO2 Nanocomposite Glasses Prepared by Sol–Gel Method

Transparent bulk Co²⁺: ZnAl₂O₄/SiO₂ nanocomposites containing nanocrystalline Co²⁺: ZnAl₂O₄ dispersed in silica glass matrix were obtained by the sol–gel method. The gels of composition 89SiO₂–6Al₂O₃–5ZnO− x CoO ( x =0.2, 0.4, 0.6, 0.8, 1.0) (mol%) were prepared at room temperature by using two different aluminum salts, aluminum nitrate and aluminum alkoxide (aluminum-iso-propoxide, Al(OPrⁱ)₃), as starting materials. The transparent gels were converted to the crystalline phase of gahnite by heating above 900°C. The microstructural evolution of gels was characterized. The effect of Co²⁺ concentration on spectroscopic properties was also discussed. Co²⁺: ZnAl₂O₄ nanocrystals dispersed in the SiO₂-based glass are formed at lower heat-treatment temperature and shorter heating time by using Al(OPrⁱ)₃ as raw material.     

覆铜板用环氧树脂的改性研究进展

本文介绍了环氧树脂在覆铜板中的使用情况和当前国内外对环氧树脂进行改性的研究现状，并介绍了今后覆铜板用环氧树脂的研究方向。     

Relay selection with feedback beamforming information through designed sector sweep report frame for mmWave WPANs

This paper proposes a novel relay selection strategy based on the feedback beamforming （BF） information through designed sector sweep （SSW） report frame for millimeter-wave （mmWave） wireless personal networks （WPANs）. First, an SSW report frame compatible with IEEE 802.11ad standard is designed. Second, an approach collecting instantaneous channel state information （CSI） overheard during BF is devised. Third, with the aim of minimizing the outage probability and maximizing the overall network throughput capacity, the optimal relay selection issue for non-line-of-sight （NLoS） links is formulated as a bipartite graph, and Kuhn Munkres （KM） algorithm is provided to resolve it. Both theoretical analysis and simulation results show, with CSI considering NLoS conditions and selected relays according to the overall network throughput capacity maximization principle, the improvements achieved over opportunistic relay selection strategy in terms of overall network throughput capacity and outage probability with minimal modifications to IEEE 802.1lad.     

Degradation of a textile azo dye by pulsed arc discharge to the surface of wastewater

The pulsed arc discharge to the surface of wastewater was applied to the degradation of a textile azo dye (Acid Red 27). A high-voltage electrode (discharging electrode) was vertically placed above the surface of the wastewater while the wastewater itself was grounded. The pulsed arc discharge occurred between the tip of the discharging electrode and the surface of the wastewater, producing various oxidative species. Oxygen was used as the working gas instead of air to prevent nitrogen oxides from forming. The effect of several parameters on the chromaticity and chemical oxygen demand (COD) removal was examined. The results obtained showed that the chromaticity of the wastewater was completely removed by this process and the COD also decreased significantly. It has been found that ozone formed in the gas phase mainly affects the removal of the dye. The contribution of other effects such as ultraviolet light emission and OH radical formation during the arc discharge to the degradation of the dye was found to be less than 15%. For the present reactor system, the optimum pH, pulse repetition rate and agitation speed were found to be 3.0, 110 Hz and 300 rpm, respectively.     

混凝土行业中基于JCS的海量数据协同模块的研究

随着国内预拌混凝土行业的发展,混凝土企业高层越来越意识到搅拌站信息化管理的必要性,各种混凝土搅拌站ERP软件在国内得到了迅速的发展,通过这种软件的信息化管理,后台数据库每天都会产生大量的生产数据。为了避免搅拌站之间的恶性竞争,混凝土行业协会和政府部门需要对某个区域乃至整个行业的搅拌站的生产运营情况有实时的了解,以便对其进行监管,最终促进行业的公平竞争。本文结合国内混凝土行业自身的特点,阐述了混凝土行业海量数据协同的总体构想和数学模型,之后从多维度论述了基于JCS多级缓存的海量数据协同模块的设计,最后,采用Socket的方式最终实现了Server端与Client端的一对多的数据通信。     

信息系统性能测试方法初探

信息系统的性能已经成为衡量企业信息系统建设水平的一个重要指标。目前不少企业在系统上线前进行性能测试,但由于缺少一套科学的测试流程和方法,企业投入的人力物力很多,但实际效果却不甚理想。本文主要介绍性能测试标准流程,该流程已在浙江电力企业实施,具有良好的实用价值。     

Crystallization behavior of starch‐filled polypropylene

Starches of different granule sizes, including corn, rice, and amaranth starches, were used to prepare starch‐filled polypropylene (PP) and the effect of starch granule size on crystallization behavior PP was investigated. Differential scanning calorimetry and scanning electron microscopy were used to monitor the energy changes of the crystallization of the melt and to characterize the morphology of PP/starch composites, respectively. Little interaction was observed between starch and PP despite the difference in starch granule size. The crystallization temperature of PP decreased with the addition of starch and this decrease became more apparent with increasing starch granule size. During nonisothermal crystallization, the dependency of the relative degree of crystallinity on time was described by the Avrami equation. The addition of starch decreased the overall crystallization rate of PP, which was attributed to an increase in the activation energy of crystallization under nonisothermal conditions according to the Kissinger equation. An increase in starch granule size of starch would increase the crystallization activation energy of PP and consequently decrease its crystallization rate. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 484–492, 2004     

Axisymmetric wave propagation in a solid viscoelastic sphere

Two problems of linear wave propagation in a viscoelastic solid sphere are solved. The waves are generated by two types of impact on the surface of the sphere. The deformation has symmetry with respect to an axis through the center of the sphere. The solution is based on a superposition principle which reduces the general solution to a static elastic solution, an elastic solution of an eigenvalue problem and an integral equation of the Volterra type involving time only. The solutions are given in double infinite series involving spherical Bessel functions, Legendre polynomials and Legendre functions of the first kind and order one.