Influence of Zirconium Addition on Magnetic Properties and Temperature Coefficient for Nanocomposite Nd10Fe78.5-xCo5ZrxB6.5 Magnets

The influence of Zr addition on magnetic properties and temperature coefficient for nanocomposite Nd10Fe78.5-xCO5ZrxB6.5 (x=0~4) bonded magnets was investigated. It was found that the room-temperature magnetic properties were remarkably improved with Zr addition due to the grain refinement and increasing volume fraction of the hard magnetic phase. The optimal magnetic properties of Jr=0.689T, iHc=769.4kA·m-1 and (BH)max=84kJ·m-3 were obtained for 2.5% Zr addition. The temperature coefficient of remanence (α) increases slightly and the temperature coefficient of coercivity (β) decreases obviously with increasing Zr content for nanocomposite Nd10Fe78.5-xCo5ZrxB6.5 (x=0~4) bonded magnets.     

A polynomial dynamic system approach to software design for attractivity requirement

Because of the widespread increasing application of Web services and autonomic computing, self-adaptive software is an area gaining increasing importance. Control theory provides a theoretical foundation for self-adaptive software. In this paper, we propose the use of the supervisory control theory of discrete event dynamic systems (DEDS) to provide a rigorous foundation for designing software for reactive systems. This paper focuses in particular on design of software with an attractivity requirement. It studies this problem using the polynomial dynamic system (PDS) model of DEDS. A necessary and sufficient condition for software existence and two algorithms for such software design are presented.     

非标压力机箱形主梁全约束优化设计

根据非标设备结构优化问题的特点,给出满足《钢结构设计规范》(GBJ17 88)规定的箱形主梁全约束优化设计方 法。将编制的内罚函数法优化程序应用于主梁的设计,计算结果表明,该优化方法可应用于实际设计。     

剖析全板电镀镍金发白现象

简要介绍了全板电镀镍金加工过程中镀金面发白现象及改善措施。特别是针对高位发白(或粗糙)的产生原因和处理过程进行较为详细的描述,并对工艺在此处理过程中存在问题进行了简要剖析。     

小生境遗传算法AVOA反演

采用具有水平对称轴的横向各向同性(HTI)模型研究裂缝性油气藏,P波振幅随炮检距和方位角变化(AVOA),表现出较强的方位各向异性特征。本文基于Ruger提出的HTI介质模型的P波反射系数公式,利用由基准测线和另外两条与之呈45°、90°测线的P波反射系数的相对差异估算裂缝方位;同时引入小生境遗传算法,对基准测线和与之呈90°测线的P波反射系数差进行反演,得到了较高精度的纵、横波波速比和Thomsen各向异性参数。     

Preparation and Characterization of Carboxymethyl Chitosan and β-Cyclodextrin Microspheres by Spray Drying

Three kinds of carboxymethyl chitosan/β-cyclodextrin microspheres loaded with theophylline were prepared by spray drying intended for pulmonary delivery. Mucociliotoxicity, permeation rate, and drug release characteristics of the product were investigated. The microspheres obtained by spray drying were found to be spherical with smooth or wrinkled surfaces. The mean particle size was between 3.39 and 6.06 µm. The microspheres demonstrated high product yield (43.7-50.2%), high drug loading (13.7-38.1%), and high encapsulation efficiency (86.9-92.8%). FT-IR indicated that there were interactions of theophylline with carboxymethyl chitosan matrix. Further studies on mucociliotoxicity and permeation confirmed that microspheres had better adaptability and high permeation rate. In vitro drug release from the microspheres was not related to the drug/polymer ratios.     

Syntheses and Structural Characterization of Triorganotin Derivatives of Bis(carboxymethyl)trithiocarbonate: X-ray Crystal Structures of 2D Network Polymers

Six triorganotin(IV) complexes of the type {(R₃Sn)₂[C₃S₃(COO)₂]}_n (R = C₆H₅ 1; n-Bu 2; PhCH₂ 4; p-F-PhCH₂ 5; o-F-PhCH₂ 6) and {(R₃Sn)₂[C₃S₃(COO)₂]}_n·[EtOH] (R = Me 3) have been synthesized by the reaction of bis(carboxymethyl)trithiocarbonate with triorganotin(IV) chloride in the presence of sodium ethoxide. All complexes were characterized by elemental analysis IR, ¹H, ¹³C and ¹¹⁹Sn NMR spectroscopy. Except for 4–6, all complexes were also characterized by X-ray crystallography. The X-ray date revealed that complexes 1–3 show two-dimensional network polymeric structure in which the geometries of tin atoms are trigonal bipyramid with the axial positions occupied by carboxylic oxygen atoms.     

c-BN color change with bonded water added into the h-BN–Mg system

Cubic boron nitride (c-BN) crystals were synthesized in conditions of high temperature and high pressure (HTHP) when different kinds of bonded water were respectively added into the system of h-BN–Mg. All bonded water used in this work could reduce the temperature of growing c-BN compared to that in the system of h-BN–Mg. The c-BN color could change from black to yellow when certain amounts of bonded water, such as NiSO₄·6H₂O and CuSO₄·5H₂O, Mg(OH)_2, were added. However, c-BN color remained black no matter how much bonded water, such as NiCl₂·6H₂O, CuCl₂·2H₂O, and SnCl₂·2H₂O, was added. The bonded water can be classified into Chlorine-containing bonded water (Cl-BW) and Chlorine-free bonded water (ClF-BW) according to their different characters and effects on the synthesized c-BN color.     

Hydrothermal Synthesis of Magnesium Aluminate Platelets

Magnesium aluminate (MgAl₂O₄) platelets were first synthesized by hydrothermal treatment of γ-AlO(OH) in a magnesium nitrate aqueous solution at 400°C. The platelets are 100–200 nm in width and 25 nm in thickness. The influence of temperature, the anions of the magnesium salt, the amount of magnesium salt, and precursor pH on the formation of such structure was investigated. The experimental results indicated that the anions of the magnesium salt and precursor pH could have a significant influence on the growth of MgAl₂O₄. MgAl₂O₄ formation followed the in situ transformation mechanism, which was the reason why the MgAl₂O₄ crystallites had a platelet morphology.     

Studies on the treatment of brilliant green solution by combination microwave induced oxidation with CoFe2O4

In this work the synergistic effects of microwave (MW) irradiation induced oxidation processes and CoFe₂O₄ were studied for the degradation of brilliant green (BG) from aqueous solutions. Under the optimum condition, the ratio of solid to liquid was 1:167 (0.3 g CoFe₂O₄ mixed with 50 mL of 20 mg L⁻¹ BG solution), MW power 600 W, and the time of the irradiation 2 min. And the decolorization rate could reach up to 100%. Further investigation showed that BG was degraded by MW-induced oxidation combined with CoFe₂O₄ surface adsorption. The CoFe₂O₄ could increase the efficiencies of MW degradation and be used repeatedly. The experimental results indicated that the method of MW degradation BG in the presence of CoFe₂O₄ could reduce reaction time and increase product yield.