Nucleation of Gas Bubbles in Extrusion Foaming of High-Pressure Polyethylene

The nucleation of gas bubbles in extrusion foaming of high-pressure polyethylene is considered. Experiments show that undissolved gas microbubbles in the solution being foamed can have a significant effect on the number density of pores in the foam. A simple model for estimating the number density of supercritical nuclei is proposed. The effect of the time of mixing of gas and polymer in the extruder, the talc concentration, and the geometric characteristics of the nozzle on the number density of pores in the foam is analyzed.     

Improvement in hydrolytic procedure for GLC determination of non-indolyl glucosinolates in rapeseed as isothiocyanates

Some methods determine the non-indolyl glucosinolates content in rapeseed as their hydrolysates: the isothiocyanates and the oxazolidinethiones. These methods in their present form underestimate the amount of the glucosinolates content. In this investigation, a modified method was developed to give a better quantitative estimate, indicating a glucosinolate level five times that obtained by a typical existing method.     

FATIGUE DAMAGE IN 1045 STEEL UNDER VARIABLE AMPLITUDE BIAXIAL LOADING

Abstract— During constant amplitude loading, two different types of crack systems have been reported In the high cycle fatigue (HCF) region, cracks nucleate on a small number of maxium shear strain amplitude planes One of these cracks becomes a dominant crack and leads to failure of the specimen In the low cycle fatigue (LCF) region, equally developed microcracks are observed over the entire gage section and grow during the majority of the life. The failure is due to a linking in which the microcracks join up during the last few cycles of the fatigue life.
To investigate the interaction of these two types of crack systems in biaxial fatigue, experiments were performed on thin-wall tubular specimens in tension, torsion and combined tension-torsion loading The test program included step loading and block loading in which two equivalent strain amplitudes were employed. One of the equivalent strain amplitudes is in the HCF region and the other was in the LCF region
Fatigue lives were predicted from constant amplitude damage curves when a single crack system dominated the fatigue process Two competitive crack systems were sometimes developed on the maximum shear strain amplitude planes in a single specimen under block loading This resulted in a conservative prediction of the fatigue life.     

AN ASSESSMENT OF CRACK CLOSURE AND THE EXTENT OF THE SHORT CRACK REGIME IN Q1N (HY80) STEEL

Abstract— The paper addresses some aspects of the differences in fatigue crack growth rate behaviour and threshold values obtained for long through-cracks, short through-cracks and surface cracks. Attention is focused on plasticity induced closure in the wake behind the growing crack tip. For long cracks at high K _max, closure is found to depend in a linear manner on K _max, i.e. K _op, increases with the size of the monotonic plastic zone. Closure increases at low δ K and this is primarily a consequence of the load shedding procedure. If short through-cracks are prepared by machining specimens containing long cracks, a substantial part of the plastic wake is removed and this can produce marked effects on the closure contribution during subsequent growth. The length of crack "closed" in a long crack threshold test was found to be of the order of 1 mm. Cracks less than this length exhibited "short crack" behaviour: greater than this length, they behaved as "long cracks", with plastic wake effects apparently fully operative. Small surface cracks exhibit "long crack" behaviour at lengths as short as 0.2 mm and reasons for this are discussed.     

Determination of molecular weight distributions of tert-octylphenol ethoxylate surfactant polymers by laser desorption Fourier transform ion cyclotron resonance mass spectrometry and high-performance liquid chromatography

Triton polymers are commercial surfactants whose molecular weight distributions are conventionally determined by means of high-performance liquid chromatography (HPLC). However, in the case of the important octylphenol ethoxylates [p-C8H17-C6H4-O-(CH2CH2O)n-H], HPLC cannot resolve individual oligomers of high molecular weight Triton surfactants (e.g., greater than 2000 u or so; u = unified atomic mass unit). In this paper, we show that laser desorption Fourier transform ion cyclotron resonance mass spectrometry (LD/FT/ICR/MS) provides a simple and accurate measure of such Triton surfactant molecular weight distributions up to at least 3500 u, based on a single-shot laser pulse measurement of a few seconds duration. Comparison of LD/FT/ICR/MS and HPLC molecular weight distributions of low molecular weight surfactants shows that laser desorption/ionization produces minimal fragmentation and thus offers an accurate measure of the relative abundances of the neutral oligomers, without the need for prior chromatographic separation of the components. Moreover, for all Triton polymer molecular weight distributions (700-3000 u), LD/FT/ICR/MS provides much more highly resolved profiles of oligomer relative abundances. Finally, LD/FT/ICR/MS reveals the presence of poly(ethylene oxide) side products of the polymerization process, which are not observed by HPLC with conventional ultraviolet absorption detection.     

Widely tunable bottom-emitting vertical-cavity SOAs

We present bottom-emitting tunable vertical-cavity semiconductor optical amplifiers (VCSOAs) with an effective wavelength tuning range of >20 nm. These devices utilize a high reflectivity micromechanically tunable Bragg mirror as the back reflector. Compared with our first generation tunable VCSOAs, the bottom-emitting devices exhibit a two-fold increase in the effective tuning range as well as a five-fold reduction in the required tuning voltage.     

Novel T-rail electrodes for substrate removed low-voltage high-speed GaAs/AlGaAs electrooptic modulators

A novel traveling-wave electrode utilizing capacitively loaded T-rail elements was developed for low-voltage high-speed substrate-removed GaAs/AlGaAs electrooptic modulators. Electrodes with varying dimensions were fabricated and characterized. Electrode phase velocity, characteristic impedance, loss coefficient, and capacitive loading were extracted from the measured s-parameters up to 40 GHz. Electrode was also simulated using a finite-element solver. The measured and calculated electrode capacitance values were found to be in excellent agreement, showing that the electrode can be precisely designed. Approaches were outlined to provide a group velocity-matched very high-speed modulator electrode suitable for a low drive-voltage substrate-removed GaAs/AlGaAs electro-optic modulator     

Analysis on the effectiveness of the 20-H rule for printed-circuit-board layout to reduce edge-radiated coupling

This paper presents the quantified study of the electromagnetic radiation mechanism of the 20-H rule using a numerical approach that has not yet been systematically addressed. The 20-H rule is a rule-of-thumb layout technique recommended to minimize radiated fields propagating from the edges of a printed circuit board (PCB) coupling onto nearby structures. Propagating electromagnetic fields may corrupt adjacent cable assemblies, sheet metal enclosures, and aperture openings. The magnitude of this design rule is investigated using the full-wave finite-difference time-domain (FDTD) method. An analysis on whether benefits exist from use of this rule is examined and under what conditions the rule is valid when correctly implemented. The purpose of this paper is to provide insight into the validity of the 20-H rule, recognizing that every PCB will have different simulation results. FDTD is used to capture a snapshot view of field propagation. This view allows one to determine the validity of the 20-H rule at a single point of time within a dynamic structure and what may be expected when digital components are finally added to a PCB assembly, which generally negates simulated results.