全文获取类型
收费全文 | 6478篇 |
免费 | 491篇 |
国内免费 | 11篇 |
专业分类
电工技术 | 95篇 |
综合类 | 3篇 |
化学工业 | 1782篇 |
金属工艺 | 75篇 |
机械仪表 | 174篇 |
建筑科学 | 248篇 |
矿业工程 | 12篇 |
能源动力 | 306篇 |
轻工业 | 1035篇 |
水利工程 | 81篇 |
石油天然气 | 29篇 |
无线电 | 429篇 |
一般工业技术 | 1041篇 |
冶金工业 | 413篇 |
原子能技术 | 35篇 |
自动化技术 | 1222篇 |
出版年
2024年 | 13篇 |
2023年 | 50篇 |
2022年 | 161篇 |
2021年 | 293篇 |
2020年 | 176篇 |
2019年 | 229篇 |
2018年 | 279篇 |
2017年 | 230篇 |
2016年 | 294篇 |
2015年 | 220篇 |
2014年 | 316篇 |
2013年 | 554篇 |
2012年 | 438篇 |
2011年 | 524篇 |
2010年 | 352篇 |
2009年 | 384篇 |
2008年 | 345篇 |
2007年 | 307篇 |
2006年 | 255篇 |
2005年 | 202篇 |
2004年 | 181篇 |
2003年 | 142篇 |
2002年 | 140篇 |
2001年 | 71篇 |
2000年 | 72篇 |
1999年 | 60篇 |
1998年 | 122篇 |
1997年 | 101篇 |
1996年 | 63篇 |
1995年 | 51篇 |
1994年 | 45篇 |
1993年 | 42篇 |
1992年 | 27篇 |
1991年 | 23篇 |
1990年 | 26篇 |
1989年 | 19篇 |
1988年 | 13篇 |
1987年 | 17篇 |
1986年 | 11篇 |
1985年 | 18篇 |
1984年 | 23篇 |
1983年 | 11篇 |
1982年 | 13篇 |
1980年 | 12篇 |
1979年 | 7篇 |
1978年 | 5篇 |
1977年 | 9篇 |
1976年 | 9篇 |
1975年 | 10篇 |
1974年 | 4篇 |
排序方式: 共有6980条查询结果,搜索用时 15 毫秒
101.
Chamorro G Salazar M Araújo KG dos Santos CP Ceballos G Castillo LF 《Archivos latinoamericanos de nutrición》2002,52(3):232-240
Spirulina (Arthrospira), a filamentous, unicellular alga, is a cyanobacterium grown in certain countries as food for human and animal consumption. It is also used to derive additives in pharmaceuticals and foods. This alga is a rich source of proteins, vitamins, amino acids, minerals, and other nutrients. Its main use, therefore, is as a food supplement. Over the last few years, however, it has been found to have many additional pharmacological properties. Thus, it has been experimentally proven, in vivo and in vitro that it is effective to treat certain allergies, anemia, cancer, hepatotoxicity, viral and cardiovascular diseases, hyperglycemia, hyperlipidemia, immunodeficiency, and inflammatory processes, among others. Several of these activities are attributed to Spirulina itself or to some of its components including fatty acids omega-3 or omega-6, beta-carotene, alpha-tocopherol, phycocyanin, phenol compounds, and a recently isolated complex, Ca-Spirulan (Ca-SP). This paper aims to update and critically review the results published over the last few years with regards to these properties. The conclusion is that even if this cyanobacterium has been one of the most extensively studied from the chemical, pharmacological and toxicological points of view, it is still necessary to expand the research in order to have more consistent data for its possible use in human beings. 相似文献
102.
DellaGreca M Isidori M Lavorgna M Monaco P Previtera L Zarrelli A 《Journal of chemical ecology》2004,30(4):867-879
Twenty-five 9,10-dihydrophenanthrenes, four phenanthrenes, a dihydrodibenzoxepin, and a pyrene, isolated from the wetland plant Juncus acutus, were tested to detect their effects on the green alga Selenastrum capricornutum. Nine of the compounds were isolated and identified for the first time. Most of the compounds caused inhibition of algal growth. The 9,10-dihydrophenanthrenes 1, 5, 21, and 22 were the most active. 相似文献
103.
Luis F. Hakim Jarod A. McCormick Guo-Dong Zhan Alan W. Weimer Peng Li Steven M. George 《Journal of the American Ceramic Society》2006,89(10):3070-3075
Surface modification of titania nanoparticles was achieved by coating them with ultrathin alumina films using atomic layer deposition. The coating process was performed in a fluidized bed reactor at low pressure and under mechanical vibration. Films were deposited using self-limiting, sequential surface reactions of trimethylaluminum and water. The composition of alumina-coated particles was verified using infrared spectroscopy. The deposited films had an average growth rate of 0.2 nm/coating cycle and were highly uniform and conformal as demonstrated by transmission electron microscopy and X-ray spectroscopy. Deposited alumina films were amorphous as verified through X-ray diffraction and high-resolution electron microscopy. The coating process did not promote particle sintering as validated via particle size and surface area analysis. 相似文献
104.
The electrochemical reduction of benzyl halides PhCH2X (X = Cl, Br and I) has been investigated at Ag and glassy carbon (GC) electrodes in CH3CN + 0.1 M Et4NClO4. At both electrodes reduction of PhCH2X involves irreversible electron transfer concerted with breaking of the carbon-halogen bond. All three halides exhibit a single 2e− reduction peak at GC, whereas up to three peaks can be observed at the Ag electrode. Silver exhibits remarkable catalytic properties for the reduction process, which is positively shifted by 0.45-0.72 V with respect to GC. The mechanism of reduction of the organic halides at Ag involves adsorption of both the starting reagents and their reduction products. Adsorption of PhCH2Cl and PhCH2Br is weak and slow, whereas PhCH2I is more rapidly and strongly adsorbed, so that two distinct peaks can be observed for the reduction of the dissolved and adsorbed molecules. Controlled-potential electrolyses at Ag have shown that the process may be directed to the production of bibenzyl or toluene, depending on the applied potential. 相似文献
105.
Córdova A 《Accounts of chemical research》2004,37(2):102-112
The direct catalytic asymmetric addition of unmodified carbonyl compounds to preformed or in situ-generated imines has emerged as a promising new route to optically enriched alpha- and beta-amino acid derivatives, beta-lactams, and 1,2- and gamma-amino alcohols. The direct catalytic asymmetric Mannich reactions are mediated by small organometallic and organic amine catalysts that can achieve levels of selectivity similar to those possible with natural enzymes. The different small-molecule catalysts described here are complementary in their applications. They also complement each other in syn or anti selectivity of the direct asymmetric Mannich reaction. In this Account, we highlight the recent developments in and contributions to this research. 相似文献
106.
Eduardo Arias-Marín Luis F. Ramos De Valle Oliverio Rodríguez-Fernndez Jesús Rodríguez-Velzquez 《乙烯基与添加剂工艺杂志》1995,1(4):217-222
The effect of elemental sulfur (S8) and tetramethyl thiuram disulfide (TMTD) on the chemical crosslinking of PVC is studied. The tensile strength, elongation at break, and gel content of crosslinked and uncrosslinked PVC molded samples, cured at different times in hot air, are evaluated. It was found that crosslinking PVC with TMTD improves its mechanical properties, and adding S8 produces a slight improvement. Also, the S8 presence accelerated the PVC/TMTD crosslinking reaction when the crosslinking reaction was carried out under shear forces, but not when the curing was done in hot air, where the S8 retards the process. 相似文献
107.
Electronic Markets - Robots are being implemented in many frontline services, from waiter robots in restaurants to robotic concierges in hotels. A growing number of firms in hospitality and tourism... 相似文献
108.
Milton Jimenez-Francisco Jose Gonzalo Carrillo Luis Alfonso Garcia-Cerda 《应用聚合物科学杂志》2021,138(1):49628
Mechanochemical degradation by planetary ball milling (PM) is used for postpolymerization modification of styrene homopolymers (PS). A complete factorial design was chosen to study the effect of radical scavengers, milling time, initial molecular weight, and revolution radius (Rp), on the shape of molecular weight distributions (MWDs) of PS. Size-exclusion chromatography analysis shows the feasibility of fine-tuning MWD of PS at up to 40% conversion. Distributions ranged from unimodal to bimodal in a PM with Rp = 150 mm at different stage of milling, whereas in a PM with Rp of 60.8 mm the adjustment of unimodal distributions is achieved. Initial polydispersity is more important to develop bimodal distributions when compared with initial molecular weight. Fourier transform infrared and X-ray electron spectrometry analysis show some suppression of PS degradation and complete oxidation inhibition of macromolecular radicals with the incorporation of radical scavengers, which we considered as additional aids when adjusting the MWDs. 相似文献
109.
Nawal Makhloufi Nadia Chougui Farouk Rezgui Elias Benramdane Carmen S. R. Freire Carla Vilela Armando J. D. Silvestre 《应用聚合物科学杂志》2021,138(20):50450
The present study investigated the fabrication and characterization of bio-based sustainable films composed of a terrestrial plant raw material, namely Opuntia ficus-indica (OFI) cladodes powder (CP) and a marine seaweed derivative, namely agar (A). The effect of glycerol concentration on the properties of the casted films was evaluated at four different contents, namely 30, 40, 50 and 60 wt%. The films present UV-blocking properties, as well as moderate mechanical performance, thermal stability, and water vapor transmission rate (WVTR). The results point to an increase in thickness, elongation at break, moisture content, water solubility, and WVTR with increasing glycerol content. On the contrary, Young's modulus, tensile strength, and water contact angle decreased as glycerol concentration increased. The best combination is obtained for the film with 30% glycerol, based on an intermediate compromise between physical, mechanical, thermal, and barrier properties. All these outcomes express the potentiality of the powder obtained from grinding the OFI cladodes as raw material to produce low-cost films for the development of sustainable packaging materials. 相似文献
110.
Cleide Borsoi Betina Hansen Ruan Ezequiel Gemmer Marcos Aurélio Dahlem Júnior Edson Luiz Francisquetti Ademir José Zattera Ruth Marlene Campomanes Santana André Luis Catto 《应用聚合物科学杂志》2021,138(45):51350
This study presents the preparation of post-consumer polypropylene (r-PP) composites filled with 30 wt% yerba mate (YM) stick particles. To improve the fiber–matrix adhesion, three surface treatments were performed: alkaline treatment with sodium hydroxide (NaOH) and use of 3-aminopropyltriethoxysilane (APTS) and maleic anhydride graft polypropylene copolymer (PP-g-MA) as coupling agents. Mechanical properties including tensile, flexural, and impact resistance were determined, and chemical (Fourier transform infrared spectroscopy [FTIR]), physical (water absorption), and morphological analyses were performed. The main findings show that the treatments were efficient in improving the mechanical properties of the composites, with emphasis on the r-PP/YM30/APTS and r-PP/YM30/PP-g-MA composites, which proved to be superior in tensile, flexion and impact strength and absorption of water compared to the untreated composite. The morphological analysis showed a better interaction between the fiber and the polymeric matrix for the composites with YM/APTS and YM/PP-g-MA, which corroborates the results of tensile and flexural strength, as well as with the spectra of FTIR in which the chemical modification of the fibers is observed. However, the results show that these treatments are promising in obtaining composites with recycled matrix with better properties. 相似文献