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61.
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63.
Yugong Wu Huili Zhang Yue Zhang Jinyi Ma Daohua Xie 《Journal of Materials Science》2003,38(5):987-994
Compositions in (Na1/2Bi1/2)TiO3 based ternary system, (0.97 – x) (Na1/2Bi1/2)TiO3-0.03NaNbO3-xBaTiO3 (x = 0, 0.01, 0.02, 0.04, 0.05, 0.06, 0.08) are synthesized using conventional solid state reaction method. Influence of BaTiO3 on crystal structure, dielectric and piezoelectric properties are investigated. All compositions can form single perovskite phase. Powder x-ray diffraction patterns can be indexed assuming a pseudo-cubic structure. Lattice constant increases with the increase of BaTiO3 concentration. Rhombohedral distortion is observed in poled samples with BaTiO3 concentration up to 6 mol%. Temperature dependence of dielectric constant and dissipation factor measurement reveals that all compositions experience two phase transitions: from ferroelectric to antiferroelectric and from antiferroelectric to paraelectric. Both transition temperatures, T
c and T
f, are lowered due to introduction of BaTiO3. Ferroelectric to antiferroelectric phase transition has relaxor characteristics. Piezoelectric properties have relatively higher value around 1 mol% to 4 mol% BaTiO3. In ceramics with x = 0.02, thickness electromechanical coupling factor (k
t) of 0.51 and piezoelectric charge constant (d
33) of 110 × 10–12 C/N are obtained. Addition of small amount of BaTiO3 (x = 0.01, 0.02) improves piezoelectric properties compared to NBT-NN binary system, while T
f remains above 140°C, higher than that of NBT-BT binary system composition with similar piezoelectric properties. This is in favor of the possible application of them as lead-free piezoelectric ceramics. 相似文献
64.
65.
求解二维结构-声耦合问题的一种直接方法 总被引:1,自引:1,他引:0
本文基于传递矩阵法(TMM)和虚拟边界元法(VBEM),提出了一种求解在谐激励作用下二维结构-声耦合问题的直接法。文中对任意形状的二维弹性环建立了一阶非齐次运动微分方程组,便于用齐次扩容精细积分法求解,对于含有任意形状孔穴的无穷域流体介质的Helmholtz外问题,采用复数形式的Burton-Miller型组合层势法建立了虚拟边界元方程,保证了声压在全波数域内存在唯一解。根据叠加原理并结合最小二乘法,提出了一种耦合方程的直接解法,由于该方法不存在迭代过程,因而具有较高的计算精度和效率。文中给出了二个典型弹性环在集中谐激励力作用下声辐射算例,计算结果表明本文方法较通常采用的混合FE/BE法更为有效。 相似文献
66.
B. Ma P.I. Djurovich S. Garon B. Alleyne M.E. Thompson 《Advanced functional materials》2006,16(18):2438-2446
Efficient blue‐, green‐, and red‐light‐emitting organic diodes are fabricated using binuclear platinum complexes as phosphorescent dopants. The series of complexes used here have pyrazolate bridging ligands and the general formula C∧NPt(μ‐pz)2PtC∧N (where C∧N = 2‐(4′,6′‐difluorophenyl)pyridinato‐N,C2′, pz = pyrazole ( 1 ), 3‐methyl‐5‐tert‐butylpyrazole ( 2 ), and 3,5‐bis(tert‐butyl)pyrazole ( 3 )). The Pt–Pt distance in the complexes, which decreases in the order 1 > 2 > 3 , solely determines the electroluminescence color of the organic light‐emitting diodes (OLEDs). Blue OLEDs fabricated using 8 % 1 doped into a 3,5‐bis(N‐carbazolyl)benzene (mCP) host have a quantum efficiency of 4.3 % at 120 Cd m–2, a brightness of 3900 Cd m–2 at 12 V, and Commission Internationale de L'Eclairage (CIE) coordinates of (0.11, 0.24). Green and red OLEDs fabricated with 2 and 3 , respectively, also give high quantum efficiencies (~ 6.7 %), with CIE coordinates of (0.31, 0.63) and (0.59, 0.46), respectively. The current‐density–voltage characteristics of devices made using dopants 2 and 3 indicate that hole trapping is enhanced by short Pt–Pt distances (< 3.1 Å). Blue electrophosphorescence is achieved by taking advantage of the binuclear molecular geometry in order to suppress dopant intermolecular interactions. No evidence of low‐energy emission from aggregate states is observed in OLEDs made with 50 % 1 doped into mCP. OLEDs made using 100 % 1 as an emissive layer display red luminescence, which is believed to originate from distorted complexes with compressed Pt–Pt separations located in defect sites within the neat film. White OLEDs are fabricated using 1 and 3 in three different device architectures, either with one or two dopants in dual emissive layers or both dopants in a single emissive layer. All the white OLEDs have high quantum efficiency (~ 5 %) and brightness (~ 600 Cd m–2 at 10 V). 相似文献
67.
Using a corrected sum rule and a generalized virial identity, we study the analytical expression for entire modes of the collective elementary excitation spectrum in a trapped Bose–Einstein condensate at any atom number. Explicit analytical formulas for the spectrum are obtained for the harmonic traps with both spherical symmetry and axial symmetry using the gaussian approximation for the N-body ground-state wave function of the condensate. These formulas give the simple dependence of all energy levels on the atom numbers, their interaction strength and trap geometry parameters. 相似文献
68.
基于模式理论光栅椭偏参数反演的数值模拟 总被引:5,自引:2,他引:3
将一种广泛用于求解系统优化问题的方法——正单纯形法,求解光栅的椭偏方程。首先,利用求解光栅的傅立叶模式理论对TE和TM波的复反射系数进行求解。然后计算出其相应的椭偏参数(△,Ψ),并在该值的基础上加入不同偏差的随机高斯噪声,将加入噪声后的值(△m,Ψm)作为模拟测量值。最后使用优化算法进行反演。通过对几种常用面形光栅椭偏参数的数值模拟,一方面表明傅立叶模式理论计算光栅的椭偏参数不仅精度高。而且速度快;另一方面表明利用正单纯形法得到的光栅参数值很接近于正演时假设的参数值,从而从理论上证明了利用椭偏法测量光栅各种光学参数的可行性。 相似文献
69.
X. Gong W. Ma J.C. Ostrowski K. Bechgaard G.C. Bazan A.J. Heeger S. Xiao D. Moses 《Advanced functional materials》2004,14(4):393-397
The electronic properties, carrier injection, and transport into poly(9,9‐dioctylfluorene) (PFO), PFO end‐capped with hole‐transporting moieties (HTM), PFO–HTM, and PFO end‐capped with electron‐transporting moieties (ETM), PFO–ETM, were investigated. The data demonstrate that charge injection and transport can be tuned by end‐capping with HTM and ETM, without significantly altering the electronic properties of the conjugated backbone. End‐capping with ETM resulted in more closely balanced charge injection and transport. Single‐layer electrophosphorescent light‐emitting diodes (LEDs), fabricated from PFO, PFO–HTM and PFO–ETM as hosts and tris[2,5‐bis‐2′‐(9′,9′‐dihexylfluorene)pyridine‐κ2NC3′]iridium(III ), Ir(HFP)3 as the guest, emitted red light with brightnesses of 2040 cd m–2, 1940 cd m–2 and 2490 cd m–2 at 290 mA cm–2 (16 V) and with luminance efficiencies of 1.4 cd A–1, 1.4 cd A–1 and 1.8 cd A–1 at 4.5 mA cm–2 for PFO, PFO–HTM, and PFO–ETM, respectively. 相似文献
70.
A note on the Gauss-Jacobi quadrature formulae for singular integral equations of the second kind 总被引:1,自引:0,他引:1
A fast and efficient numerical method based on the Gauss-Jacobi quadrature is described that is suitable for solving Fredholm
singular integral equations of the second kind that are frequently encountered in fracture and contact mechanics. Here we
concentrate on the case when the unknown function is singular at both ends of the interval. Quadrature formulae involve fixed
nodal points and provide exact results for polynomials of degree 2n − 1, where n is the number of nodes. Finally, an application of the method to a plane problem involving complete contact is presented. 相似文献