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491.
Responses of aquatic organisms to metal pollution in a lowland river in Flanders: a comparison of diatoms and macroinvertebrates 总被引:1,自引:0,他引:1
De Jonge M Van de Vijver B Blust R Bervoets L 《The Science of the total environment》2008,407(1):615-629
The role of macroinvertebrates and diatoms as indicator for metal pollution was investigated by assessing both biota along a metal gradient in the Belgian river the Dommel. Macroinvertebrates and diatoms were sampled in summer and winter and physical-chemical characteristics of the water were measured at four different sample periods and related to sediment characteristics. Although metal concentrations, except cadmium, in the water nowhere exceeded water quality standards, high metal concentrations were measured in the sediment, indicating historical contamination of the Dommel. At the sites that were situated downstream of the pollution source, high levels of conductivity and chloride were measured in the water. Redundancy Analysis (RDA) indicated pH, phosphate and zinc as the significant environmental variables explaining each respectively 7.7%, 11.6% and 22.6% of the macroinvertebrate community composition. Two clusters could be separated, with Gammarus pulex, Leptocerus interruptus, Baetis rhodani and Cloeon dipterum associated with low zinc concentrations and Tubificidae, Asellus aquaticus, Erpobdella sp. and Chironomus thummi-plumosus associated with higher zinc concentrations. Ammonium (10.6%), conductivity (16.5%), chloride (11.4%) and zinc (5.9%) turned out to be significant variables explaining the diatom community structure. Based on physical-chemical differences and species composition, three different groups could be separated. With this Tabellaria flocculosa and Fragilaria capucina var. rumpens were associated with low metal concentrations, Gomphonema parvulum and Nitzschia palea with elevated concentrations and Eolimna minima and Sellaphora seminulum with high zinc concentrations. In conclusion, the diatom community best reflected the metal gradient. With regard to water quality indices, those based on macroinvertebrates best followed the metal pollution gradient and were most strongly correlated with physical-chemical variables of water and sediment. This study indicated that to assess the effect of metal pollution in lowland rivers, the combined use of macroinvertebrates and diatoms is more appropriate than the use of both biota separately. 相似文献
492.
This paper describes the electroactuation of microcantilevers coated on one side with cationic polyelectrolyte brushes. We observed very strong cantilever deflection by alternating the potential on the cantilever between +0.5 and -0.5 V at frequencies up to 0.25 Hz. The actuation resulted from significant increases in the expansive stresses in the polymer brush layer at both negative and positive potentials. However, the deflection at negative bias was significantly larger. We have developed a theoretical framework that correlates conformational changes of the polymer chains in the brush layer with the reorganization of ions due to the potential bias. The model predicts a strong increase in the polymer volume fraction, close to the interface, which results in large expansive stresses that bend the cantilever at negative potentials. The model also predicts that the actuation responds much stronger to negative potentials than positive potentials, as observed in the experiments. 相似文献
493.
Coulier L Bas R Hekman M van der Werff BJ Burgering M Thissen U 《Journal of food science》2011,76(7):C1081-C1087
An ion-pair LC-ESI-MS method was developed capable of analyzing various reported umami or umami-enhancing compounds, including glutamic acid and 5'-ribonucleotides. The method was validated using tomato and potato samples and showed overall good analytical performance with respect to selectivity, detection limit, linearity, and repeatability. The method was applied to various tomato samples resulting in concentrations of glutamic acid and 5'-ribonucleotides that were in good comparison with literature. The methodology might also be used for the discovery of new umami (enhancing) compounds in an untargeted mode. This was to a certain extent demonstrated for tomato samples by correlating all peaks observed with the ion-pair liquid chromatography-mass spectrometry (LC-MS) method to sensory properties using multivariate statistics. PRACTICAL APPLICATION: This study describes the development and application of a LC-MS method, which can be used to quantify several known umami (enhancing) compounds in various foods. Furthermore, the method might be useful for the discovery of new umami (enhancing) compounds. 相似文献
494.
Little information is available concerning cosorbing oxyanion and metal contaminants in the environment, yet in most metal-contaminated areas, cocontamination by arsenate [AsO4, As(V)] is common. This study investigated the cosorption of As(V) and Zn on goethite at pH 4 and 7 as a function of final solution concentration. Complimentary extended X-ray absorption fine structure (EXAFS) spectroscopic data were collected at the As and Zn K-edges in order to glean information about the coordination environment of As and Zn at the goethite-water interface. Macroscopic sorption studies revealed that As(V) and Zn sorption on goethite increased in cosorption experiments beyond that suggested by single sorption isotherms. At pH 4 and 7, As(V) surface saturation was 3.2 and 2.2 micromol m(-2), respectively, and Zn surface saturation was absent at pH 4 and approximately 1.0 micromol m(-2) at pH 7. Arsenate sorption on goethite increased in the presence of Zn by 29% and by more than 500% at pH 4 and 7, respectively. In the presence of As(V), Zn sorption on goethite increased by 800 and 1300% at pH 4 and 7, respectively. More As(V) than Zn sorbed on goethite below surface saturation at pH 7. Above surface saturation, the Zn:As surface density ratio (SDR) remained constant at 0.91 +/- 0.03. At pH 4, the Zn:As SDR was less than 1 throughout the concentration range. Below As(V) surface saturation on goethite, As(V) formed bidentate binuclear bridging complexes on Fe and/or Zn octahedra, while Zn mainly formed edge-sharing complexes with Fe at the goethite surface. Above surface saturation, Zn was increasingly complexed by AsO4, gradually forming an adamite-like [Zn2(AsO4)OH] surface precipitate on goethite. Precipitated contaminants are more stable due to the limited dissolution kinetics of their solid phase. This study may therefore prove useful in remediation strategies of sites knowingly contaminated with oxyanions and metals. 相似文献
495.
A surface-micromachined nanotractor device has been used to investigate the tribological behavior of MEMS devices made of
polycrystalline silicon. An accelerated wear test, spanning several hundreds of thousands of cycles, was developed to monitor
the evolution of wear characteristics and frictional behavior during its operational lifetime. Postmortem microscopic observations
of the wear surfaces revealed features that can be categorized into two regimes of wear: (i) adhesion-dominated wear and (ii)
third-body wear. The former was characterized by asperity blunting, plastic deformation of asperity peaks, and smearing of
fine wear debris into a thin-surface film. With an increased number of wear cycles, the wear mechanism transitioned to the
latter regime which consisted of debris agglomeration and material removal through scratches induced by these agglomerates.
Finally, it was theorized that one of the agglomerates grows to a large size, adheres to one of the contact surfaces and causes
severe wear in a localized region on the counter surface to lock the two surfaces and cause device failure. 相似文献
496.
现在,大自然面临着日益增多的潜在威胁,这个脆弱的花园邀请您小心地触摸各种植物。我们不清楚未来将给我们带来什么,也不了解我们未来的生活将会是怎样。是否一直都有大自然、森林生存的地方?是否我们要建造的每一栋房子都有一个小花园?是否我们应该相信媒体试图让我们相信的,一切都将越来越好、更快捷、更便利。 相似文献
497.
Smits K Govaere J Peelman LJ Goossens K de Graaf DC Vercauteren D Vandaele L Hoogewijs M Wydooghe E Stout T Van Soom A 《Reproduction (Cambridge, England)》2012,143(2):173-181
The necessity for early interaction between the embryo and the oviductal and/or uterine environment in the horse is reflected by several striking differences between equine embryos that develop in vivo and those produced in vitro. Better understanding of the salient interactions may help to improve the efficiency of in vitro equine embryo production. In an initial experiment, cleavage-stage in vitro-produced (IVP) equine embryos were transferred into the uterus of recipient mares that had ovulated recently to determine whether premature placement in this in vivo environment would improve subsequent development. In a second experiment, an important element of the uterine environment was mimicked by adding uterocalin, a major component of the endometrial secretions during early pregnancy, to the culture medium. Intrauterine transfer of cleavage-stage IVP equine embryos yielded neither ultrasonographically detectable pregnancies nor day 7 blastocysts, indicating that the uterus is not a suitable environment for pre-compact morula stage horse embryos. By contrast, exposure to uterocalin during IVP improved capsule formation, although it did not measurably affect the development or expression of a panel of genes known to differ between in vivo and in vitro embryos. Further studies are required to evaluate whether uterocalin serves purely as a carrier protein or more directly promotes improved capsule development. 相似文献
498.
Karolien Vanhove Elien Derveaux Liesbet Mesotten Michiel Thomeer Maarten Criel Hanne Mariën Peter Adriaensens 《International journal of molecular sciences》2022,23(10)
Lung cancer cells are well documented to rewire their metabolism and energy production networks to enable proliferation and survival in a nutrient-poor and hypoxic environment. Although metabolite profiling of blood plasma and tissue is still emerging in omics approaches, several techniques have shown potential in cancer diagnosis. In this paper, the authors describe the alterations in the metabolic phenotype of lung cancer patients. In addition, we focus on the metabolic cooperation between tumor cells and healthy tissue. Furthermore, the authors discuss how metabolomics could improve the management of lung cancer patients. 相似文献
499.
Eduardo Solano Jolien Dendooven Davy Deduytsche Nithin Poonkottil Ji-Yu Feng Maarten B. J. Roeffaers Christophe Detavernier Matthias Filez 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(5):2205217
Metal nanoparticle (NP) sintering is a prime cause of catalyst degradation, limiting its economic lifetime and viability. To date, sintering phenomena are interrogated either at the bulk scale to probe averaged NP properties or at the level of individual NPs to visualize atomic motion. Yet, “mesoscale” strategies which bridge these worlds can chart NP populations at intermediate length scales but remain elusive due to characterization challenges. Here, a multi-pronged approach is developed to provide complementary information on Pt NP sintering covering multiple length scales. High-resolution scanning electron microscopy (HRSEM) and Monte Carlo simulation show that the size evolution of individual NPs depends on the number of coalescence events they undergo during their lifetime. In its turn, the probability of coalescence is strongly dependent on the NP's mesoscale environment, where local population heterogeneities generate NP-rich “hotspots” and NP-free zones during sintering. Surprisingly, advanced in situ synchrotron X-ray diffraction shows that not all NPs within the small NP sub-population are equally prone to sintering, depending on their crystallographic orientation on the support surface. The demonstrated approach shows that mesoscale heterogeneities in the NP population drive sintering and mitigation strategies demand their maximal elimination via advanced catalyst synthesis strategies. 相似文献
500.
Ilah Joos Fernando A. Lugo Maarten K. Sabbe Jeriffa De Clercq Jeroen Lauwaert 《American Institute of Chemical Engineers》2023,69(10):e18173
Biobased molecules constitute sustainable alternatives for fossil-based chemicals. However, to allow further valorization, the complex product mixtures resulting from biomass processing typically require downstream separation. Although many (semi)empirical thermodynamic models, like NRTL, are available for separation process design, their application for biobased molecules is hampered due to the lack of the necessary data to determine the binary interaction parameters used in these models. Therefore, in this work a case study comprising a set of furfural derivates has been used to showcase a methodology to efficiently determine these parameters. Based on first principles, COSMO-RS is used to generate a dataset of thermodynamic activities, which is subsequently used to regress the NRTL model against. Comparison of NRTL-HOC simulated vapor–liquid equilibria (VLE's) with experimental VLE's showed excellent agreement, confirming that COSMO-RS can be used to extend the use of (semi)-empirical models toward applications involving biobased molecules of which limited experimental data is available. 相似文献