Breaking the ice: a work domain analysis of icebreaker operations

Cognition, Technology & Work - Icebreakers are special-purpose ships designed to operate in different ice-covered waters, either independently or during assistance of weaker ships. In the...     

Rice-like CuO nanostructures for sensitive electrochemical sensing of hydrazine

In this work, a low temperature aqueous chemical growth methodology was used for the fabrication of CuO nanostructures. The as-synthesised nanostructures were then elaborately characterised by number of analytical techniques such as scanning electron microscopy (SEM) and X-ray powder diffraction (XRD). The obtained nanostructures were observed to possess interlaced rice-shaped structural features with the length and width of individual rice determined to be in the range of 200–300 nm and 50–100 nm respectively. The unique nanostructures when utilised as electrode material exhibited excellent electro-catalytic potential towards oxidation of hydrazine in alkaline media. The excellent conductive of CuO added by the high surface area of obtained nanorice-like structures enabled development of highly sensitive (3087 µA mM⁻¹ cm⁻²), selective and stable electrochemical sensor for hydrazine. In addition, the successfully application of the developed sensor in spiked tap, bottled and industrial water samples for the detection of hydrazine suggested its feasibility for practical environmental application.

     

Timber-framed partition walls and their restraining effect on warp in built-in wall studs – Models for twist

The shape of timber changes due to variations in moisture content (MC). Analytical models, which explain how the cladding restrains the timber studs that are prone to twist, are presented. The models are used for parametric studies of various properties, such as longitudinal shrinkage, torsional modulus of elasticity and cross-sectional size of the timber stud and stiffness of the cladding. With respect to twist, the bending stiffness of the cladding is of great importance. Large bending stiffness increases the restraint in the twist-prone studs and results in a straighter wall. Low torsional stiffness in the studs makes it easier for the cladding to restrain twist.     

Dielectric mismatch effect on coupled impurity states in a freestanding nanowire

We studied the coupled impurity states in a freestanding semiconductor nanowire (NW), within the effective mass approximation and including the effect of the dielectric mismatch, by using finite element method. Bonding and anti-bonding states are found and their energies converge with increasing distance d_i between the two impurities. The dependence of the binding energy on the wire radius R and the distance d_i between the two impurities is investigated, and we compare it with the result of a freestanding NW that contains a single impurity.     

Timber-framed partition walls and their restraining effect on warp in built-in wall studs – A model for spring

The shape of timber changes due to variations in moisture content (MC). A poor way of designing and/or erecting a structure may result in excessive deformation. An analytical model, which explains spring in a partition wall, is presented. The model is used for parametric studies of various properties such as longitudinal shrinkage coefficient, modulus of elasticity and cross-sectional size of the timber studs and stiffness of the cladding. With respect to spring, a problem is likely to occur when erecting a wall with single-sided cladding in a drying climate and the structure will benefit from relatively stiff studs and weak cladding.     

The isothermal variation of the entropy (ΔST) may be miscalculated from magnetization isotherms in some cases: MnAs and Gd5Ge2Si2 compounds as examples

The determination of the isothermal variation of the entropy (ΔS_T) is discussed in the present work. We show that ΔS_T has very different profiles and magnitudes when calculated from M vs. H or M vs. T experimental data. For MnAs compound, ΔS_T obtained from M vs. T data does not present a colossal peak. This result and the agreement between theoretical and experimental non-colossal magnetocaloric effect indicate that the colossal peak may be miscalculated from M vs. H experimental data. For Gd₅Ge₂Si₂ compound, ΔS_T obtained from M vs. T data does not present the peak observed in ΔS_T from M vs. H data.     

Thermomechanical properties of copper–carbon nanofibre composites prepared by spark plasma sintering and hot pressing

Several types of carbon nanofibres (CNF) were coated with a uniform and dense copper layer by electroless copper deposition. The coated fibres were then sintered by two different methods, spark plasma sintering (SPS) and hot pressing (HP). The Cu coating thickness was varied so that different volume fraction of fibres was achieved in the produced composites. In some cases, the CNF were pre-coated with Cr for the improvement the Cu adhesion on CNF. The results show that the dispersion of the CNF into the Cu matrix is independent of the sintering method used. On the contrary, the dispersion is directly related to the efficiency of the Cu coating, which is tightly connected to the CNF type. Overall, strong variations of the thermal conductivity (TC) of the composites were observed (20–200 W/mK) as a function of CNF type, CNF volume fraction and Cr content, while the coefficient of thermal expansion (CTE) in all cases was found to be considerably lower than Cu (9.9–11.3 ppm/K). The results show a good potential for SPS to be used to process this type of materials, since the SPS samples show better properties than HP samples even though they have a higher porosity, in applications where moderate TC and low CTE are required.     

Phase-based multidimensional volume registration

We present a method for accurate image registration and motion compensation in multidimensional signals, such as two-dimensional (2-D) X-ray images and three-dimensional (3-D) computed tomography/magnetic resonance imaging volumes. The method is based on phase from quadrature filters, which makes it robust to noise and temporal intensity variations. The method is equally applicable to signals of two, three or higher number of dimensions. We use parametric models, e.g., affine models, finite elements or local affine models with global regularization. Experimental results show high accuracy for 2-D and 3-D motion compensation.