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71.
Cellulose and abaca fibre reinforced polyoxymethylene (POM) composites were fabricated using an extrusion coating (double screw) compounding followed by injection moulding. The long cellulose or abaca fibres were dried online with an infrared dryer and impregnated fibre in matrix material by using a special extrusion die. The fibre loading in composites was 30 wt.%. The tensile properties, flexural properties, Charpy impact strength, falling weight impact strength, heat deflection temperature and dynamic mechanical properties were investigated for those composites. The fibre pull-outs, fibre matrix adhesion and cracks in composites were investigated by using scanning electron microscopy. It was observed that the tensile strength of composites was found to reduce by 18% for abaca fibre and increase by 90% for cellulose fibre in comparison to control POM. The flexural strength of composites was found to increase by 39% for abaca fibre and by 144% for cellulose fibre. Due to addition of abaca or cellulose fibre both modulus properties were found to increase 2-fold. The notched Charpy impact strength of cellulose fibre composites was 6-fold higher than that of control POM. The maximum impact resistance force was shorted out for cellulose fibre composites. The heat deflection temperature of abaca and cellulose fibre composites was observed to be 50 °C and 63 °C higher than for control POM respectively. 相似文献
72.
Thermal-hydraulic and aerosol containment phenomena modelling in ASTEC severe accident computer code 总被引:1,自引:0,他引:1
Ivo Kljenak Maik Dapper Luis E. Herranz Joan Fontanet 《Nuclear Engineering and Design》2010,240(3):656-667
Transients in containment systems of different scales (Phebus.FP containment, KAEVER vessel, Battelle Model Containment, LACE vessel and VVER-1000 nuclear power plant containment) involving thermal-hydraulic phenomena and aerosol behaviour, were simulated with the computer integral code ASTEC. The results of the simulations in the first four facilities were compared with experimental results, whereas the results of the simulated accident in the VVER-1000 containment were compared to results obtained with the MELCOR code. The main purpose of the simulations was the validation of the CPA module of the ASTEC code. The calculated results support the applicability of the code for predicting in-containment thermal-hydraulic and aerosol phenomena during a severe accident in a nuclear power plant. 相似文献
73.
The incorporation of salt in a polymer matrix could potentially achieve a humidity‐regulating film system of high porosity for packaging applications. In this study, sodium chloride (NaCl) powder was used as a model substance for humidity‐regulating fillers in polypropylene films. A polypropylene homopolymer was extrusion‐blended with NaCl at concentrations of 0.03, 0.06, 0.12, and 0.24 g NaCl·g film–1. Films were produced and were subsequently oriented mono and biaxially. At stretching ratios (SRs) of between 2 and 25 a porosity of 20% v/v to 50% v/v was achieved. The porosity positively correlated with the SR. An empirical model based on ellipsoids that approximated the correlation between the SR and the porosity was developed. This correlation offers a basis for further studies on other salt‐polymer systems that have undergone differing orientation processes. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
74.
Steven Angel Julian Neises Maik Dreyer Klaus Friedel Ortega Malte Behrens Yuan Wang Hamidreza Arandiyan Christof Schulz Hartmut Wiggers 《American Institute of Chemical Engineers》2020,66(1):e16748
Nano-sized perovskites were synthesized in a spray flame from nitrate precursors dissolved in ethanol and in ethanol/2-ethylhexanoic acid (2-EHA) mixtures. Experiments with ethanol led to a broad particle-size distribution and to the formation of undesired phases such as La2CoO4, La2O3, and Co3O4. The addition of 2-EHA can initiate micro explosions of the burning droplets and has been systematically investigated toward the formation of single-phase, high-surface-area LaCoO3 and LaFeO3 with a narrow size distribution. To investigate the effect of 2-EHA, temperature-dependent changes of the chemical composition of the precursor solutions were analyzed with ATR-FTIR between 23 and 70°C. In all cases, the formation of esters was identified while in the solutions containing iron, additional formation of carboxylates was observed. The synthesized materials were characterized by BET SSA, XRD, SAED and EDX-TEM and their catalytic activity was analyzed, reaching 50% CO conversion at temperatures below 160 and 300°C for LaCoO3 and LaFeO3, respectively. 相似文献
75.
Maik Negendank Soeren Mueller Walter Reimers 《Journal of Materials Processing Technology》2012,212(9):1954-1962
In this study extrusion experiments were carried out in order to investigate and develop the coextrusion process for light weight magnesium–aluminum macro composites. Seamless tubes were extruded using hybrid billets combining EN AW-6060 tubes as coating material and various Mg-alloys (ZM21, AZ31, AS11, AM10, AM30 and AM50) as core material. Further AZ31/EN AW-6060 rods were produced to investigate the influence of the die angle and different combining techniques of Mg-core and Al-sleeve on the diffusion layer formation. Additionally the effect of mechanically interlocked fittings and a Zn-foil as interlayer material on the coextrusion process and products were examined. For characterization of the compound's shear strength push-out tests were performed. 相似文献
76.
John O. Akindoyo Mohammad D. H. Beg Suriati Ghazali A. K. M. M. Alam Hans P. Heim Maik Feldmann 《应用聚合物科学杂志》2019,136(15):47400
In vitro biocompatibility of impact modified composites produced from poly(lactic acid) (PLA) and hydroxyapatite (HA) is reported in this study. Surface modification was previously used to facilitate the dispersion of HA in PLA, whereas impact property of the PLA-HA composites was deliberately enhanced as it was necessary. Herein, osteoblast cell culture assay was used to assess the possible effects of HA surface modification and impact modification on the cell behavior in physiological media. Furthermore, antimicrobial properties of the HA were assessed. Evidence of HA modification was confirmed through elemental and spectroscopic analysis. Incorporation of HA offered better cell attachment and proliferation to the PLA matrix, with significant increase in the cell viability (%). Also, modification of HA did not present obvious cytotoxicity to the PLA-HA composite. Conversely, incorporation of impact modifier slowed down the rate of cell proliferation on the composite surface but facilitates increased wettability. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47400. 相似文献
77.
78.
Iron‐catalyzed depolymerizations of silicones with hexanoic anhydride provide a potential recycling method for end‐of‐life polymers
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79.
We present a fast and accurate time domain based algorithm which extracts simultaneously the thickness and refractive index
of highly transparent samples from terahertz time domain spectroscopy data. The utilized transfer function considers the Fabry-Perot
oscillations of the sample and enables to analyze data with multiple reflections. The algorithm can also be applied to signals
corrupted by vapor absorption lines. Since the data extraction takes only fractions of a second, this computation method is
well suited for real-time monitoring of industrial processes. We show that the accuracy of the new algorithm is comparable
to that of sophisticated, highly accurate and time consumptive frequency domain algorithms. 相似文献
80.