Waste cement dusts as fillers for rubber compounds

The possibility of substitution of expensive active fillers, e.g. carbon black, for the waste products which can play the role of these fillers, e.g. the waste cement dusts or the waste post-HF silica, were investigated. The physico-chemical properties of the investigated waste cement dusts and the waste post-HF silica, as well as the strength properties of the rubber compounds containing these as fillers, were determined. To increase the activity and chemical affinity with the rubber, the waste cement dusts and the waste post-HF silica were modified by the use of adhesion promoters, that is alkoxysilanes. It was found that it would be possible to partly substitute carbon black for the waste cement dusts and the waste post-HF silica. The mixture ratio of a compound which had these wastes and showed the optimum strength properties was proposed.     

General modelling method of power losses in transmission with parameter identification

There is rarely a general or standard method to calculate the overall efficiency of a complete vehicle gearbox. This paper aims to develop such method which can possibly be applied to different types of transmissions in a flexible way and provide a platform to compare several different products from different OEMs or suppliers in parallel.A number of standards and publications concerning the calculation of power losses specifically for one transmission component such as gears, roller bearings or specific phenomenon like oil churning are available in the literature. Different models from these sources are compared, selected and combined to obtain the resulting efficiency map of a complete gearbox system.This paper presents the calculation of such a combined efficiency map of a transmission for an electric vehicle through either the standard models (ISO14179) for industry transmissions or this new joint overall model. The comparisons of available experimental data and calculations show that the result of the joint overall model has a better proximity to the test results. Nevertheless, the uncertainties in the input parameters of the model strongly affect the calculated power loss and the resulting efficiency of the gearbox. Parameter studies are conducted to determine the most influential parameters in the joint overall model. Several selected parameters are identified through experimental overall efficiency maps by classic parameter identification method and algorithm. On the one hand, a much better proximity is achieved. On the other hand, the identified parameters indicate the optimization potential of the component losses for benchmarking of transmissions.     

Partition-based workload scheduling in living data warehouse environments

The demand for so-called living or real-time data warehouses is increasing in many application areas such as manufacturing, event monitoring and telecommunications. In these fields, users normally expect short response times for their queries and high freshness for the requested data. However, meeting these fundamental requirements is challenging due to the high loads and the continuous flow of write-only updates and read-only queries that might be in conflict with each other. Therefore, we present the concept of workload balancing by election (WINE), which allows users to express their individual demands on the quality of service and the quality of data, respectively. WINE exploits these information to balance and prioritize both types of transactions—queries and updates—according to the varying user needs. A simulation study shows that our proposed algorithm outperforms competing baseline algorithms over the entire spectrum of workloads and user requirements.     

Pigment Epithelium-Derived Factor (PEDF) Receptors Are Involved in Survival of Retinal Neurons

The demise of retinal ganglion cells (RGCs) is characteristic of diseases of the retina such as glaucoma and diabetic or ischemic retinopathies. Pigment epithelium-derived factor (PEDF) is a multifunctional secreted protein that mediates neuroprotection and inhibition of angiogenesis in the retina. We have studied expression and regulation of two of several receptors for PEDF, patatin-like phospholipase 2 gene product/PEDF-R and laminin receptor (LR), in serum-starved RGC under normoxia and hypoxia and investigated their involvement in the survival of retinal neuronal cells. We show that PEDF-R and LR are co-expressed in RGC and R28 retinal precursor cells. Expression of both receptors was enhanced in the presence of complex secretions from retinal glial (Müller) cells and upregulated by VEGF and under hypoxic conditions. PEDF-R- and LR-knocked-down cells demonstrated a markedly attenuated expression of anti-apoptotic Bcl-2 family members (Bcl-2, Bcl-xL) and neuroprotective mediators (PEDF, VEGF, BDNF) suggesting that both PEDF-R and LR mediate pro-survival effects of PEDF on RGC. While this study does not provide evidence for a differential survival-promoting influence of either PEDF-R or LR, it nevertheless highlights the importance of both PEDF receptors for the viability of retinal neurons.     

Silicon-nanowire transistors with intruded nickel-silicide contacts

Schottky barrier field effect transistors based on individual catalytically-grown and undoped Si-nanowires (NW) have been fabricated and characterized with respect to their gate lengths. The gate length was shortened by the axial, self-aligned formation of nickel-silicide source and drain segments along the NW. The transistors with 10-30 nm NW diameters displayed p-type behaviour, sustained current densities of up to 0.5 MA/cm2, and exhibited on/off current ratios of up to 10(7). The on-currents were limited and kept constant by the Schottky contacts for gate lengths below 1 microm, and decreased exponentially for gate lengths exceeding 1 microm.     

A nanostructured electrochromic supercapacitor

We report the first successful application of an ordered bicontinuous double-gyroid vanadium pentoxide network in an electrochromic supercapacitor. The freestanding vanadia network was fabricated by electrodeposition into a voided block copolymer template that had self-assembled into the double-gyroid morphology. The highly ordered structure with 11.0 nm wide struts and a high specific surface to bulk volume ratio of 161.4 μm(-1) is ideal for fast and efficient lithium ion intercalation/extraction and faradaic surface reactions, which are essential for high energy and high power density electrochemical energy storage devices. Supercapacitors made from such gyroid-structured vanadia electrodes exhibit a high specific capacitance of 155 F g(-1) and show a strong electrochromic color change from green/gray to yellow, indicating the capacitor's charge condition. The nanostructuring approach and utilizing an electrode material that has intrinsic electrochemical color-change properties are concepts that can be readily extended to other electrochromic intercalation compounds.     

Caffeine in your drink: natural or synthetic?

Owing to possible adulteration and health concerns, it is important to discriminate between natural and synthetic food ingredients. A new method for compound-specific isotope analysis (CSIA) by coupling high-temperature reversed-phase liquid chromatography to isotope ratio mass spectrometry (HT-RPLC/IRMS) was developed for discrimination of natural and synthetic caffeine contained in all types of drinks. The analytical parameters such as stationary phase, column inner diameter, and column temperature were optimized for the separation of caffeine directly from drinks (without extraction). On the basis of the carbon isotope analysis of 42 natural caffeine samples including coffee beans, tea leaves, guaraná powder, and maté leaves, and 20 synthetic caffeine samples from different sources by high-temperature reversed-phase liquid chromatography coupled to isotope ratio mass spectrometry, it is concluded that there are two distinguishable groups of caffeine δ(13)C-values: one between -25 and -32‰ for natural caffeine, and the other between -33 and -38‰ for synthetic caffeine. Isotope analysis by HT-RPLC/IRMS has been applied to identify the caffeine source in 38 drinks. Four mislabeled products were detected due to added but nonlabeled synthetic caffeine with δ(13)C-values lower than -33‰. This work is the first application of HT-RPLC/IRMS to real-world food samples, which showed several advantages: simple sample preparation (only dilution), high throughput, long-term column stability, and high precision of δ(13)C-value. Thus, HT-RPLC/IRMS can be a very promising tool in stable isotope analysis of nonvolatile compounds.     

When other separation techniques fail: compound-specific carbon isotope ratio analysis of sulfonamide containing pharmaceuticals by high-temperature-liquid chromatography-isotope ratio mass spectrometry

Compound-specific isotope analysis (CISA) of nonvolatile analytes has been enabled by the introduction of the first commercial interface to hyphenate liquid chromatography with an isotope ratio mass spectrometer (LC-IRMS) in 2004, yet carbon isotope analysis of unpolar and moderately polar compounds is still a challenging task since only water as the eluent and no organic modifiers can be used to drive the separation in LC. The only way to increase the elution strength of aqueous eluents in reversed phase LC is the application of high temperatures to the mobile and stationary phases (HT-LC-IRMS). In this context we present the first method to determine carbon isotope ratios of pharmaceuticals that cannot be separated by already existing separation techniques for LC-IRMS, such as reversed phase chromatography at normal temperatures, ion-chromatography, and mixed mode chomatography. The pharmaceutical group of sulfonamides, which is generally mixed with trimethoprim in pharmaceutical products, has been chosen as probe compounds. Substance amounts as low as 0.3 μg are sufficient to perform a precise analysis. The successful applicability and reproducibility of this method is shown by the analysis of real pharmaceutical samples. The method provides the first tool to study the pharmaceutical authenticity as well as degradation and mobility of such substances in the environment by using the stable isotopic signature of these compounds.     

Structural response of A2TiO5 (A = La,Nd, Sm,Gd) to swift heavy ion irradiation

Different compositions of orthorhombic A₂TiO₅ (A = La, Nd, Sm, Gd) have been irradiated with swift Xe ions (1.47 GeV). Systematic analysis of the structural modifications induced by ion track formation was completed using transmission electron microscopy, synchrotron X-ray diffraction, and Raman spectroscopy. Significant radiation-induced amorphization occurred, but the size of the amorphous regions within the tracks decreased as smaller cations (higher Z) occupied the A-site. This decrease in the amorphous domain size is attributed primarily to epitaxial recrystallization of a disordered phase at the outer edge of the tracks, the stability of which is related to the ratio of the ionic radii of the A- and B-site (B = Ti) cations. While similar ion track recrystallization phenomena have been observed in pyrochlores of varying composition, A₂TiO₅ is unique in that the disordered phase is not a high-temperature polymorph, suggesting kinetic control of the radiation-induced transformation.     

Microstructural Analysis of Reballed Tin-Lead,Lead-Free,and Mixed Ball Grid Array Assemblies Under Temperature Cycling Test

In this study, ball grid array (BGA) packages with Sn-3.0Ag-0.5Cu (SAC305) solder balls were reballed with Sn-37Pb solder balls. Three different reballing methods were used. The non-reballed lead-free BGAs were assembled with SAC305 and Sn-37Pb solder pastes to form the lead-free and mixed assemblies. The reballed Sn-Pb BGAs were assembled with Sn-37Pb solder paste to form the reballed Sn-Pb assemblies. All assemblies were subjected to a temperature cycling test with a temperature range of −55°C to 125°C. For the same component type, the reballed BGA assemblies showed similar temperature cycling reliability regardless of the reballing methods. However, the temperature cycling reliability of the reballed assemblies was worse than that of the mixed and the lead-free assemblies. The mean cycles-to-failure of the mixed assemblies was larger than or equal to that of the lead-free assemblies. Failure analysis revealed that the failure site in reballed Sn-Pb assemblies was located in the bulk solder at the component side regardless of the component type and the reballing method, indicating that the reballing method did not influence the crack propagation in reballed assemblies. The mixed assemblies had the same failure site as the lead-free assemblies, i.e., in the bulk solder at the component side. The microstructure differences between the tin-lead, lead-free, and mixed assemblies are also discussed in detail.