Ion-irradiation-induced structural transitions in orthorhombic Ln2TiO5

The response of a material to a high radiation field is important when selecting materials for nuclear applications, such as structural materials, nuclear waste forms and inert matrix fuels. In the present study, the radiation response of orthorhombic, rare-earth titanates, Ln₂TiO₅ (Ln = La, Nd, Sm, Gd, Dy and Y), was investigated by 1 MeV Kr²⁺ ion bombardment at temperatures ranging from 50 to 1073 K. In situ transmission electron microscopy revealed that the radiation tolerance and irradiation-induced structural transitions vary largely with composition. Y₂TiO₅ exhibits the lowest critical amorphization temperature (T_c = 623 K), above which crystals cannot be amorphized, which is consistent with its use in the form of nanoclusters in radiation-resistant oxide-dispersion-strengthened steels. The disordered fluorite structure type of Ln₂TiO₅, with smaller Ln cations, formed as an intermediate phase prior to becoming fully amorphous. The fluorite structure type of Ln₂TiO₅, containing more vacancies as compared with that of Ln₂Ti₂O₇, may exhibit enhanced ionic conductivity, which highlights an effective way of using ion beams to modify the properties of materials.     

Colour analysis on portable sphere for custom white balance with multiple illuminations

A novel, efficient white balancing technique is presented for images illuminated by multiple light sources. The existing portable twodimensional grey reference colour chart has been replaced by a portable three-dimensional (3D) grey sphere to deal with multiple illuminant sources in the 3D real world. Experiments indicate that the proposed solution provides significantly better white balance results in the sense of both objective error measure and subjective visual quality.     

Battery-Buffered Alkaline Water Electrolysis Powered by Photovoltaics

The combination of an alkaline water electrolyzer (AWE) with a battery system powered by photovoltaics (PV) for the production of green hydrogen is investigated. A model describes the power distribution between these three subsystems (AWE, battery and PV). Variation of AWE and battery power and capacity is carried out for two locations, to identify the most appropriate setup, where the highest energy usage and operating time can be reached. The battery helps to reduce the power level of the AWE. However, an estimation of the costs indicates that further optimization is necessary.     

Preparation and properties of B6O/TiB2-composites

B₆O/TiB₂ composites with varying compositions were produced by FAST/SPS at temperatures between 1850 and 1900 °C following a non-reactive or a reactive sintering route. The densification, phase and microstructure formation and the mechanical and thermal properties were investigated. The comparison to an also investigated pure B₆O material showed that the addition of TiB₂ in a non-reactive sintering route promotes the B₆O densification. Further improvement was obtained by sintering reactive B–TiO₂ mixtures which also results in materials with a finer grain size and thus in enhanced mechanical properties. The fracture toughness was significantly improved in all composites and is up to 4.0 MPa m^1/2 (SEVNB) and 2.6–5.0 MPa m^1/2 (IF method) while simultaneously a high hardness of up to 36 GPa (HV_0.4) and 28 GPa (HV₅) could be preserved. The high temperature properties at 1000 °C of hardness, thermal conductivity and CTE were up to 20 GPa, 18 W/mK and 6.63 × 10^?6/K, respectively.     

Amber Light Control of Peptide Secondary Structure by a Perfluoroaromatic Azobenzene Photoswitch

The incorporation of photoswitches into the molecular structure of peptides and proteins enables their dynamic photocontrol in complex biological systems. Here, a perfluorinated azobenzene derivative triggered by amber light was site-specifically conjugated to cysteines in a helical peptide by perfluoroarylation chemistry. In response to the photoisomerization (trans→cis) of the conjugated azobenzene with amber light, the secondary structure of the peptide was modulated from a disorganized into an amphiphilic helical structure.     

Experimental and numerical studies on the braiding of carbon fibres over structured end-fittings for the design and manufacture of high performance hybrid shafts

Braiding is an attractive manufacturing method for tubular elements such as hollow shafts and struts. One of the main challenges however is the integration of suitably performing end-fittings. Recent advances in additive layer manufacture have enabled the fabrication of end-fittings which can be ‘co-impregnated’ or ‘co-cured’ with the fibre preform in a single step, i.e. without the need for secondary adhesive bonding. This requires the introduction of protrusions onto the surface of the end-fitting to promote mechanical interlocking with the fibres. However, the lack of accurate modelling tools for the simulation of this manufacturing process means that much empiricism is currently used in the design of such structures. A novel numerical framework is presented here for the full-scale simulation of the braiding process over structured end-fittings. Nonlinear finite element analysis is applied at the meso-scale, with strands of beam elements representing individual yarns and meshed surfaces modelling the mandrel and tooling. Penalty-based contact formulations are then used to simulate all inter-yarn and yarn-metal interactions, enabling detailed predictions of fibre paths around surface protrusions. In order to verify and validate this numerical framework, a series of full-scale braiding experiments was conducted using additively-manufactured thermoplastic mandrels. Final braid patterns as well as the occurrence of braid imperfections were investigated and compared to model predictions. It is shown that the proposed modelling strategy reproduces well the trends observed experimentally in terms of final braid quality. A parametric study was then conducted on the effects of initial end-fitting alignment with respect to oncoming yarns, suggesting that better control over this parameter could reduce considerably the occurrence of braid imperfections.     

High temperature properties of B6O-materials

B₆O is a potential superhard material with a hardness of 45 GPa measured on single crystals. Recently it was found that different oxides can be utilized as an effective sintering additive which allows densification under low pressures. In this work the effect of addition of Y₂O₃/Al₂O₃ on high temperature properties was investigated using impulse excitation technique (IET), hardness measurements and dilatometric measurements. The IET technique reveals the softening of the residual B₂O₃ in the materials without additives at 450 °C; in the materials with Y₂O₃/Al₂O₃ the softening is observed at only about 800 °C. This data agrees with the values found for different borate glasses.The materials showed no pronounced reduction of hardness at these temperatures. This is additional evidence, supporting previous observations that the material consists of pure grain boundaries between B₆O grains. Hardness values (HV5) of up to 17 GPa at 1000 °C were observed.     

Aspects of reproducibility and stability for partial cure of epoxy matrix resin

Partial cure of thermosets is a promising approach to enhance manufacturing possibilities of reinforced and unreinforced polymers. If partial cure is taken into consideration as a genuine process parameter, novel manufacturing technologies can be developed by exploiting the specific properties of incomplete polymer networks. A main concern in this context is to control the kinetic reaction avoiding inhomogeneous or instable degrees of cure. Based on a combination of numerical simulations and experiments, a methodology is presented that enables a systematic assessment of the reproducibility and stability of partial cure. Special attention is paid to the interaction of thermal boundary conditions and the cure kinetic of thick samples as well as the storability of partially cured resin under different conditions. Guidelines for cure cycle selection, mold design, and storage are derived. The possibility to use complex multistep cure schedules and extended storage periods is demonstrated for an unmodified noninhibited epoxy resin. © 2019 The Authors. Journal of Applied Polymer Science published by Wiley Periodicals Inc. J. Appl. Polym. Sci. 2020 , 137, 48342.     

Kinetic Investigation of Polyurethane Rubber Formation from CO2-Containing Polyols

A novel CO₂ utilization technology allows for the inclusion of CO₂ as carbonate units and double bond moieties to give additional functionality in polyether polyols. This study examines the chain-elongation kinetics of these diols with diisocyanates to polyurethane rubbers by means of thermal analysis. A reaction order of 1 indicates a strong influence of the chains' mobility on the reaction rate. Spectrometry and comparison with non-double-bond polyols reveal that the effect cannot be attributed to a substantial occurrence of side reactions but is rather due to the intertwining of lengthy chains.