Investigation on the electrical characteristics of sol-gel derived Pb1.05(Zr0.53Ti0.47)O3 thin films

Abstract

Lead zirconate titanate (PZT) thin films with composition Zr/Ti ～ 0.53/0.47 were deposited by the sol-gel technique. The films were characterized in terms of its polarization relaxation, fatigue and imprint characteristics. We have found that the polarization relaxation is due to the presence of a depolarization field which increases dramatically with the rise in temperature. Improved fatigue performance was observed when the film was fatigued with higher frequency. The direction of imprint depends on the state of polarization. With the increase in net polarization, the trapped charge density at the film-electrode interface increases which leads to imprint characteristics. Also the imprint increases considerably with the rise in temperature. Finally, we have made an attempt to correlate simultaneously fatigue, polarization relaxation, and imprint characteristics with the presence of mobile charge defects (viz. V_o) and defect dipoles (viz. V_Pb – V_o) in the film.     

Self-tuning flexible ac transmission system controllers for power oscillation damping: a case study in real time

Design and real-time implementation of a self-tuning flexible ac transmission system (FACTS) controller is illustrated for power oscillation damping. Although the system model is not required for self-tuning control design, it is shown to perform similar to a model-based design. For parameter estimation, the classical recursive least square (RLS) is supplemented by a random walk (RW) with a switched structure and compared to standard variable forgetting factor (VFF) approach. It is shown that the RW improves the accuracy and convergence of the estimated system parameters, which is critical to self-tuning control following large disturbances. The performance is validated in real time using a commercial real-time simulation platform. The control computation time is shown to be considerably less than the typical sampling time used for power oscillation damping applications demonstrating the feasibility of self-tuning FACTS controllers in practice.     

Hydrogeochemistry and arsenic contamination of groundwater in the Ganges Delta Plain, Bangladesh

Geochemical composition and the level of Arsenic (As) contamination of groundwater in the Ganges Delta Plain, southwestern Bangladesh were elucidated. Hydrogeochemical data of tube well samples suggested that the groundwater is mostly Ca-Mg-HCO(3) type with bicarbonate (HCO(3)(-)) as the dominant anion, though other type waters are also observed. In contrast, the elevated EC, Cl(-) and high content of Na(+) relative to Ca(2+), Mg(2+) and K(+) in six groundwater samples suggest their saline origin. Low concentrations of NO(3)(-) and SO(4)(2-), and high concentrations of dissolved organic carbon (DOC), HCO(3)(-) and PO(4)(3-) indicate the reducing conditions of subsurface aquifer where sediments are deposited with abundant organic matter. The total As concentration in the analyzed samples is very high (0.0431-1.352 mg/L) along with high Fe (2.791-17.058 mg/L) and relatively low Mn (0.134-1.972 mg/L) at different depths. Distinct relationship of As with Fe and Mn, and strong correlation with DOC suggests that the biodegradation of organic matter and reductive dissolution of Fe-oxyhydroxide is considered to be the dominant processes to release As in aquifers. Moreover, negative correlation between As and SO(4)(2-) demonstrates the As may not be directly mobilized from sulfide minerals like arsenopyrite.     

Comparison of the Electrical Characteristics of PZT and SBT Thin Films

The electrical properties of lead zirconate titanate (PZT) and strontium bismuth tantalate (SBT) thin films are compared for nonvolatile random access memory applications. PZT thin films have high switchable polarization with poor fatigue resistance and higher leakage current densities as compared to SBT thin films deposited on platinized silicon substrates. Characterization of these films in terms of their domain dynamics under application of sub-switchable and switchable electric fields give valuable insight about the observed differences in the electrical behavior. In the present work the dielectric behaviors of SBT and PZT thin films at sub-switchable electric field were analyzed in terms of Rayleigh law. The reversible and irreversible polarization component of switchable polarization was separated by the measurement of capacitance-voltage (C-V) and polarization hysteresis loops. The conduction mechanisms in these films were evaluated by measuring field dependence of leakage current densities at various temperatures. The observed differences in electrical properties are explained in terms of the intrinsic defects and defect-domain interaction of these two materials.     

Critical Issues in Sol-Gel Derived Ferroelectric Thin Films: A Review

In this article we have reviewed our recent research efforts on the synthesis and characterization of a wide spectrum of ferroelectric thin films for a variety of electronic and electro-optic devices including computer memories, tunable microwave devices, infra-red detectors, and electro-optic modulators. The review is separated into three sections; first we have described the process induced modifications of the properties of perovskite films prepared by sol-gel technique. The next section reviews the effect of certain impurity elements (e.g. La, Nd, Ce etc) in modifying the electrical characteristics of perovskite thin films followed by our experimental observations on the synthesis of epitaxially grown perovskite thin films by sol-gel technique. The epitaxial quality of BST thin films has been evaluated by fabricating eight element coupled microstrip phase shifters at NASA Glenn Research Center. Finally, future directions of sol-gel thin film research have been highlighted in view of these experimental observations.     

Some studies on uncertainty management in dynamical systems using cybernetic approaches and fuzzy techniques with applications

Uncertain information processing by fuzzy if–then rules has received much attention. Here we have taken a different path to model a system, about which we do not have precise information, namely modelling the system by fuzzy-valued functions without resorting to fuzzy if–then rules. As a result, the phase (state) space of the system becomes a fuzzy set and the underlying fuzzy mapping becomes a fuzzy attainability set mapping. Uncertain or fuzzy dynamical systems have been defined in terms of fuzzy attainability set mappings. Fuzzy differentiable dynamical systems have been discussed with a particular emphasis on fuzzy differential inclusion (FDI) relations. An evolutionary algorithm for solving one-dimensional FDIs has been developed. A model of the creation of a tropical cyclone in the form of a vortex, created by winds coming from different directions and colliding under certain conditions, has been proposed in terms of FDIs. A model has been considered for the highly uncertain system of evolution of a tumour in a human body and an FDI relation model of the whole system has been proposed and simulated. The model of an evolution of turbulence, as a random occurrence of vortices in a three-dimensional dynamic fluid, has been proposed and simulated, where each vortex is modelled by a fuzzy-valued function, where uncertain parameter and variable values are fuzzy numbers. All the systems represented by FDI relations have been simulated with the help of the evolutionary algorithm mentioned above.     

Pattern recognition,image processing and computer vision in fifth generation computer systems

It is well-known that one of the goals of research for the last two decades or so in pattern recognition and its sub-areas, such as processing, analysis and understanding of image, speech and natural language, and computer vision techniques etc., has always been to develop fundamental techniques for flexible interactive intelligent man-machine interfaces for computers. In this paper, the author tries to argue that for the evolution of fifth generation computer systems (FGCS) as defined by Japanese scientists, some of the things required are realisation and implementation of the advances in pattern recognition and its sub-areas, not only to achieve the man-machine interface with a natural mode of communication, but also for the realisation of the basic mechanisms of inference, association and learning, which are inherent both in pattern recognition and in the core functions of FGCS. The next generation computers will be knowledge-based systems, which form a subdomain of artificial intelligence (a1) techniques, and soa1 provides the essential link between pattern recognition domains and different application systems. No attempt is made to discuss other essential conceptual building blocks, such as software engineering, computer architecture and very large scale integration technology unless these become very relevant in the discussions of concerned topics of the paper. A section on limitations of perception, learning and knowledge for computing machines is also included. This work was funded by the Knowledge-based Computer Systems Project of the Department of Electronics, Government of India.     

Evaluation of standard thermodynamic parameters for the sorption of n-hexane and methanol in zeolites

Adsorption isotherms for n-hexane and methanol in mordenite and ZSM5 in the temperature range from 323 K to 473 K were found to be of type 1. The adsorbate-adsorbent interaction (C₁) and adsorbate-adsorbate interaction (C₂) wee computed according to Bradley and Wilkins model, whereas the Rees and Williams model predicts the adsorption characteristics. Finally, the thermodynamic parameters such as ΔG^o, ΔS^o, ΔH^o, K, K⁺ have been evaluated for the sorption of n-hexane in mordenite and ZSM5.     

Infant and child mortality determinants in Bangladesh: are they changing?

From the data of the 1989 Bangladesh Fertility Survey, aggregate deaths reported at ages 0-12 and 13-60 months are used to estimate infant and child mortality. Multivariate analysis shows that preceding birth interval length, followed by survival status of the immediately preceding child, are the most important factors associated with differential infant and child mortality risks; sex of the index child and mother's and father's education are also significant. Demographic factors are influential during infancy as well as childhood, but social factors, particularly mother's and father's education, now emerge as significant predictors of infant mortality risks. This indicates a change in the role of socioeconomic factors, since the earlier Bangladesh Fertility Survey in 1975.     

Androgen receptor mRNA detection in the human foetal prostate

OBJECTIVE: The objective of this study is to present our preliminary experience with pulmonary hypertension inhaled nitric oxide therapy with two newborns presenting with transposition of the great arteries, as well as the usefulness of the Doppler in pulmonary hypertension diagnosis. PATIENTS AND METHODS: Revision of the variations of the hypoxic parameters according to the therapy and revision of the diagnostic procedures in both cases was carried out. RESULTS: Nitric oxide therapy was followed by an evident improvement of the hypoxia and the patient's hemodynamic stabilization, which allowed surgical correction in optimal conditions. The ductal flow pattern allowed recognition of the presence of pulmonary hypertension. CONCLUSIONS: Inhaled nitric oxide must be taken into account as a very useful option in the treatment of this kind of patient and the Doppler examination allows the evaluation of the presence of pulmonary hypertensions.