Diphenole und Caramelkomponenten in R?stkaffees verschiedener Sorten. II.

Zusammenfassung Elf Diphenole and sieben Caramelkomponenten wurden aus entfettetem Röstkaffee durch Extraktion mit Pentan/Äther (1 + 1) isoliert und nach Silylierung mit BSTFA gaschromatographischmassenspektrometrisch charakterisiert and größen-ordnungsmäßig bestimmt. Sieben Phenole und fünf Caramelkomponenten konnten erstmals in Röstkaffee identifiziert warden. Robustakaffee besitzt die größten Mengen an Phenolen and Maltol, während Arabica-kaffee die höchsten Konzentrationen an Furaneol (2,5-Dimethyl-4-hydroxy-3(2H)-furanen), Isomaltol, 5-Hydroxymaltol and 5-Hydroxy-5,6-dihydro-maltol aufweist.

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Diphenols and caramel compounds in roasted coffees of different varieties. II.

Summary Eleven diphenols and seven caramel compounds were extracted from roasted coffee with pentane/ether (1 + 1), silylated with BSTFA, characterized, and semiquantified by GC-MS. Seven phenols and five caramel components were identified for the first time in roasted coffee.Robusta coffee contained the highest amounts of phenols and maltol.Arabica showed higher amounts of furaneol (2.5-dimethyl-4-hydroxy-3(2H)-furanone), isomaltol, 5-hydroxymaltol, and 5-hydroxy-5.6-dihydromaltol.

     

Regression of advanced atherosclerosis in swine

Advanced complicated atherosclerosis was produced in the abdominal aorta of swine by a combination of mechanical injury and high-cholesterol, high-fat diet for four months. After removal of the high-cholesterol diet and placing the animal on swine mash for 14 months, there was a significant (P less than .005) decrease in size of lesions with remodeling of the intima toward a smooth surface. Sudanophilia had virtually disappeared and atheromas were almost absent in the regression group, as were thrombosis and hemorrhage in plaques. Cell proliferation, as judged by the number of labeled cells in autoradiography, was less pronounced in this group. There was no decrease in the numbers of segments showing calcification; however, the size of the calcified areas was smaller in the regression group than in the base line. The data suggest that advanced atherosclerosis is susceptible to regression on removal of the atherosclerotic stimulus.     

Yearly simulation of the interaction between an ice rink and its refrigeration system: A case study

A transient model of airflow and heat transfer in an indoor ice rink and a quasi-steady model of its refrigeration system have been coupled and used to simulate their response to the time dependent ambient conditions and operating schedule for a typical meteorological year. The results for two different cases show that it is possible to reduce significantly the time of operation of the compressors and the energy consumption of the refrigeration system by simultaneously reducing the ceiling emissivity and increasing the secondary coolant temperature without affecting the quality of the ice.     

Optimization of continuous electrocoagulation-adsorption combined process for the treatment of a textile effluent

The aims of this study is to design and optimize the functioning of a full continuous combined process based on electrocoagulaion-adsorption on crude Tunisian clay to treat a real textile effluent. The clay characterization shows that the used clay is a rich-smectite clay. The response surface methodology (RSM) technique based on Box-Behnken design (BBD) was used to optimize the process. At optimum conditions which are initial pH solution of 8.24, effluent flow rate of 0.5 L·min^-1, voltage of 70 V, and added suspension of clay flow rate of 100 ml·min^-1 the achieved color, chemical oxygen demand (COD) and total suspended solid (TSS) removal efficiencies were respectively 96.87%, 89.77% and 84.46% with 0.75USD·m^-3 as total cost. The additional laboratory experiments at optimum conditions agree with the predicted results, which confirm the accuracy and the capability of RSM to predict results in the defined space. Finally the designed process could be a good eco-friendly alternative to treat and reuse wastewater in industrial process with reasonable cost.     

Performance analysis of distributed storage clusters based on kernel and userspace traces

Distributed storage systems are commonly used in modern computing. They are highly scalable and offer data replication and fault tolerance. The complexity of those systems makes them difficult to debug using traditional tools. The existing tools are able to evaluate the overall performance of such systems but they do not provide enough information to find the root cause of performance issues. In this article, we propose a tracing‐based performance analysis framework for storage clusters. We use a tracing strategy that reduces the tracing overhead in production systems. The traces collected from the different storage nodes are correlated and used to generate a data model that represents the cluster. Userspace tracing is used to gather data from the storage daemons, while Kernel tracing is used to provide detailed information about operating system internals such as disk queues, network queues and process scheduling. Efficient data structures are used to store the model and to generate metrics and graphical views. Our tool is used in different real world scenarios and is able to investigate interesting performance problems including I/O latencies, data replication and storage nodes failures.     

Long-term bond performance of GFRP bars in concrete under temperature ranging from 20 °C to 80 °C

Eighty pull-out specimens were used to study the effect of temperature ranging from 20 °C to 80 °C in dry environment on bond properties between Glass Fiber Reinforced Polymer (GFRP) bars and concrete. The pullout-test specimens were subjected during 4 and 8 months to high temperatures up to 80 °C and then compared to untreated specimens (20 °C). Experimental results showed no significant reduction on bond strength for temperatures up to 60 °C. However, a maximum of 14% reduction of the bond strength was observed for 80 °C temperature after 8 months of thermal loading. For treated specimens, the coefficient β in the CMR model, which predicts the bond–stress–displacement behavior, seems to be dependant with the temperature.     

The effect of plasma‐polymerised silicon hydride‐rich polyhydrogenmethylsiloxane on the adhesion of silicone elastomers

BACKGROUND: Silicone elastomers have outstanding material properties including good thermal stability, low electrical conductivity, biocompatibility and resilient physical and chemical properties. These elastomers, however, exhibit relatively poor adhesion to stainless steel, and the use of a nanometre thick plasma‐polymerised primer layer as a means of enhancing this adhesion was investigated in this study. The primer coatings studied consisted of polyhydrogenmethylsiloxane (PHMS), tetraethyl orthosilicate (TEOS) and mixtures of these two liquid precursors. RESULTS: The plasma‐polymerised primer coatings were deposited onto stainless steel substrates using a PlasmaStream^? atmospheric pressure plasma jet system. Deposited coatings were examined using ellipsometry, contact angle measurements, optical profilometry, Fourier transform infrared spectroscopy, X‐ray photoelectron spectroscopy and scanning electron microscopy. The adhesion of silicone elastomers bonded to the primed and bare stainless steel surfaces was assessed using 45° adhesion strength measurements. Elastomer adhesion was correlated with surface energy, thickness and roughness. CONCLUSION: An up to 15‐fold increase in adhesive fracture energy was observed for silicone elastomers bonded to the primed versus untreated stainless steel. The highest adhesion was observed for a coating deposited from a PHMS‐to‐TEOS precursor molar ratio of 3 to 1. Copyright © 2009 Society of Chemical Industry     

Electrical properties of magnesium sodium hydrogen monophosphate: MgNa3H(PO4)2

Magnesium sodium hydrogen monophosphate, Na₃MgH(PO₄)₂, crystallizes in the triclinic cell . The crystal morphology is related to the synthesis temperature and the evaporation rate. Samples were characterized through X-ray diffraction and chemical analysis, examined by IR and Raman vibrational spectroscopy and impedance and modulus spectroscopy techniques. The conductivity relaxation parameters associated with some H^· conduction have been determined from an analysis of the M^″/M_max^″ spectrum measured in a wide temperature range. Transport properties in this material appear to be due to an H^· ion hopping mechanism.