Second harmonic generation diagnostic of layer-by-layer deposition from Disperse Red 1 – functionalized maleic anhydride copolymer

Layer-by-layer (LBL) electrostatic assembly of polyelectrolytes is proving to be an increasingly rich and versatile technique for the formation of multilayered thin films with a wide range of electrical, magnetic, and optical properties. In the present work we synthesized a new non-linear optical (NLO) maleic acid copolymer containing Disperse Red 1 moieties, built-up multilayer assemblies by alternate adsorption of poly(allylamine hydrochloride) (PAH) and maleic copolymer derivative, and carried out an investigation on their second harmonic generation (SHG) properties. The resulting multilayer assemblies exhibit SHG which arises from the non-centrosymmetric alignment of the chromophores in the copolymer. The SHG signal increases with the number of chromophore-containing polymer layers, up to five layers. Further assembly reduces the signal.     

Dendritic anion hosts: perchlorate uptake by G5-NH2 poly(propyleneimine) dendrimer in water and model electrolyte solutions

Perchlorate (ClO4-) has emerged as a major groundwater and surface water contaminant in the United States. Ion exchange (IX) is the most widely used technology for treating water containing lower concentrations of perchlorate (<100 ppb). However, a major drawback of IX is the need for frequent regeneration or disposal of the perchlorate-laden resins. As a first step toward the development of high-capacity, selective and recyclable dendritic ligandsforthe recovery of perchloratefrom aqueous solutions by dendrimer filtration, we tested the hypothesis that dendrimers with hydrophobic cavities and positively charged internal groups should selectively bind ClO4- over more hydrophilic anions such as Cl-, NO3-, SO4(2-), and HCO3-. We measured the uptake of ClO4- by the fifth generation (G5-NH2) poly(propyleneimine) (PPI) dendrimer with a diaminobutane core and terminal NH2 groups in deonized water and model electrolyte solutions as a function of (i) anion-dendrimer loading, (ii) solution pH, (iii) background electrolyte concentration, and (iv) reaction time. The ClO4- binding capacity of this dendrimer is comparable to those of perchlorate-selective IX resins. However, its ClO4- binding kinetics is faster and reaches equilibrium in approximately 1 h. Note also that only a high pH (approximately 9.0) aqueous solution is needed to release more than 90% of the bound ClO4- anions by deprotonation of the dendrimer tertiary amine groups. The overall results of this study suggest that dendritic macromolecules such as the G5-PPI NH2 dendrimer provide ideal building blocks for the development of high-capacity, selective and recyclable ligands for the recovery of anions such as perchlorate from aqueous solutions by dendrimer enhanced filtration.     

An equivalence between rational H2 and Hankel-norm approximations

Let H(z) be a given function in H₂ A classical problem in engineering analysis is to find a rational function G (z) ε H₂ degree M say, which is closest to H(z) in 2-norm. This problem is typically approached using the cost function |H(z) − G(z)|₂, in which G(z) is allowed to vary over the set of Mth-order rational functions in H₂ and for which stationary points are sought. We show that each stationary point of degree M of this functional coincides with a weighted Hankel-norm approximant to H(z). The weighting function derives from the outer factor of the error function H(z) − G(z) stationary point of the rational H₂ approximation problem.     

Effect of type and level of roughage offered to sheep and urine addition on compost quality and millet growth and production in the Sahel

A greenhouse trial was carried out at the International Crop Research Institute for the Semi-Arid Tropics (ICRISAT), at Sadoré (13°15′ N, 2°18′ E), Niger. Experiments were conducted in conjunction with a feeding trial. The feeding trial yielded eight types of compost made from faeces and leftovers with or without urine addition from sheep fed either bush straw or millet stover offered at 60 or 80 g dry matter (DM) kg⁻¹ live weight (LW). In the second trial the agronomic value of composts to a millet crop was evaluated. The level of roughage on offer did not affect compost quality. Urine addition increased N content in composts (P<0.05), but had no effect on P. Millet stover based composts contained 24% more N and 42.5% more P than composts made with bush straw (P<0.05). Urine addition enhanced millet growth between 15 and 60 days after planting (DAP), increased millet aboveground mass by a factor 2.8, and increased the efficiency of N and P use by 100% and 50%, respectively. Millet response (growth, phytomass, N and P uptake, apparent efficiency of N and P use) to urine addition was higher with millet stover based composts than with bush straw based composts (P<0.05). It was concluded that addition of urine during composting of roughage leftovers and faeces from stall-fed animals could significantly improve nutrient recycling and consequently the productivity of mixed farming systems of semi-arid West Africa. This revised version was published online in November 2006 with corrections to the Cover Date.