Improved PWM control for GTO inverters with pulse number modulation

This paper proposes pulse number modulation (PNM)-assisted pulse-width modulation (PWM) control to improve the modulation factor of bridge inverters and to solve voltage uncontrollability in neutral point clamped (NPC) inverters. The basic idea is to enlarge the linear region of PWM control via PNM technology. The authors show the following through simulation and experimental results: (1) conventional bridge inverters can utilize at most 80% of the nominal inverter capacity because of the limit of the modulation factor. The PWM and PNM combined control is able to improve the modulation factor up to approximately 1.0; and (2) the PWM and PNM control enables linear voltage control in the NPC inverter even for an extremely small reference. The PNM technology also contributes to a reduction in switching losses     

Coherency strains influence on martensitic transformation of γ-Fe particles in compressed Cu-Fe alloy single crystals

Single crystals of a Cu-Fe alloy, which contained spherical -Fe particles, were compressed up to shear strain of 0.17 in liquid nitrogen bath. In the process of straining the structural (optical and TEM) observations in as-deformed and post-deformation annealed samples were provided. The substructure of deformed samples was characterized by slightly developed cell structure and lack of distinct layer-like arrangements of dislocations. Three kinds of particles were found: coherent and semi-coherent f.c.c. -Fe and martensiticly transformed b.c.c. -Fe. The critical diameter for coherency loss was found to be 58 nm at the initial stage of deformation decreasing with strain to 50 nm. These values coincided with the theoretical estimations. It was suggested that relaxation of coherency strains around -Fe particles by the generation of interface dislocations might occur prior to the martensitic transformation. This assumption might explain the particle size dependency of martensitic transformation.     

An immunodominant haptenic epitope of carbamazepine detected in serum from patients given long-term treatment with carbamazepine without allergic reaction

An anticarbamazepine antibody was detected in the serum of a patient with severe carbamazepine-induced serum sickness. We found that the patient's T cells and IgG antibody recognized an epitope which appeared in subjects showing an allergic reaction, as well as that in subjects who showed no allergic reaction, after long-term carbamazepine therapy. These results show that an anti-carbamazepine immune response does not occur in the majority of subjects who undergo long-term carbamazepine therapy without developing allergic symptoms, although the immunodominant haptenic epitope of carbamazepine is present in their sera.     

Molecular dynamic simulation of heterogeneity and chemical states of fluorine in amorphous alkaline earth silicate systems

Chemical states of fluorine in fluorosilicate glasses in the system MF₂-MO-SiO₂ (M = Ca, Sr and Ba; SiO₂ content < 60 mol%) have been investigated by molecular dynamic (MD) simulations with a perfect ionic two-body potential. Comparison of the results with those derived by X-ray photoelectron spectra of the actual glasses demonstrates that MD simulations reproduce well the bonding states of fluorine in the systems as well as the formation of M-F clusters. The MD generated structure of imaginary glasses, or glasses not obtained by the conventional melt-quench technique, with 70 mol% SiO₂ indicates that an acidic environment induces a greater amount of F---Si bonds. Their M-F pair correlation functions plotted against normalized M-F distances suggest that relative ion positions in the clusters are very similar.     

Wind-flow measurement over the Subaru Telescope

Wind flows over the 8.2-m Subaru Telescope at Mauna Kea in Hawaii were analyzed with a correlation method. Three or four wind flows were detected from our measurements. Spatial and temporal resolution of the wind-flow analysis across the 8.2 m pupil were investigated experimentally. A three-dimensional spatiotemporal-frequency analysis was also applied to the wind-flow data.     

Rate of emulsion polymerization of styrene

In emulsion polymerization, the Smith and Ewart theory gives about two or three times the number of polymer particles obtained by experiment. In this paper, a reaction model is proposed which, from the standpoint of reactor design, can give an adequate explanation of the whole course of an emulsion polymerization of monomer highly insoluble in water. Among other things, the generating process of polymer particles is examined in detail. It is demonstrated experimentally that a new parameter proposed here, which represents the degree of difficulty of monomer initiation in micelles, is indispensable in explaining that process. Also confirmed is that monomer initiation takes place more easily in polymer particles than in micelles. According to the new model, the progress of polymerization, i.e., monomer conversion, the number of the polymer particles, and properties of polymer thus produced can be estimated with satisfactory accuracy. Furthermore, approximate equations are derived for easier estimation.     

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Effects of rice cleaning and cooking process on the residues of flutolanil,fenobucarb, silafluofen and buprofezin in rice

We studied the effect of cleaning and cooking on the residues of flutolanil, fenobucarb, silafluofen and buprofezin in rice. The rice had been sprayed in a paddy field in Wakayama city, with 3 kinds of pesticide application protocols: spraying once at the usual concentration of pesticides, repeated spraying (3 times) with the usual concentration of pesticides and spraying once with 3 times the usual concentration of pesticides. The residue levels of pesticide decreased during the rice cleaning process. Silafluofen, which has a higher log Pow value, remained in the hull of the rice. Fenobucarb, which has a lower log Pow value, penetrated inside the rice. The residue concentration of pesticide in polished rice was higher than that in pre-washed rice processed ready for cooking. During the cooking procedure, the reduction of pesticides in polished rice was higher than that in brown rice.