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631.
In this age of globalization, the realization of production innovation and highly stable operation is the chief objective of the process industry in Japan. Obviously, modern advanced control plays an important role to achieve this target, but the key to success is the maximum utilization of PID control and conventional advanced control. This paper surveys how the three central pillars of process control – PID control, conventional advanced control, and linear/nonlinear model predictive control – have been used and how they have contributed toward increasing productivity. In addition to introducing eminently practical methods, emerging methods, and their applications, the authors point out challenging problems. In Japan, industry and academia are working in close cooperation to share their important problems and develop new technologies for solving them. Several methods introduced in this paper are results of such industry–academia collaboration among engineers and researchers in various companies and universities. Furthermore, soft-sensor or virtual sensor design is treated with emphasis on its maintenance, because soft-sensors must cope with changes in process characteristics for their continuous utilization. Maintenance is a key issue not only for soft-sensors but also for controllers. Finally, we will expand our scope and briefly introduce recent activities in tracking simulation and alarm management. A part of the results of our recent questionnaire survey of process control are also introduced; the results are extremely helpful in clarifying the state of the art in chemical process control in Japan. 相似文献
632.
Manabu Shimada Kikuo Okuyama Seiji Okazaki Takuya Asai Masao Matsukura Yoshiaki Ishizu 《Aerosol science and technology》2013,47(3):242-255
ABSTRACT The change in concentration distribution of particulate contaminants emitted in a room was studied experimentally and theoretically to investigate whether the transport of contaminants in a room with a source of particles can be predicted by numerical simulation. Tracer contaminants, monodisperse latex particles, were introduced into a 3.3 m ×2.7 m ×2 m room with clean air for a given time, and the change in the contaminant concentrations with time was measured at various positions in the room. Calculations of the spatial and temporal distributions in the gas velocity and contaminant concentration were performed to predict the concentration change, with the Navier-Stokes and convection-diffusion equations solved numerically. The experimental results showed that the concentration distribution depends on the position of introduction of the contaminants. It was also indicated that the contaminants introduced near the room floor diffuse more than predicted. However, the calculated concentrations agreed almost quantitatively with the measured results, except near the floor and walls. The change in the concentration with time and the dependence of the concentration distribution on the position of the particle source were well reproduced by the calculation. 相似文献
633.
Ryoichi Furushima Yuki Nakashima Yutaka Maruyama Kiyoshi Hirao Tatsuki Ohji Manabu Fukushima 《Journal of the American Ceramic Society》2023,106(8):4944-4954
Two mechanical properties, fracture toughness (KIC) and bending strength (σ), of silicon nitride (Si3N4) ceramics were determined from their microstructural images via convolutional neural network (CNN) models. The Si3N4 samples used for database were fabricated using various kinds of sintering additives under different process conditions. In total, 330 data sets were prepared and used for building the CNN models for artificial intelligence-bassed determination of the two mechanical properties and testing the determination accuracy of the trained models. The determination coefficients (R2), which were used as accuracy indices, were approximately 0.85 for KIC and 0.92 for σ. Although both the R2 values were relatively high, the lower value for KIC suggests that it is influenced more by what is little obtained from the microstructural information, such as grain-boundary characteristics. Furthermore, gradient-weighted class activation mapping, which can visualize which parts of the image the CNN models focus on, showed that the trained models determined the two mechanical properties based on correct recognition of the microstructural difference among the images. 相似文献
634.
Optically active polymers having chiral 2‐aminomethylpyrrolidine side chains have been newly synthesized by a radical homopolymerization of the corresponding protected acrylamide monomer and copolymerization with N‐isopropylacrylamide followed by deprotection. The resulting polymers were found to be thermoresponsive showing lower critical solution temperatures (LCSTs) at 27–65°C in their aqueous solutions. The pyrrolidine side chains of the resulting thermoresponsive polymer promoted aldol reaction between cyclohexanone and p‐nitrobenzaldehyde in water, and the reaction proceeded most smoothly at its LCST. Moreover, the diastereomeric ratio (syn : anti) of the aldol adducts obtained at the reaction at 40°C was 22 : 78, whereas the diastereomeric ratio (syn : anti) was 55 : 45 at 20°C. These results indicate that the pyrrolidine side chains catalyze the aldol reactions in the relatively hydrophobic field generated by the thermoresponsive polymer at its LCST. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
635.
A series of phosphoric acid (PA)‐doped blend membranes composed of block or random sulfonated polyimides (SPIs) and polybenzimidazole (PBI) were prepared with similar PA contents to investigate the influence of chemical structures of SPIs on proton conductivity. The proton conductivity of a PA‐doped blend membrane containing block‐type SPI, PA‐bSPI(80/20)/oPBI, was higher than that of the corresponding pristine block‐type SPI, PA‐SPI/PBI containing random‐type SPI and Nafion membranes over a wide temperature range, and reached 0.37 S cm?1 at 90 °C and 98% relative humidity. The PA‐bSPI(80/20)/oPBI membrane also showed distinct proton conductivity even at low humidity due to a new proton transport pathway among PA and sulfonic acid groups. Also, the novel PA‐doped blend membrane showed higher proton conductivity than Nafion at both above 100 °C and below 0 °C under low relative humidity conditions. © 2013 Society of Chemical Industry 相似文献
636.
The effect of an electrical charge on a dielectric wall on the deposition of charged aerosol particles is investigated. The dielectric walls used in the deposition experiments, poly(vinyl chloride) or polytetrafluoroethylene disks, are prepared to have known uniform surface charge distributions by using a corona discharge procedure. This avoids any effects on deposition caused by nonuniformity of the surface charge. The surface charge densities are based on measurements of the surface voltage in the center of the sample. Deposition experiments using a turbulently-mixed stirred tank demonstrate that particle deposition rates to the wall decrease as the sample's thickness increases or its relative permittivity decreases, even at a constant surface voltage. The electric field over the sample wall is calculated using the surface charge density, and the convection-diffusion equations describing particle deposition by Brownian and turbulent diffusion and electric migration are solved numerically. The calculated deposition rates agree well with those measured, indicating that quantitative prediction of particle deposition is possible if the surface charge, material, thickness and the effect of adjacent walls are taken into account. 相似文献
637.
Tamaki Hada Manabu Kanazawa Nanako Miyamoto Hengyi Liu Maiko Iwaki Yuriko Komagamine Shunsuke Minakuchi 《International journal of molecular sciences》2022,23(4)
Photopolymer resins are widely used in the production of dental prostheses, but their mechanical properties require improvement. We evaluated the effects of different zirconia filler contents and printing directions on the mechanical properties of photopolymer resin. Three-dimensional (3D) printing was used to fabricate specimens using composite photopolymers with 0 (control), 3, 5, and 10 wt.% zirconia filler. Two printing directions for fabricating rectangular specimens (25 mm × 2 mm × 2 mm) and disk-shaped specimens (φ10 mm × 2 mm) were used, 0° and 90°. Three-point bending tests were performed to determine the flexural strengths and moduli of the specimens. The Vickers hardness test was performed to determine the hardness of the specimens. Tukey’s multiple comparison tests were performed on the average values of the flexural strengths, elastic moduli, and Vickers hardness after one-way ANOVA (α = 0.05). The flexural strengths and elastic moduli at 0° from high to low were in the order of 0, 3, 10, and 5 wt.%, and those at 90° were in the order of 3, 0, 10, and 5 wt.% (p < 0.05). For 5 and 10 wt.%, no significant differences were observed in mechanical properties at 0° and 90° (p < 0.05). The Vickers hardness values at 0° and 90° from low to high were in the order of 0, 3, 5, and 10 wt.% (p < 0.05). Within the limits of this study, the optimal zirconia filler content in the photopolymer resin for 3D printing was 0 wt.% at 0° and 3 wt.% at 90°. 相似文献
638.
639.
Kazuhiko Toshimitsu Koutarou Nishikawa Wataru Haruki Shinichi Oono Manabu Takao Yuji Ohya 《热科学学报(英文版)》2008,17(4):375-380
The wind turbines with a flanged-diffuser shroud -so called "wind lens turbine"- are developed as one of high performance wind turbines by Ohya et al. In order to investigate the flow characteristics and flow acceleration, the paper presents the flow velocity measurements of a long-type and a compact-type wind turbines with a flanged-diffuser shroud by particle image velocimetry. In the case of the long type wind turbine, the velocity vec- tors of the inner flow field of the diffuser for turbine blades rotating and no blades rotating are presented at Rey- nolds number, 0.9x105. Fur~thermore the flow fields between with and without rotating are compared. Through the PIV measurement results, one can realize that the turbine blades rotating affects as suppress the disturbance and the flow separation near the inner wall of the diffuser. The time average velocity vectors are made on the av- erage of the instantaneous velocity data. There are two large vortices in downstream region of the diffuser. One vortex behind the flange acts as suck in wind to the diffuser and raise the inlet flow velocity. Another large vortex appears in downstream. It might be act as blockage vortex of main flow. The large blockage vortex is not clear in the instantaneous velocity vectors, however it exists clearly in the time average flow field. The flow field around the wind turbine with a compact-type flanged-diffuser shroud is also investigated. The flow pattern behind the flange of the compact-type turbine is the same as the long-type one. It means that the effect of flow acceleration is caused by the unsteady vortices behind the flange. The comparison with CFD and PIV results of meridional time-average streamlines after the compact-type diffuser is also presented. 相似文献
640.
Manabu Kuroboshi Kiyoshi Kanie Tamejiro Hiyama 《Advanced Synthesis \u0026amp; Catalysis》2001,343(3):235-250
The oxidative desulfurization‐fluorination reaction of organosulfur compounds using an N‐haloimide and a fluoride source is demonstrated to be an effective and mild fluorinaton method that allows us to synthesize in high yields with high chemoselectivity various types of gem‐difluoro compounds, trifluoromethyl‐substituted (hetero)aromatics, trifluoromethyl ethers, and N‐trifluoromethylanilines. Herein briefly summarized are the synthetic procedures as well as the scope and limitations of the reaction. The applicability of the reaction is demonstrated by the synthesis of a difluorinated glutamic acid and novel liquid‐crystalline materials having an N‐trifluoromethylamino, trifluoromethoxy, or 1,2‐difluoroethylene group. The fluorine‐containing liquid‐crystalline materials are compared with the corresponding non‐fluorinated materials in respect to phase transition behaviors and electro‐optical properties and shown to be suitable for not only super twisted nematic (STN) but also for thin film transistor (TFT)‐addressed liquid crystals displays. 1. Introduction 2. Fluorination Reactions 2.1 Fluorination of Sulfides and Thiols 2.2 Fluorination of Dithioacetals 2.3 Oxidative Desulfurization‐Fluorination of Dithioester and Orthothioester 2.4 Synthesis of Trifluoromethyl Ethers from Dithiocarbonates 2.5 Oxidative Desulfurization‐Fluorination of Thionesters and Thioncarbonates 2.6 Synthesis of Trifluoromethylamines from Dithiocarbamates 3. Synthesis and Electro‐Optical Properties of Novel Fluorine‐Containing Liquid Crystals 3.1 Synthesis and Electro‐Optical Properties of N‐Trifluoromethylamino‐Substituted Liquid Crystals 3.2 Syntheses and Electro‐Optical Properties of Liquid Crystals having Trifluoromethoxy Polar Functional Group 3.3 Synthesis and Properties of 3‐Substituted Phenyl Trifluoromethyl Ethers 3.4 Synthesis and Electro‐Optical Properties of Liquid Crystals with a vic‐Difluoro‐Olefinic Moiety 相似文献