Differential nanofiller cluster formations in dental adhesive systems

Nanofillers are added to dental adhesives to improve mechanical properties of the hybrid layer. Ethanol or water added to the demineralized dentin to improve adhesive infiltration may produce filler aggregation. OBJECTIVE: To assess the effect of 5 vol% water or ethanol addition on nanoparticles distribution in dental adhesives. METHODS: Six available commercial adhesives systems were selected: Clearfil SE Bond (CSE), Clearfil Protect Bond (CPB), FL‐Bond (FLB), Clearfil S3 (CS3), Bond Force (BF), One Up Bond F plus (OUB), and an experimental adhesive system without filler (EXP). Polymer films were obtained by adding 0 (control) or 5 vol% water or ethanol into the bonding resins. Preparations were light‐cured (40 s). Three specimens were analyzed for each mixture. Three phases and 3D images were taken from each specimen by means of an atomic force microscope in taping mode (TM/AFM). Cluster sizes and surface nanoroughness were assessed. RESULTS: Control specimens from CSE, FLB, OUB, and BF presented clusters. The addition of solvents lead to particles aggregation in tested bonding resins. Ethanol addition produced more aggregates, particularly in adhesives containing fluoraluminosilicate as fillers. CONCLUSIONS: Nanofillers aggregation occurred in all adhesive systems in presence of additional solvents. In general, aggregate sizes were higher after the addition of ethanol. Formed clusters size values are always above the dimensions of the spaces existing between the demineralized collagen fibers. Microsc. Res. Tech. 75:749–757, 2012. © 2011 Wiley Periodicals, Inc.     

Evolution of the thymus size in response to physiological and random events throughout life

During embryogenesis and in the early stages of life, the thymus is a crucial organ for the generation of the T cell repertoire. T cells are generated from hematopoietic stem cells already differentiated to precursor T cells in the bone marrow. These cells enter the thymus guided by chemotactic factors secreted by this organ. The complex maturation process takes place that ensures self-tolerance and homeostasis. Thymocytes that show autoreactivity do not leave the thymus, but rather die by apoptosis. The final percentage of mature T cells that survive to migrate from the thymus to the periphery is very low: at most 5%, under optimal conditions. The highest migration occurs in childhood and adulthood, at least in mice and humans; however, it declines throughout life and is minimal in the elderly. Under normal circumstances, the thymus commences involution soon after birth, and this involution correlates with the capacity to export mature T cells to the periphery. Hormones, cytokines, and neurotransmitters all play a role in this age-associated process, but the reasons for and mechanisms of this involution remain unknown. Apart from physiological conditions that change throughout life and govern age-related thymus evolution, random states and events provoked by intrinsic or extrinsic factors can induce either thymus involution, as in reversible transient thymic hypoplasias, or thymic hyperplasias. The age-associated involution, unlike transient involutions, follows a regular pattern for all individuals, though there are clear differences between the sexes. Nevertheless, even the age-associated involution seems to be reversible, raising the possibility of therapeutic strategies aimed at enhancing thymus function in the elderly.     

Different strategies for selective monoacylation of hexoaldoses in acetone

Experimental protocols for the selective production of 6-O-acylhexoaldose emulsifiers from precursor sugars (mannose, glucose, and galactose) and corresponding fatty acids are compared. The protocols employ an immobilized Candida antarctica lipase in a solvent (acetone) which is both easily eliminated and accepted by the European Economic Community for use as an extraction solvent in the manufacture of foods and/or food additives. This comparative study provides guidelines for selection of appropriate conditions for quantitative monoacylation of aldoses in acetone, on the basis of the solubilities of the precursor sugar and the monoester in acetone at different temperatures. Although relatively low temperatures (<40°C) favor precipitation of glucose monoesters, higher temperatures (e.g., 55°C) should be used to increase solubility of mannose and thus selectivity of the reaction leading to the mannose ester. Galactose is transformed with poor selectivity to the desired monoester by these procedures. Factors affecting the viability of these synthetic reactions in acetone are also discussed.     

Microstructural Design of Silicon Nitride with Improved Fracture Toughness: II, Effects of Yttria and Alumina Additives

Significant improvements in the fracture resistance of self-reinforced silicon nitride ceramics have been obtained by tailoring the chemistry of the intergranular amorphous phase. First, the overall microstructure of the material was controlled by incorporation of a fixed amount of elongated ß-Si₃N₄ seeds into the starting powder to regulate the size and fraction of the large reinforcing grains. With controlled microstructures, the interfacial debond strength between the reinforcement and the intergranular glass was optimized by varying the yttria-to-alumina ratio in the sintering additives. It was found that the steady-state fracture toughness value of these silicon nitrides increased with the Y:Al ratio of the oxide additives. The increased toughness was accompanied by a steeply rising R -curve and extensive interfacial debonding between the elongated ß-Si₃N₄ grains and the intergranular glassy phase. Microstructural analyses indicate that the different fracture behavior is related to the Al (and O) content in the ß´-SiAlON growth layer formed on the elongated ß-Si₃N₄ grains during densification. The results imply that the interfacial bond strength is a function of the extent of Al and Si bonding with N and O in the adjoining phases with an abrupt structural/chemical interface achieved by reducing the Al concentration in both the intergranular phase and the ß´-SiAlON growth layer. Analytical modeling revealed that the residual thermal expansion mismatch stress is not a dominant influence on the interfacial fracture behavior when a distinct ß´-SiAlON growth layer forms. It is concluded that the fracture resistance of self-reinforced silicon nitrides can be improved by optimizing the sintering additives employed.     

A probabilistic model for discretionary lane change proposals in highway driving situations

This contribution presents a novel probabilistic approach for the generation of discretionary lane change proposals with a focus on highway driving situations. The developed model is based on the quantification of the utility of driving lanes. It generates a lane change proposal if the current driving lane is unsatisfactory in the sense that the desired velocity of the automated vehicle is undershot because of a slow preceding vehicle. A driving simulator study was conducted to create a dataset for the optimization of the model parameters. The optimization goal is to accurately match the timings of the lane change intentions of all participants. Finally, the applicability of the model is shown on real data from a test vehicle.

     

Distillation column configurations in ammonia–water absorption refrigeration systems

In ammonia–water absorption refrigeration systems a purification process to reduce the water content in the vapour leaving the generator is required. During this process the water content in the vapour must be reduced to a minimum, otherwise it tends to accumulate in the evaporator and strongly deteriorates the efficiency of the system. The vapour purification can be carried out by partial condensation, by establishing a liquid–vapour counter flow or by combining both methods. In systems with partial condensation, the distillation column can be composed of one or more rectifiers using different cooling mediums, and the rectifying and stripping sections. In complete condensation systems only the rectifying and stripping sections can be used. Therefore different distillation column arrangements should be considered. This paper presents a study of several distillation column configurations for single stage ammonia–water absorption refrigeration systems with partial and complete condensation. In order to evaluate and compare the different configurations, a parameter that indicates the ratio of the ammonia vapour concentration increase in each part of the column to the total ammonia purification has been defined. The analysis has been based on the system COP. Finally the efficiency in each part of the column has been calculated to estimate its design requirements.     

MHP‐OSGi convergence: a new model for open residential gateways

Nowadays, we are living in a time of important technological changes that affect our lives at home and our communication with the outside world. Among them, the developments in Interactive Digital TV (IDTV) and the smart home field can be considered as particularly important. Related to the former, the new Set‐Top Boxes (STBs) are not only a decoder for digital television broadcast but also an entry point to the Information Society and a suitable platform to support the execution of interactive applications. With regards to the latter, the Residential Gateways (RGs) combine different network technologies to allow the connection of different electronics devices and appliances at home, not only with each other but also with the Internet. Since there is no widespread consensus about the configurations and functions of the RGs, we propose to coordinate the two aforementioned worlds by extending the functionality of STBs to become a RG. Our proposal consists of merging the Multimedia Home Platform (MHP), one of the main standard frameworks for IDTV, with Open Service Gateway Initiative (OSGi), the most widely used open platform to set up RGs. To overcome the radically different nature of these specifications—the function‐oriented MHP middleware and the service‐oriented OSGi framework—we define a new kind of application, coined as XbundLET. This application is able to bridge the gap between the two frameworks and make their interaction feasible. We also show how this proposal has the potential to enable the production of scenarios that cannot currently be put into practice in a natural way. Copyright © 2006 John Wiley & Sons, Ltd.     

Supporting scenario-based requirements engineering

Scenarios have been advocated as a means of improving requirements engineering yet few methods or tools exist to support scenario based RE. The paper reports a method and software assistant tool for scenario based RE that integrates with use case approaches to object oriented development. The method and operation of the tool are illustrated with a financial system case study. Scenarios are used to represent paths of possible behavior through a use case, and these are investigated to elaborate requirements. The method commences by acquisition and modeling of a use case. The use case is then compared with a library of abstract models that represent different application classes. Each model is associated with a set of generic requirements for its class, hence, by identifying the class(es) to which the use case belongs, generic requirements can be reused. Scenario paths are automatically generated from use cases, then exception types are applied to normal event sequences to suggest possible abnormal events resulting from human error. Generic requirements are also attached to exceptions to suggest possible ways of dealing with human error and other types of system failure. Scenarios are validated by rule based frames which detect problematic event patterns. The tool suggests appropriate generic requirements to deal with the problems encountered. The paper concludes with a review of related work and a discussion of the prospects for scenario based RE methods and tools     

Green pavements: reuse of plastic waste in asphalt mixtures

Nowadays, the disposal of plastic waste is an issue of major concern worldwide because of its considerable volume and growth. An option to tackle this problem is to recycle this waste. This alternative reduces the quantity of net discards, conserves both material and energy and provides a comparatively simple way to make a substantial reduction in the overall volume of solid waste. The purpose of this study is to investigate an environmentally friendly approach about the influence of recycling different percentages of urban and rural plastic waste by adding them in a dry process on an asphalt mixture, through a comparative laboratory study. The resulting mixtures are analyzed considering their volumetric parameters and the values from diverse laboratory mechanical tests. The performance tests include, Marshall stability, Marshall quotient, indirect tensile strength, fracture energy, resilient modulus, permanent deformation and creep compliance, which were carried out on unmodified and modified hot asphalt mixtures. The obtained results are presented and discussed in this paper showing that the reuse of recycled plastics in asphalt mixtures is a viable alternative that contributes to the reduction of plastic wastes as well as the protection of the environment.     

A robust constrained reference governor approach using linear matrix inequalities

The purpose of this paper is to examine and provide a solution to the output reference tracking problem for uncertain systems subject to input saturation. As well-known, input saturation and modelling errors are very common problems at industry, where control schemes are implemented without accounting for such problems. In many cases, it is sometimes difficult to modify the existing implemented control schemes being necessary to provide them with external supervisory control approaches in order to tackle problems with constraints and modelling errors. In this way, a cascade structure is proposed, combining an inner loop containing any proper controller with an outer loop where a generalized predictive controller (GPC) provides adequate references for the inner loop considering input saturations and uncertainties. Therefore, the contribution of this paper consists in providing a state space representation for the inner loop and using linear matrix inequalities (LMI) to obtain a predictive state-vector feedback in such a way that the input reference for the inner loop is calculated to satisfy robust tracking specifications considering input saturations. Hence, the final proposed solution consists in solving a regulation problem to a fixed reference value subjected to a set of constraints described by several LMI and bilinear matrix inequalities (BMI). The main contribution of the paper is that the proposed solution is a non-linear setpoint tracking approach, that is, it is allowed that the system goes into saturation facing the problem of setpoint tracking instead of regulating to the origin. An illustrative numerical example is presented.