Understanding of the annealing temperature impact on ion implanted bifacial n‐type solar cells to reach 20.3% efficiency

Ion implantation has the advantage of being a unidirectional doping technique. Unlike gaseous diffusion, this characteristic highlights strong possibilities to simplify solar cell process flows. The use of ion implantation doping for n‐type PERT bifacial solar cells is a promising process, but mainly if it goes with a unique co‐annealing step to activate both dopants and to grow a SiO₂ passivation layer. To develop this process and our SONIA cells, we studied the impact of the annealing temperature and that of the passivation layers on the electrical quality of the implanted B‐emitter and P‐BSF. A high annealing temperature (above 1000 °C) was necessary to fully activate the boron atoms and to anneal the implantation damages. Low J_0BSF (BSF contribution to the saturation current density) of 180 fA/cm² was reached at this high temperature with the best SiO₂ passivation layer. An average efficiency of 19.7% was reached using this simplified process flow (“co‐anneal process”) on large area (239 cm²) Cz solar cells. The efficiency was limited by a low FF, probably due to contaminations by metallization pastes. Improved performances were achieved in the case of a “separated anneals” process where the P‐BSF is activated at a lower temperature range. An average efficiency of 20.2% was obtained in this case, with a 20.3% certified cell. Copyright © 2014 John Wiley & Sons, Ltd.     

Analysis of delay mean and variance of collision-free WDM rings with segment recirculation of blocked traffic

In Tunable-Transmitter Fixed-Receiver (TT-FR)-based Wavelength Division Multiplexed (WDM) ring topologies, each node is provided with a dedicated wavelength (home channel) for reception, which must be shared by the upstream nodes willing to communicate with it. Thus, to avoid channel collisions, it is necessary to define a Medium Access Control (MAC) mechanism that arbitrates access to a given destination wavelength. This work proposes and analyses a simple MAC mechanism that avoids channel collisions by recirculating traffic on the upstream ring segment where congestion was detected. Essentially, whenever a given node has got any traffic to transmit, it must first block access to in-transit traffic, which is reflected back to the upstream node over a second optical fibre. Such blocked traffic is given a second chance to pass through the congested node after a round segment delay, thus making use of the ring topology as buffering units. This work analyses the performance operation of such a MAC protocol under two policies applied to recirculated traffic: (1) recirculation bypass and (2) recirculation store-and-forward.     

Exciton Formation Dynamics and Band-Like Free Charge-Carrier Transport in 2D Metal Halide Perovskite Semiconductors

Metal halide perovskite (MHP) semiconductors have driven a revolution in optoelectronic technologies over the last decade, in particular for high-efficiency photovoltaic applications. Low-dimensional MHPs presenting electronic confinement have promising additional prospects in light emission and quantum technologies. However, the optimisation of such applications requires a comprehensive understanding of the nature of charge carriers and their transport mechanisms. This study employs a combination of ultrafast optical and terahertz spectroscopy to investigate phonon energies, charge-carrier mobilities, and exciton formation in 2D (PEA)₂PbI₄ and (BA)₂PbI₄ (where PEA is phenylethylammonium and BA is butylammonium). Temperature-dependent measurements of free charge-carrier mobilities reveal band transport in these strongly confined semiconductors, with surprisingly high in-plane mobilities. Enhanced charge-phonon coupling is shown to reduce charge-carrier mobilities in (BA)₂PbI₄ with respect to (PEA)₂PbI₄. Exciton and free charge-carrier dynamics are disentangled by simultaneous monitoring of transient absorption and THz photoconductivity. A sustained free charge-carrier population is observed, surpassing the Saha equation predictions even at low temperature. These findings provide new insights into the temperature-dependent interplay of exciton and free-carrier populations in 2D MHPs. Furthermore, such sustained free charge-carrier population and high mobilities demonstrate the potential of these semiconductors for applications such as solar cells, transistors, and electrically driven light sources.     

Image segmentation towards new image representation methods

Very low bit-rate video coding has recently become one of the most important areas of image communication and a large variety of applications have already been identified. Since conventional approaches are reaching a saturation point, in terms of coding efficiency, a new generation of video coding techniques, aiming at a deeper “understanding” of the image, is being studied. In this context, image analysis, particularly the identification of objects or regions in images (segmentation), is a very important step. This paper describes a segmentation algorithm based on split and merge. Images are first simplified using mathematical morphology operators, which eliminate perceptually less relevant details. The simplified image is then split according to a quad tree structure and the resulting regions are finally merged in three steps: merge, elimination of small regions and control of the number of regions.     

The MIMO Iterative Waterfilling Algorithm

This paper considers the noncooperative maximization of mutual information in the vector Gaussian interference channel in a fully distributed fashion via game theory. This problem has been widely studied in a number of works during the past decade for frequency-selective channels, and recently for the more general multiple-input multiple-output (MIMO) case, for which the state-of-the art results are valid only for nonsingular square channel matrices. Surprisingly, these results do not hold true when the channel matrices are rectangular and/or rank deficient matrices. The goal of this paper is to provide a complete characterization of the MIMO game for arbitrary channel matrices, in terms of conditions guaranteeing both the uniqueness of the Nash equilibrium and the convergence of asynchronous distributed iterative waterfilling algorithms. Our analysis hinges on new technical intermediate results, such as a new expression for the MIMO waterfilling projection valid (also) for singular matrices, a mean-value theorem for complex matrix-valued functions, and a general contraction theorem for the multiuser MIMO watefilling mapping valid for arbitrary channel matrices. The quite surprising result is that uniqueness/convergence conditions in the case of tall (possibly singular) channel matrices are more restrictive than those required in the case of (full rank) fat channel matrices. We also propose a modified game and algorithm with milder conditions for the uniqueness of the equilibrium and convergence, and virtually the same performance (in terms of Nash equilibria) of the original game.     

A 65nm CMOS Ramp Generator Design and its Application Towards a BIST Implementation of the Reduced-Code Static Linearity Test Technique for Pipeline ADCs

This work presents an efficient on-chip ramp generator targeting to facilitate the deployment of Built-In Self-Test (BIST) techniques for ADC static linearity characterization. The proposed ramp generator is based on a fully-differential switched-capacitor integrator that is conveniently modified to produce a very small integration gain, such that the ramp step size is a small fraction of the LSB of the target ADC. The proposed ramp generator is employed in a servo-loop configuration to implement a BIST version of the reduced-code linearity test technique for pipeline ADCs, which drastically reduces the volume of test data and, thereby, the test time, as compared to the standard test based on a histogram. The demonstration of the pipeline ADC BIST is carried out based on a mixture of transistor-level and behavioral-level simulations that employ actual production test data.     

Proton Transport in Electrospun Hybrid Organic–Inorganic Membranes: An Illuminating Paradox

Chemistry and processing have to be judiciously combined to structure the membranes at various length scales to achieve efficient properties for polymer electrolyte membrane fuel cell to make it competitive for transport. Characterizing the proton transport at various length and space scales and understanding the interplays between the nanostructuration, the confinement effect, the interactions, and connectivity are consequently needed. The goal here is to study the proton transport in multiscale, electrospun hybrid membranes (EHMs) at length scales ranging from molecular to macroscopic by using complementary techniques, i.e., electrochemical impedance spectroscopy, pulsed field gradient‐NMR spectroscopy, and quasielastic neutron scattering. Highly conductive hybrid membranes (EHMs) are produced and their performances are rationalized taken into account the balances existing between local interaction driven mobility and large‐scale connectivity effects. It is found that the water diffusion coefficient can be locally decreased (2 × 10^?6 cm² s^?1) due to weak interactions with the silica network, but the macroscopic diffusion coefficient is still high (9.6 × 10^?6 cm² s^?1). These results highlight that EHMs have slow dynamics at the local scale without being detrimental for long‐range proton transport. This is possible through the nanostructuration of the membranes, controlled via processing and chemistry.     

Southern spanish windmills: Technological aspects

This paper shows the study carried out in a doctoral thesis about windmills in south-east Spain, in the area of Campo de Níjar in the province of Almeria. It intends to pay homage to Spanish windmills as a way of commemorating the fourth centenary of the masterwork of Spanish Literature, ‘Don Quixote’ in which the silhouette of the windmill is a pervading symbol.Wheat milling has been an important factor in the socio-economic development of rural Spain for centuries. The type of mill used depended on the energy resources available, wind or water. In the Campo de Níjar (Almeria, Andalusia, Spain), wind is the principal energy source, and therefore, windmills were widely used, as in other areas of Spain. In this paper, we study the technological conditions of these old windmills, we carry out a wind evaluation of the area, and we calculate the power and momentum of these windmills with a discussion of the results found.