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21.
Sarah Wittmann;M. Mangir Murshed;Lars Schumacher;Aylin Koldemir;Rainer Pöttgen;Thorsten M. Gesing; 《Journal of the American Ceramic Society》2024,107(9):6465-6476
The susceptibility of either oxidation into Sn(IV) or disproportionation into Sn(IV) and Sn(0) limits the study of metal tin-(II)-borate ceramics. We report mullite-type SnCrBO4 and SnVBO4 synthesized in sealed quartz tubes by conventional solid-state method. X-ray powder diffraction data Rietveld refinements confirm that both compounds are isostructural to PbMBO4 phases for M = Al, Ga, Cr, Mn, and Fe. The end-members show a complete miscibility within the Sn(Cr1−xVx)BO4 solid solution. Both the microstructural (average crystallite size, microstrain, and degree of crystallinity) and crystal structural (metric parameters, bond lengths, polyhedral volume, and polyhedral distortion) parameters are observed with respect to the compositional x-value. The stereochemical activity of the 5 s2 lone electron pairs of Sn2+ cations has been measured by using the Wang–Liebau eccentricity parameter. The structural features are complemented by 119Sn Mössbauer, Raman, and Fourier-transformed infrared spectroscopy. The 119Sn Mössbauer isomer shifts and the quadrupole splitting values confirm the SnO4 coordination and an Sn(II) valence state. The electronic band gap has been calculated from the UV/Vis diffuse reflectance spectra, which slightly increases with successive decrease of the cationic radius from V to Cr. Temperature-dependent inverse DC magnetic susceptibility suggests that SnCrBO4 and SnVBO4 are antiferromagnetic and ferromagnetic (FM) with a Néel temperature of 17.2(1) K and a Curie temperature of 29.8(1) K, respectively. Alike the end-member SnVBO4, Sn(Cr0.5V0.5)BO4 is also found to be a rare FM insulator. The thermal stability decreases with increasing vanadium content in the solid solution. 相似文献
22.
Pectin‐[(3‐acrylamidopropyl) trimethylammonium chloride‐co‐acrylic acid] hydrogel has been prepared from the aqueous blend solution of pectin, (3‐acrylamidopropyl) trimethylammonium chloride (APTAC), and acrylic acid (AAc) by applying gamma radiation of different doses (1–25 kGy) from 60Co gamma source. The hydrogels were characterized by equilibrium swelling, Fourier transform infrared, differential scanning calorimetry, and scanning electron microscopy. The hydrogels were used in multielement adsorption and it was found that pectin‐(APTAC‐co‐AAc) gel is highly selective toward silver (I) ion among 27 metal ions. The data obtained from equilibrium adsorption studies were fitted in Langmuir and Freundlich adsorption isotherm models and model parameters evaluated. The maximum adsorption capacity of pectin‐(APTAC‐co‐AAc) gel was found to be 67.6413 mg/g of dry gel at sample volume of 25 mL. The kinetic data were tested using pseudo‐first order and pseudo‐second order kinetic models and different adsorption diffusion models such as film diffusion and intra‐particle diffusivity model. Thiourea solution was used for desorption of adsorbed metal ions from the hydrogel. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45906. 相似文献
23.
Md. Imran Hossain M. Mangir Murshed Thorsten M. Gesing 《Journal of the American Ceramic Society》2023,106(10):6268-6278
Sillenite-type ceramics are non-centrosymmetric phases of ongoing research interest because of their structural defects and optoelectronic properties. We report a series of sillenite compounds with a general composition Bi12(Bi3+4/5−3xIn3+5x□1/5−2x)O19.2+3x□0.8−3x for x = 0.03–0.27 to understand how the crystal–physicochemical properties change with a successive filling of empty Bi3+ positions in the tetrahedral site by In3+ cation. Conventional solid-state synthesis method is used to prepare the microcrystalline samples. Each sample is characterized by X-ray diffraction, Raman, UV/Vis diffuse reflectance spectroscopy, and thermogravimetry (TG/DSC). X-ray powder data Rietveld refinement reveals that phase-pure samples can be obtained for x = 0.03–0.08 in the space group I23. Appearance of starting In2O3 as minor phases with the final products for 0.10 < x < 0.27 suggests for xmax = 0.08. The successive decrease of the lattice parameter indicates the incorporation of smaller In3+ cations in the structure. The effect of the lone electron pairs of Bi3+ and the structural cation vacancies lead to the modification of the interatomic bond lengths. At least one Raman active phonon mode shows hardening for decreasing cation vacancy concentration in the system. The bandgap energy increases with increasing indium content. An additional absorption band at lower energy for x = 0.03–0.08 complements the theoretical study, which completely disappears for x > 0.08. The stronger In–O bonds play pivotal roles in the thermal stability of the phases studied by TGA/DSC analysis. 相似文献
24.
Abstract and Key Results
相似文献
• | We examine the impact of NAFTA on FDI into the region and the individual member countries. The literature on FDI and regional economic integration suggests that the implementation of NAFTA makes the entire area a more desirable investment location. However, insofar as individual member countries are concerned, the a priori effects are not necessarily unambiguously positive. |
• | We find that the implementation of NAFTA had a generally positive effect on inward FDI into the entire region, with the benefits accruing only to the United States and Canada. |
25.
Sarah Wittmann Mohammad Mangir Murshed Vitaliy Bilovol Aylin Koldemir Rainer Pöttgen Ulla Gro Nielsen Thorsten Michael Gesing 《Journal of the American Ceramic Society》2024,107(2):1302-1314
Metal tin-(II)-borates are rarely studied mainly due to the susceptibility of either oxidation into tin(IV) or disproportionation into elemental tin(0) and tin(IV). We report mullite-type SnAlBO4 and SnGaBO4 ceramics produced by conventional solid-state synthesis in sealed quartz tubes at low pressure of 10–7 MPa. Both compounds are isostructural to PbAlBO4 as confirmed by Rietveld refinements of powder X-ray data. The crystal structures are highly influenced by the stereochemical activity of the 5s2 lone electron pair of the Sn2+ cation measured by the Wang–Liebau eccentricity parameter. To further consolidate the structural features 119Sn Mössbauer, solid state NMR, Raman, IR and UV/vis spectroscopic measurements are performed. The 119Sn Mössbauer isomer shifts and the quadrupole splitting values confirm the SnO4 coordination and Sn(II) valence states. Solid state 11B, 27Al and 119Sn NMR spectra provided insights into the local crystal-chemical environment. The vibrational properties are discussed from group theoretical analysis to mode assignments. SnAlBO4 and SnGaBO4, respectively, possess an electronic band gap of 3.73(9) and 3.21(4) eV calculated from the diffuse reflectance UV/Vis spectra. 相似文献
26.
Konrad Schmitt Rabindra Bhatta Manohar Chamana Mahtab Murshed Ilham Osman Stephen Bayne Luciane Canha 《Journal of Modern Power Systems and Clean Energy》2023,11(1):3-16
Industrial, commercial, and residential facilities are progressively adopting automation and generation capabilities. By having flexible demand and renewable energy generation, traditional passive customers are becoming active participants in electric power system operations. Through profound coordination among grid operators and active customers, the facilities’ capability for demand response(DR) and distributed energy resource(DER) management will be valuable asset for ancillary services(ASs). To comply with the increasing demand and flexible energy, utilities urgently require standards, regulations, and programs to efficiently handle load-side resources without trading off stability and reliability. This study reviews different types of customers’ flexibilities for DR, highlighting their capabilities and limitations in performing local ancillary services(LASs), which should benefit the power grid by profiting from it through incentive mechanisms. Different financial incentives and techniques employed around the world are presented and discussed. The potential barriers in technical and regulatory aspects are successfully identified and potential solutions along with future guidance are discussed. 相似文献
27.
Néstor Novoa Juan Pablo Soto Rodrigo Henríquez Carolina Manzur David Carrillo Jean-René Hamon 《Journal of Inorganic and Organometallic Polymers and Materials》2013,23(6):1247-1254
This paper discloses two new side-chain metallopolymers containing an unsymmetrical organometallic Schiff base complex of Ni(II) linked to a polymethylmethacrylate (PMMA) matrix. The neutral ferrocene substituted Schiff base complex 1, Ni{CpFe(η5-C5H4)-C(O)CH=C(CH3)N–o-C6H4N=CH-(2-O,5-OH-C6H3)} where (Cp = η5-C5H5), was synthesized via template reaction by condensation of the tridentate half-unit metalloligand Fc-C(O)CH=C(CH3)-N(H)-o-C6H4NH2 (Fc = ferrocenyl = CpFe(η5-C5H4)) with 2,5-dihydroxybenzaldehyde in the presence of nickel(II) acetate tetrahydrate. The binuclear Schiff base complex of Ni(II) containing an aromatic free hydroxyl group was reacted under basic conditions with PMMA to afford, upon trans-esterification reaction, metallopolymers 2 (complex 1 monomeric unit/PMMA = 1/5) and 3 (complex 1 monomeric unit/PMMA = 1/3). Elemental analysis, FT-IR, 1H and 13C NMR spectroscopies, and cyclic voltammetry were utilized to characterize the newly synthetized compounds. Surface morphology of the metallopolymer film of 2 was studied using atomic force microscopy. 相似文献
28.
Angel Manzur 《应用聚合物科学杂志》2008,108(3):1574-1581
The double yield phenomenon was studied using numerous specimens uniaxially deformed up to different elongations of linear low‐density polyethylene samples. Extruded samples prepared under different conditions were deformed at 1, 10, and 50 mm/min. The crystallinity under stressed state was calculated using the wide‐angle X‐ray scattering technique. The crystallinity degrees of the samples without deformation were less than 55%. This parameter, as a function of the elongation, presented a multistep behavior. An increment before the first yield point and a decrement after this point; then, at higher elongation values around the second yield point, another decrement and an abrupt increment. The behavior was more notorious at intermediate and lower strain rates. The results around the second yield point were interpreted in terms of melting of the less perfect crystallites followed by a recrystallization process. These experimental findings show that the partial melting–recrystallization process is one of the main mechanisms of the double yield phenomenon. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
29.
Novel velocity and call duration support for QoS provision in mobile wireless networks 总被引:2,自引:0,他引:2
This article presents a novel mobility-based resource reservation and call admission control scheme that is applicable to any real wireless multimedia network. The scheme exploits three key mobility parameters - the position, direction, and speed of a mobile unit - together with the duration of a particular call to accurately estimate the cell visiting probability in order to identify a shadow cluster of cells the unit is most likely to visit. Each cell in the cluster reserves resources for an estimated time interval, which is adapted depending on the aggregated probability of all active units visiting a particular cell. Simulation results confirm the superiority of the new scheme over the existing predictive mobility support scheme in terms of three QoS parameters: call blocking rate, call dropping rate, and channel utilization. 相似文献
30.
D Nauffal Manzur R Menéndez Villanueva MJ Cremades Romero 《Canadian Metallurgical Quarterly》1997,33(5):220-224
Our objective was to investigate possible factors implicated in either early death from or scintigraphic resolution of pulmonary embolism. To that end we conducted a retrospective study of 116 patients with either a high likelihood of pulmonary thromboembolism (PTE) diagnosed by scintiscan or with a fair probability of PTE by scintiscan accompanied by a positive phlebograph. The images were taken upon admission, at 7 days, 10 days and 6 months. The factors analyzed were age, sex, trauma, immobility, surgery, obesity, hemiplegia, venous insufficiency, cardiopulmonary disease, neoplasia, chest X-ray and ECG alterations, D(A-a)O2 and size of perfusion defects upon admission and 7 to 10 days later. We performed single-variable analyses and multiple logical regression analyses using perfusion defect at 6 months as the dependent variable. The early mortality rate (13%) was higher in patients with neoplasms, a larger alveolar-arterial index and greater perfusion defects upon admission. Scintiscans became normal in 28%. Multivariate analysis to predict total or partial resolution at 6 months showed that size of perfusion defects at 7 to 10 days was the best predictive factor. A cutoff point was calculated by analyzing the ROC for this factor. Thus, when the defect at 7 to 10 days was equal to or greater than 1 segment, the probability of residual defects remaining after 6 months was twice as great (sensitivity 83%, specificity 57%). In conclusion, early death was more likely in PTE patients with neoplasms, larger defects upon admission and greater alveolar-arterial difference. Scintigrams showed resolution 6 months after admission in 28%. The size of perfusion defects 7 to 10 days after admission was the factor that best predicted total of partial resolution at 6 months. 相似文献