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This paper investigates the evaluation of the sensitivity, with respect to tangential perturbations of the singular point, of boundary integrals having either weak or strong singularity. Both scalar potential and elastic problems are considered. A proper definition of the derivative of a strongly singular integral with respect to singular point perturbations should accommodate the concomitant perturbation of the vanishing exclusion neighbourhood involved in the limiting process used in the definition of the integral itself. This is done here by esorting to a shape sensitivity approach, considering a particular class of infinitesimal domain perturbations that ‘move’ individual points, and especially the singular point, but leave the initial domain globally unchanged. This somewhat indirect strategy provides a proper mathematical setting for the analysis. Moreover, the resulting sensitivity expressions apply to arbitrary potential-type integrals with densities only subjected to some regularity requirements at the singular point, and thus are applicable to approximate as well as exact BEM solutions. Quite remarkable is the fact that the analysis is applicable when the singular point is located on an edge and simply continuous elements are used. The hypersingular BIE residual function is found to be equal to the derivative of the strongly singular BIE residual when the same values of the boundary variables are substituted in both SBIE and HBIE formulations, with interesting consequences for some error indicator computation strategies. © 1998 John Wiley & Sons, Ltd.  相似文献   
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Herein we report the first kinetic study of the intrachannel wall phase-transition of amorphous titania to nanocrystalline anatase for periodic mesoporous titania thin films, monitored by time-resolved in situ high-temperature X-ray diffraction. Structural transformations associated with the phase transition are further probed by high-resolution scanning electron microscopy and transmission electron microscopy. The model found to be most consistent with the kinetic data involves 1D diffusion-controlled growth of nanocrystalline anatase within the spatial confines of the channel walls of the mesostructure. The observation of anisotropic, rod-shaped anatase nanocrystals preferentially aligned along the channel axis implies that the framework of the liquid-crystal-templated mesostructure guides the crystal growth.  相似文献   
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Spectroscopic Ellipsometry is a fast, non‐destructive and reliable method for characterizing thin films, based on interaction between incident light and a multilayer system. For our investigations, light in the visible spectral range has been used to characterize protective carbon coatings with thicknesses of 2‐7nm on magnetic hard disks. The specific disk layer stack has been described with an adequate one‐layer model. With regard to an accurate analysis of the covering carbon coating a reproducible procedure for determining the underlying metallic material has been developed. The measured ellipsometric parameters (ψ, Δ) display a linear dependence on carbon film thickness which shows an appropriate application of the used model down to a thickness of 2 nm. By means of simulation calculations, criteria for the selection of optimized wavelengths with respect to film characterization has been established. Furthermore, an increasing extinction coefficient κ with rising nitrogen content in the carbon coating could be stated. Apparent time instabilities in the determination of layer thickness d and extinction coefficient κ of the carbon film could be explained as due to adsorption processes on the surface.  相似文献   
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Animal studies indicate that insulin resistance and glucose intolerance leading to dyslipidemia in uremic rats are associated with increased cytosolic calcium ([Ca++ i]). The resistance and intolerance are reversed with verapamil, but recur after its discontinuation. This finding suggests that hyperparathyroid‐induced [Ca ++ i] increase is responsible for the metabolic derangement. We retrospectively examined, over a 12‐year period, the effects of factors that lower [Ca ++i] on total serum cholesterol and triglycerides in 332 hemodialysis (HD) patients. Because the study was retrospective, detailed lipid profiles were not available. We therefore relied on morbidity and mortality outcomes related to atherosclerotic vascular disease. Patients with diabetes mellitus were excluded, because their dyslipidemia and vascular disease are mediated via a different mechanism. Four groups emerged: group I [high parathormone (PTH) in the absence of calcium channel blockers (CCBs), n = 107], representing the highest [Ca++ i]; group II (high PTH in the presence of CCBs, n = 76) and group III (lower PTH in the absence of CCBs, n = 66), representing intermediate [Ca ++ i]; and group IV (lower PTH in the presence of CCBs, n = 83) representing the lowest [Ca ++i]. The theoretically lower [Ca ++ i] was achieved via CCB therapy or lower PTH, or both. The mean serum cholesterol in group I was 322 ± 24 mg/dL and the level of triglycerides was 398 ± 34 mg/dL. Group II had mean serum cholesterol of 196 ± 16 mg/dL and triglycerides of 157 ± 17 mg/dL. Group III had a mean serum cholesterol of 202 ± 19 mg/dL and triglycerides of 160 ± 15 mg/dL. Group IV had a mean serum cholesterol of 183 ± 9 mg/dL and triglycerides of 94 ± 6 mg/dL. The differences in cholesterol and triglyceride levels among four groups were significant (p < 0.001) by one‐way analysis of variance (ANOVA). The incidence of cardiovascular morbidity and mortality events was 61% in group I, 24% in group II, 28% in group III, and 18% in group IV (χ 2 = 47.7, p < 0.001). We conclude that, in non diabetic HD patients, hyperparathyroidism, especially in the absence of CCBs, is associated with severe dyslipidemia and increased risk of cardiovascular morbidity and mortality. Dyslipidemia may be related to a hyperparathyroid‐induced increase in cytosolic calcium [Ca++i]. Lowering [Ca++i] by decreasing PTH or by blocking calcium entry into cells (via CCBs), or both, is associated with less dyslipidemia and improved long‐term cardiovascular morbidity and mortality. Prospective randomized studies, with actual measurement of [Ca ++i], are needed to verify the results of this study.  相似文献   
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Conducted a reliability and validity study of the French version of E. L. Deci and R. M. Ryan's (1985) General Causality Orientations Scale (GCOS), which measures the extent to which people are oriented toward the autonomy, control, and impersonal aspects of the initiation and regulation of behavior. Findings support the psychometric and construct validity of the French version of the GCOS; suggestions for its use in French-Canadian psychological research are discussed. (English abstract) (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
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Procedures based on group representation theory, allowing the exploitation of geometrical symmetry in symmetric Galerkin BEM formulations, are investigated. In particular, this investigation is based on the weaker assumption of partial geometrical symmetry, where the boundary has two disconnected components, one of which is symmetric; e.g. this can be very useful for defect identification problems. The main development is expounded in the context of 3D Neumann elastostatic problems, considered as model problems; and then extended to SGBIE formulations for Dirichlet and/or scalar problems. Both Abelian and non‐Abelian finite symmetry groups are considered. The effectiveness of the present approach is demonstrated through numerical examples, where both partial and complete symmetry are considered, in connection with both Abelian and non‐Abelian symmetry groups. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
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