Phase-object detection by use of double-exposure fringe-modulated speckle patterns

We study the properties of a double-exposure image specklegram of a diffuse object obtained by use of a double-aperture pupil. A phase object is placed in front of one aperture during the first or the second exposure. Also, it is assumed that a uniform displacement of the diffuser between exposures is produced. The recorded specklegram is coherently illuminated and analyzed by Fourier transform operations. The average intensity distribution and the interference fringe visibility in the Fourier plane are investigated. On this basis, an alternative interference technique to detect phase objects is proposed.     

Initial in-orbit results from a low-cost atmospheric ozone monitor operating on board the FASat-Bravo microsatellite

In 1994, a collaborative programme was set up between the University of Surrey and the Chilean Air Force to design and build a low-cost 50 kg microsatellite with instrumentation capable of monitoring the distribution and concentration of stratospheric ozone, particularly over Chilean territory. This resulted in the joint design and development of the ozone-layer monitoring experiment (OLME), which was flown on board the resultant FASat-Bravo microsatellite, launched in July 1998 into an 820 km altitude Sun-synchronous orbit. The nadir-pointing OLME measures the solar ultraviolet light backscattered from the atmosphere in four spectral bands. From these raw radiometric data, total column ozone concentrations can be deduced. Since the launch, a series of high-spatial-resolution measurements have been made over Chilean scientific stations, while continuous low-spatial-resolution measurements have been used to provide global coverage. To date, the University of Surrey has concentrated on these global measurements, and has used a simplified ozone retrieval algorithm to check the results qualitatively against ozone maps produced by NASA's Earth Probe Total Ozone Mapping Spectrometer (TOMS) payload. These initial results look promising, with apparently good correlation between the two datasets. A novel, more-complex retrieval algorithm has been applied to the high-resolution data, and early results have shown agreement with the TOMS.     

The EuQoS system: a solution for QoS routing in heterogeneous networks [Quality of Service based Routing Algorithms for Heterogeneous Networks]

EuQoS is the acronym for "end-to-end quality of service support over heterogeneous networks", which is a European research project aimed at building an entire QoS framework, addressing all the relevant network layers, protocols, and technologies. This framework, which includes the most common access networks (xDSL, UMTS, WiFi, and LAN) is being prototyped and tested in a multidomain scenario throughout Europe, composing what we call the EuQoS system. In this article we present the novel QoS routing mechanisms that are being developed and evaluated in the framework of this project. The preliminary performance results validate the design choices of the EuQoS system, and confirm the potential impact this project is likely to have in the near future     

Modelling gross primary production of a tropical semi-deciduous forest in the southern Amazon Basin

Semi-deciduous forest in the Amazon Basin is sensitive to temporal variation in surface water availability that can limit seasonal rates of leaf and canopy gas exchange. We estimated the seasonal dynamics of gross primary production (GPP) over 3 years (2005–2008) using eddy covariance and assessed canopy spectral reflectance using MODIS imagery for a mature tropical semi-deciduous forest located near Sinop, Mato Grosso, Brazil. A light-use efficiency model, known as the Vegetation Photosynthesis Model (VPM), was used to estimate seasonal and inter-annual variations in GPP as a function of the enhanced vegetation index (EVI), the land surface water index (LSWI), and local meteorology. Our results indicate that the standard VPM was incapable of reproducing the seasonal variation in GPP, primarily because the model overestimated dry-season GPP. In the standard model, the scalar function that alters light-use efficiency (ε_g) as a function of water availability (W_scalar) is calculated as a linear function of the LSWI derived from MODIS; however, the LSWI is negatively correlated with several measures of water availability including precipitation, soil water content, and relative humidity (RH). Thus, during the dry season, when rainfall, soil water content, and RH are low, LSWI, and therefore, W_scalar, are at a seasonal maximum. Using previous research, we derived new functions for W_scalar based on time series of RH and photosynthetic photon flux density (PPFD) that significantly improved the performance of the VPM. Whether these new functions perform equally well in water stressed and unstressed tropical forests needs to be determined, but presumably unstressed ecosystems would have high cloud cover and humidity, which would minimize variations in W_scalar and GPP to spatial and/or temporal variation in water availability.     

Determination of water content in Brazilian honeybee-collected pollen by Karl Fischer titration

This paper assesses the performance of a chemical method based on the Karl Fischer titration to determine the water content in samples of dehydrated honeybee-collected pollen. The following analysis parameters were investigated: extraction temperature, particle size, reaction time, and weight of a dried pollen sample. After optimization, the method was used to determine the water content of 154 samples of dried honeybee-collected pollen from different geographical regions of Brazil. The Karl Fischer titration method, performed using a solvent mixture of methanol and n-octanol (1:1 v/v) at 50 °C on pollen particles 600 μm in size produced the best results. Mean values for water content of the 154 samples of dried honeybee-collected pollen from 12 Brazilian regions ranged from 3% to 9%.     

Computer simulation and SERR detection of cytochrome c dynamics at SAM-coated electrodes

In this paper we present a combined experimental and theoretical study of the heterogeneous electron transfer reaction of cytochrome c electrostatically adsorbed on metal electrodes coated with monolayers of 6-mercaptohexanoic acid. Molecular dynamics simulations and pathways calculations show that adsorption of the protein leads to a broad distribution of orientations and, thus, to a correspondingly broad distribution of electron transfer rate constants due to the orientation-dependence of the electronic coupling parameter. The adsorbed protein exhibits significant mobility and, therefore, the measured reaction rate is predicted to be a convolution of protein dynamics and tunnelling probabilities for each orientation. This prediction is confirmed by time-resolved surface enhanced resonance Raman which allows for the direct monitoring of protein (re-)orientation and electron transfer of the immobilised cytochrome c. The results provide a consistent explanation for the non-exponential distance-independence of electron transfer rates usually observed for proteins immobilized on electrodes.     

Development of Low-Cost Remote-Control Generators Based on BiTe Thermoelectric Modules

This paper presents a new thermogenerator based on moderate-temperature (up to 175°C) BiTe modules available on the open market. Despite this handicap relative to commercial thermogenerators based on high-temperature proprietary-technology PbBi modules (up to 560°C), this new design may become economically competitive due to its innovative thermal sink. Our thermal sink is based on a free-convection water loop built with standard tubing and household hot-water radiators, leading to a more practical, modular design. So, the specific cost of about 55,000 USD/kW obtained for this 120-W prototype is improved to 33,000 USD/kW for a 1-kW unit, which represents about half the price of commercial thermogenerators. Moreover, considering recently launched BiTe modules (that withstand up to 320°C), our proposition could have an even more favorable outlook.