A Protein-Adsorbent Hydrogel with Tunable Stiffness for Tissue Culture Demonstrates Matrix-Dependent Stiffness Responses

Although tissue culture plastic has been widely employed for cell culture, the rigidity of plastic is not physiologic. Softer hydrogels used to culture cells have not been widely adopted in part because coupling chemistries are required to covalently capture extracellular matrix (ECM) proteins and support cell adhesion. To create an in vitro system with tunable stiffnesses that readily adsorbs ECM proteins for cell culture, a novel hydrophobic hydrogel system is presented via chemically converting hydroxyl residues on the dextran backbone to methacrylate groups, thereby transforming non-protein adhesive, hydrophilic dextran to highly protein adsorbent substrates. Increasing methacrylate functionality increases the hydrophobicity in the resulting hydrogels and enhances ECM protein adsorption without additional chemical reactions. These hydrophobic hydrogels permit facile and tunable modulation of substrate stiffness independent of hydrophobicity or ECM coatings. Using this approach, it is shown that substrate stiffness and ECM adsorption work together to affect cell morphology and proliferation, but the strengths of these effects vary in different cell types. Furthermore, it is revealed that stiffness-mediated differentiation of dermal fibroblasts into myofibroblasts is modulated by the substrate ECM. The material system demonstrates remarkable simplicity and flexibility to tune ECM coatings and substrate stiffness and study their effects on cell function.     

Modelling of Drop Size Distribution of Rain from Rain Rate and Attenuation Measurements at Millimeter and Optical Wavelengths

This paper describes a technique for modelling of rain drop size distributions at Calcutta in terms of negative exponential function, from the measurements of rain rate and attenuation over a dual wavelength LOS link at millimeter and optical frequencies. The DSD model obtained is then used to determine the attenuation at 94 GHz, for comparison with experimentally obtained attenuation at 94 GHz. This is also compared with the attenuation calculated by considering other experimentally obtained DSD models. The best fit negative exponential distribution function (modified M-P model) is presented along with some other experimentally obtained and reference models.     

Composite Nanostructures of TiO2 and ZnO for Water Splitting Application: Atomic Layer Deposition Growth and Density Functional Theory Investigation

The commercialization of solar fuel devices requires the development of novel engineered photoelectrodes for water splitting applications which are based on redundant, cheap, and environmentally friendly materials. In the current study, a combination of titanium dioxide (TiO₂) and zinc oxide (ZnO) onto nanotextured silicon is utilized for a composite electrode with the aim to overcome the individual shortcomings of the respective materials. The properties of conformal coverage of TiO₂ and ZnO layers are designed on the atomic scale by the atomic layer deposition technique. The resulting photoanode shows not only promising stability but also nine times higher photocurrents than an equivalent photoanode with a pure TiO₂ encapsulation onto the nanostructured silicon. Density functional theory calculations indicate that segregation of TiO₂ at the ZnO surfaces is favorable and leads to the stabilization of the ZnO layers in water environments. In conclusion, the novel designed composite material constitutes a promising base for a stable and effective photoanode for the water oxidation reaction.     

Performance Evaluation of Packet Mobile Communications through Level Crossing Analysis

In this paper the performance of a packet mobile radio network is studied inthe presence of shadow fading outage intervals.Under quite general assumptions for the medium access protocol,the probability mass function of the sequence of packets that may be lostdue to an outage interval is derived. It is seen that long sequences of lostpackets are likely to occur for typical values of the mobile speed andshadowing correlation parameters.For delay constrained sources, e.g., voice, the analysis is mainly focused atderiving the probability function of the sequence of dropped packetsand the probability of dropping. For data sources, the delay statistic isalso derived. In the latter case, the effect of finite buffer length isaddressed. Simulation is used to verify the accuracy of approximations introduced in the analysis.     

Waterproof,Breathable, and Antibacterial Self‐Powered e‐Textiles Based on Omniphobic Triboelectric Nanogenerators

Multifunctional electronic textiles (e‐textiles) incorporating miniaturized electronic devices will pave the way toward a new generation of wearable devices and human–machine interfaces. Unfortunately, the development of e‐textiles is subject to critical challenges, such as battery dependence, breathability, satisfactory washability, and compatibility with mass production techniques. This work describes a simple and cost‐effective method to transform conventional garments and textiles into waterproof, breathable, and antibacterial e‐textiles for self‐powered human–machine interfacing. Combining embroidery with the spray‐based deposition of fluoroalkylated organosilanes and highly networked nanoflakes, omniphobic triboelectric nanogenerators (R^F‐TENGs) can be incorporated into any fiber‐based textile to power wearable devices using energy harvested from human motion. R^F‐TENGs are thin, flexible, breathable (air permeability 90.5 mm s^?1), inexpensive to fabricate (<0.04$ cm^?2), and capable of producing a high power density (600 µW cm^?2). E‐textiles based on R^F‐TENGs repel water, stains, and bacterial growth, and show excellent stability under mechanical deformations and remarkable washing durability under standard machine‐washing tests. Moreover, e‐textiles based on R^F‐TENGs are compatible with large‐scale production processes and exhibit high sensitivity to touch, enabling the cost‐effective manufacturing of wearable human–machine interfaces.     

Demonstration of the monolithic interconnection on CIS solar cells by picosecond laser structuring on 30 by 30 cm2 modules

In this paper, we present the selective structuring of all three patterns (P1, P2 and P3) of a monolithic interconnection of CIS (Cu(In,Ga)(S,Se)₂) thin film solar cells by picosecond laser pulses at a wavelength of 1064 nm. We show results for single pulse ablation threshold values and line scribing of molybdenum films on glass (P1), CIS on molybdenum (P2) and zinc oxide on CIS (P3). The purposes of these processes are the p‐type isolation (P1), cell interconnect (P2) and n‐type isolation (P3), which are required for complete cell architecture. The half micron thick molybdenum back electrode can be structured with a process speed of more than 15 m/s at about 15 W average power without detectable residues and damage by direct induced laser ablation from the back side (P1). The CIS layer can be structured selectively down to the molybdenum at process speeds up to 1 m/s at about 15 W average power, due to the precision of direct laser ablation in the ultrashort pulse regime (P2). The ZnO front electrode layer is separated by clean trenches with straight side walls at process speeds of up to 15 m/s at about 10 W average power, as a result of indirect induced laser ablation (P3). A validation of functionality of all processes is demonstrated on CIS solar cell modules (30 × 30 cm²). By replacing one state‐of‐the‐art process by a picosecond laser process at a time, solar efficiencies could be increased for P1 and P2 and stayed on a similar level for P3. After an optimization of the patterning processes in the R&D pilot line of AVANCIS, we achieved a new record efficiency for an all‐laser‐patterned CIS solar module: 14.7% as best value for the aperture area efficiency of a 30 × 30 cm² sized CIS module was reached. Copyright © 2014 John Wiley & Sons, Ltd.     

Light-Weight AAA Infrastructure for Mobility Support Across Heterogeneous Networks

Security and privacy architecture for various access networks have often been considered on the upper service layers in the form of application and transport security and from lower layers in the form of security over wireless networks. Today there is no trust relationship between the stakeholders of different access network types for e.g. wireless mesh network, wireless PAN, wireless LAN, cellular network, satellite etc. and each have their own security mechanism. What is common for these access networks is the networking layer which is IP based. In order to provide seamless service across these heterogeneous access networks there must be a trust relationship among the stakeholders for authentication, authorization, accounting and billing of end user. However, what is still missing is a general solution which is both adaptable to the network types and conditions and also takes into account end system capabilities as well as enabling inter-domain AAA negotiation. This paper proposes a light-weight AAA infrastructure providing continuous, on-demand, end-to-end security in heterogeneous networks.     

Atomic layer deposition of aluminum oxide films for carbon nanotube network transistor passivation

Ultra-thin (2-5 nm thick) aluminum oxide layers were grown on non-functionalized individual single walled carbon nanotubes (SWCNT) and their bundles by atomic layer deposition (ALD) technique in order to investigate the mechanism of the coating process. Transmission electron microscopy (TEM) was used to examine the uniformity and conformality of the coatings grown at different temperatures (80 degrees C or 220 degrees C) and with different precursors for oxidation (water and ozone). We found that bundles of SWCNTs were coated continuously, but at the same time, bare individual nanotubes remained uncoated. The successful coating of bundles was explained by the formation of interstitial pores between the individual SWCNTs constituting the bundle, where the precursor molecules can adhere, initiating the layer growth. Thicker alumina layers (20-35 nm thick) were used for the coating of bottom-gated SWCNT-network based field effect transistors (FETs). ALD layers, grown at different conditions, were found to influence the performance of the SWCNT-network FETs: low temperature ALD layers caused the ambipolarity of the channel and pronounced n-type conduction, whereas high temperature ALD processes resulted in hysteresis suppression in the transfer characteristics of the SWCNT transistors and preserved p-type conduction. Fixed charges in the ALD layer have been considered as the main factor influencing the conduction change of the SWCNT network based transistors.