The electrochemical behaviour of nitrogen-containing austenitic stainless steel in methanolic solution

The corrosion behaviour of nitrogen-containing austenitic stainless steel in methanol containing different concentrations of H₂SO₄, HCl, LiCl and H₂SO₄ + HCl has been investigated using a potentiostatic polarization method. The cathodic reaction in the H₂SO₄, HCl and H₂SO₄ + HCl solutions was proton reduction whereas in the neutral LiCl solution, oxygen reduction was the predominant cathodic reaction. Active, passive and transpassive behaviours were observed only for higher concentrations of H₂SO₄ (0.01–2.0 M) due to the inherent water content. A cathodic loop, characterized by measured negative current in the anodic region, was also observed in solutions, in which the concentration of H₂SO₄ was 1.0 M or higher. The relative stability of the passive films decreased as the H₂SO₄ concentration increased, and thus the steel suffered from mild pitting corrosion. In the chloride environment, the rate of corrosion increased as the Cl⁻ ion concentration increased. The presence of acid along with Cl⁻ ions enhanced corrosion, and the corrosion rate increased significantly. The steel suffered from mild intergranular corrosion in acidic chloride solutions of methanol. In the H₂SO₄ + HCl solutions, passive films were only formed when the H₂SO₄ to HCl concentration ratio was greater than ∼10:1.     

Nanocrystalline Ni coatings strengthened with ultrafine particles

In this study, nanocrystalline Ni powders and thermally sprayed coatings, containing ultrafine AlN particles, were synthesized and characterized. The results indicated that the presence of AlN particles in the powders drastically decreased the dimension of agglomerates formed by cryomilling and increased the surface roughness of the agglomerates. The AlN phase was broken down into ultrafine particles of approximately 30 nm in size. These particles were dispersed in the Ni matrix and enhanced the development of a nanocrystalline structure in the Ni matrix during cryomilling. Selected-area diffraction patterns, obtained from transmission electron microscopy (TEM) and X-ray mapping with scanning electron microscopy (SEM), confirmed the presence of AlN particles in the coatings. The presence of AlN particles also led to an increase in the amount of NiO phase that was distributed in the coating, in the form of ultrafine, round particles. AlN particles increased the microhardness of the Ni coating by approximately 60 pct. Indentation-fracture results also indicated that the fine, dispersed AlN particles raised the apparent toughness of the Ni coating. The synthesized Ni coatings containing ultrafine AlN particles were characterized as equiaxed nanocrystalline grains with an average size of 24 nm, in which twins were observed. The increase in microhardness resulted from both grain refinement and the presence of ultrafine particles. The latter played the primary role in strengthening.     

Time-dependent deformation in an enhanced SiC/SiC composite

Time-dependent deformation in an enhanced SiC/SiC composite has been studied under constant load at high temperatures of 1200 °C, 1300 °C, and 1400 °C. Creep damage evolution was evaluated by a Young’s-modulus change of partial unloading and microscopic observation. The addition of the glassy phase in the matrix is very effective for protecting the composite from oxidation. The transient creep is dominant in creep life at all the temperatures. An empirical equation is proposed to describe creep behavior of the composite. It is found that creep activation energy increases with creep time at stresses lower than matrix cracking stress, but the activation energy remains constant at stresses higher than the matrix cracking stress. The creep strain rate of the composite is considered to be controlled by creep of fibers based on examining the time, strain, stress, and temperature dependencies of creep strain rates.     

PERFORMANCE OF THREE STAGE TURBO－EQUALIZATION－DECODING

An increasing demand for high data rate transmission and protection over bandlimited channels with severe inter-symbol interference has resulted in a flurry of activity to improve channel equalization. In conjunction with equalization, channel coding-decoding can be employed to improve system performance. In this letter, the performance of the three stageturbo-equalization-decoding employing log maximum a posteriori probability is experimentally evaluated by a fading simulator. The BER is evaluated using various information sequence and interleaver sizes taking into account that the communication medium is a noisy inter symbol interference channel.     

POWER OPTIMIZATION OF FINITE STATE MACHINE BASED ON GENETIC ALGORITHM

Using state assignment to minimize power dissipation and area for finite state machines is computationally hard.Most of published results show that the reduction of switching activity often trades with area penalty.In this paper,a new approach is proposed.Experimental results show a significant reduction of switching activity without area penalty compared with previous publications.     

A combination of differential equations and convolution in understanding the spread of an epidemic

Nonlinear dynamical method of projecting the transmission of an epidemic is accurate if the input parameters and initial value variables are reliable. Here, such a model is proposed for predicting an epidemic. A method to supplement two variables and two parameters for this proposed model is demonstrated through a robust statistical approach. The method described here worked well in case of three continuous distributions. Model predictions could be lower estimates due to under-reporting of disease cases. Anad hoc procedure with a technical note is provided in the appendix An earlier version of this paper was presented at the annual conference of the Indian Society for Mathematical Modelling & Computer Simulation, Bangalore, November 14–15, 2002     

STUDY ON PHASE PERCEPTION IN SPEECH

The perceptual effect of the phase information in speech has been studied by auditory subjective tests. On the condition that the phase spectrum in speech is changed while amplitude spectrum is unchanged, the tests show that: (1) If the envelop of the reconstructed speech signal is unchanged, there is indistinctive auditory perception between the original speech and the reconstructed speech; (2) The auditory perception effect of the reconstructed speech mainly lies on the amplitude of the derivative of the additive phase; (3) td is the maximum relative time shift between different frequency components of the reconstructed speech signal. The speech quality is excellent while td <10ms; good while 10ms< td <20ms; common while 20ms< td <35ms, and poor while td >35ms.     

Microstructural and textural characterization of a hot-rolled IF steel

The present paper reports the experimental results on the microstructural and textural characterization of a hot-rolled IF steel. The IF steel was hot-rolled in multiple passes in the austenitic field (1,070 °C) followed by air-cooling. SEM, TEM, and LOM were used to image the microstructure of the material. The global texture was determined by X-ray diffraction (XRD) technique. The mesotexture of selected regions was investigated by electron backscatter diffraction (EBSD). Results show the presence of a diffuse (nearly random) and weak texture in the hot-band that consists of recrystallized polygonal grains and subgrains. The fraction of boundaries with misorientations comprised in the interval 2° ≤ ψ < 15° was found to be lower than 5%. It can be concluded that these low angle boundaries and the presence of subgrains can be associated to the existence of a few areas softened by recovery during or after hot rolling in austenitic field.     

Effect of hydrogen charging on dislocation behavior in Ni-Cr and Ni<Subscript>2</Subscript>Cr alloys

The effects of hydrogen charging on the dislocation behaviour in Ni-Cr binary alloys have been investigated by means of transmission electron microscope (TEM) observations using single-crystalline specimens. The deformation mode of Ni-Cr alloys in the absence of hydrogen is characterized by planar dislocations. However, hydrogen charging changed the dislocation configurations to promote curved dislocations, such as dislocation loops and dipoles. The hydrogen-affected dislocation configurations are enhanced with increasing Ni content and reducing Cr content. Weak-beam images show that the Shockley partials of the hydrogen-affected dislocations frequently constrict to make kinks and cross-slip, as if the dislocations were generated by a thermally activated process. The effect of hydrogen charging on superdislocations of a Ni₂Cr superstructure has been also investigated using an aged 70Ni-30Cr alloy. While the deformation mode in the Ni₂Cr superlattice is classified as five variants of superdislocation triplets and one variant of ordinary dislocations, the hydrogen charging has preferred the ordinary dislocations to the superdislocation triplets. The results suggest that the charged hydrogen changes the local plasticity to affect the deformation dynamics in Ni-Cr alloys, where the influence of hydrogen on the plasticity is sensitive to the Ni/Cr concentration and the symmetry of atomic arrangement.