Characterization and Modeling of Broad Spectrum InAs–GaAs Quantum-Dot Superluminescent Diodes Emitting at 1.2–1.3 μm

High-power broadband superluminescent diodes (SLDs) emitting in the 1.2-1.3-mum region are demonstrated using InAs-GaAs quantum dots (QDs). The highest output powers of ~30-50 mW are achieved using 18 QD layers with p-doped GaAs spacers. At these high powers the device operates in a regime of broad bandwidth (~100 nm) with a spectral dip of ~5 dB between two separate peaks originated by the QD ground and excited states. Spectral calculations performed with a traveling-wave rate equation model show excellent agreement with the experimental data and provide design rules for optimizing the output spectrum. SLD characteristics are presented for two different device structures consisting of tilted and bent waveguides. The latter allows the achievement of higher output powers at lower currents. The coherence properties and the temperature characteristics are also discussed in detail.     

处理器性能推动车载娱乐系统的发展

以前,汽车还只是一种普通而简单的运输工具.随着电子时代的来临,从防刹车死锁到汽车仪表板,电子和半导体器件在汽车领域的应用变得日益广泛.现在,应用在汽车中的电子娱乐设备将更直接的出现在你面前,比如一个后排座的DVD播放器(其实可以把一个车载收音机也称作娱乐设备,但是它不能像DVD播放器那样令人兴奋).实际上,人们已经有能力在汽车中集成具有无线连接能力的DVD播放器、移动电话、全球定位系统、MP3播放器、卫星电台和因特网浏览器,所有这些都可以通过语音识别和中央控制系统来操控.     

Ultrawideband Radar Measurements of Thickness of Snow Over Sea Ice

An accurate knowledge of snow thickness and its variability over sea ice is crucial in determining the overall polar heat and freshwater budget, which influences the global climate. Recently, algorithms have been developed to extract snow thicknesses from satellite passive microwave data. However, validation of these data over the large footprint of the passive microwave sensor has been a challenge. The only method used thus far has been with meter sticks during ship cruises. To address this problem, we developed an ultrawideband frequency-modulated continuous-wave radar to measure the snow thickness over sea ice. We synthesized a very linear chirp signal by using a phase-locked loop with a digitally generated chirp signal as a reference to obtain a fine-range resolution. The radar operates over the frequency range from 2-8 GHz. We made snow-thickness measurements over the Antarctic sea ice by operating the radar from a sled in September and October 2003. We performed radar measurements over 11 stations with varying snow thicknesses between 4 and 85 cm. We observed an excellent agreement between radar estimates of snow thickness with physical measurements, achieving a correlation coefficient of 0.95 and a vertical resolution of about 3 cm. Comparison of simulated radar waveforms using a simple transmission line model with the measurements confirms our expectations that echoes from snow-covered sea ice are dominated by reflections from air-snow and snow-ice interfaces.     

Highly Porous Materials as Tunable Electrocatalysts for the Hydrogen and Oxygen Evolution Reaction

The facile preparation of highly porous, manganese doped, sponge‐like nickel materials by salt melt synthesis embedded into nitrogen doped carbon for electrocatalytic applications is shown. The incorporation of manganese into the porous structure enhances the nickel catalyst's activity for the hydrogen evolution reaction in alkaline solution. The best catalyst demonstrates low onset overpotential (0.15 V) for the hydrogen evolution reaction along with high current densities at higher potentials. In addition, the possibility to alter the electrocatalytic properties of the materials from the hydrogen to oxygen evolution reaction by simple surface oxidation is shown. The surface area increases up to 1200 m²g^?1 after mild oxidation accompanied by the formation of nickel oxide on the surface. A detailed analysis shows a synergetic effect of the oxide formation and the material's surface area on the catalytic performance in the oxygen evolution reaction. In addition, the synthesis of cobalt doped sponge‐like nickel materials is also delineated, demonstrating the generality of the synthesis. The facile salt melt synthesis of such highly porous metal based materials opens new possibilities for the fabrication of diverse electrode nanostructures for electrochemical applications.     

Intrinsic isotopic C labelling of polyphenols

The intrinsic isotopic labelling of plants with ¹³CO₂ is an effective method to generate highly labelled compounds using photosynthesis and avoiding labour-intensive complex organic syntheses. In this study, the intrinsic isotopic labelling of polyphenols in parsley, spinach and peppermint is shown for the first time. The plants were grown in an atmosphere where ¹²CO₂ was replaced by ¹³CO₂, in order to generate highly labelled compounds. The total content of ¹³C as well as the individual polyphenols were analysed by Isotopic Ratio-MS and HPLC–Iontrap-MSⁿ.     

Environmental selenium research: from microscopic processes to global understanding

Selenium is a natural trace element that is of fundamental importance to human health. The extreme geographical variation in selenium concentrations in soils and food crops has resulted in significant health problems related to deficient or excess levels of selenium in the environment. To deal with these kinds of problems in the future it is essential to get a better understanding of the processes that control the global distribution of selenium. The recent development of analytical techniques and methods enables accurate selenium measurements of environmental concentrations, which will lead to a better understanding of biogeochemical processes. This improved understanding may enable us to predict the distribution of selenium in areas where this is currently unknown. These predictions are essential to prevent future Se health hazards in a world that is increasingly affected by human activities.     

用于聚酯POY生产的WINGS

Oerlikon Barmag在2007年ITMA国际纺织博览会上以提出的用于化纤装置的全新理念,首次做了名符其实的成功展示。在ITMA2007上展示的新型POY纺丝机的WINGS（卷绕集成导辊的方案）,在2008年卖出了1600多次。采用WINGS的几种装置在印度和中国同时成功投产。WINGS已占有全球市场份额的50％以上。     

Elemental composition of HULIS in the Pearl River Delta Region, China: results inferred from positive and negative electrospray high resolution mass spectrometric data

The HUmic-LIke Substances (HULIS) fraction isolated from aerosol samples collected at a rural location of the Pearl River Delta Region (PRD), China, during the harvest season was analyzed by both positive and negative mode electrospray ionization (ESI) coupled with an ultrahigh resolution mass spectrometer (UHRMS). With the remarkable resolving power and mass accuracy of ESI-UHRMS, thousands of elemental formulas were identified. Formulas detected in the positive (ESI+) and the negative (ESI-) mode complement each other due to differences in the ionization mechanism, and the use of both provides a more complete characterization of HULIS. Compounds composed of C, H, and O atoms were preferentially detected in ESI- by deprotonation, implying their acidic properties. Tandem MS and Kendrick Mass Defect analysis implies that carboxyl groups are abundant in the CHO compounds. This feature is similar to those of natural fulvic acids, but relatively smaller molecular weights are observed in the HULIS samples. A greater number of reduced nitrogen organic compounds were observed in the ESI+ compared to ESI-. Compounds with biomass burning origin including alkaloids, amino acids, and their derivatives are their probable constituents. Sulfur-containing species were dominantly detected in ESI-. The presence of sulfate fragments in the MS/MS spectra of these species and their high O/S ratios implies that they are mainly organosulfates. Organosulfates and nitrooxy-organosulfates were often the most intensive peaks in the ESI- spectra. They are believed to be products of reactive uptake of photooxidation products of reactive volatile organic compounds by acidic sulfate particles. The elemental compositions deduced from the UHRMS analysis confirm the conclusion from our previous study that biomass burning and SOA formation are both important sources of HULIS in the PRD region.