Mercury‐Mediated Organic Semiconductor Surface Doping Monitored by Electrolyte‐Gated Field‐Effect Transistors

Surface doping allows tuning the electronic structure of semiconductors at near‐surface regime and is normally accomplished through the deposition of an ultrathin layer on top or below the host material. Surface doping is particularly appealing in organic field‐effect transistors (OFETs) where charge transport takes place at the first monolayers close to the dielectric surface. However, due to fabrication restrictions that OFET architecture imparts, this is extremely challenging. Here, it is demonstrated that mercury cations, Hg²⁺, can be exploited to control doping levels at the top surface of a thin film of a p‐type organic semiconductor blended with polystyrene. Electrolyte‐ or water‐gated field‐effect transistors, which have its conductive channel at the top surface of the organic thin film, turn out to be a powerful tool for monitoring the process. A positive shift of the threshold voltage is observed in the devices upon Hg²⁺ exposure. Remarkably, this interaction has been proved to be specific to Hg²⁺ with respect to other divalent cations and sensitive down to nanomolar concentrations. Hence, this work also opens new perspectives for employing organic electronic transducers in portable sensors for the detection of an extremely harmful water pollutant without the need of using specific receptors.     

Why Catalonia cannot be considered as a regional innovation system

We present a model to assess the systemness of an innovation system. Patent and citation datawith an institutional address in Catalonia (1986-1996) were analyzed in terms of relationallinkages and the development in these distributions over time was evaluated using methods fromsystems dynamics. Relational linkages are extremely scarce. A transition at the system's levelcould be indicated around 1990 when using institutional addresses, but not when using cognitivecategories. The institutional restructuring has led to changes in the pattern of linkages(coauthorship, etc.), but the reproduction of the system's knowledge base has remaineddifferentiated. We conclude that although a system in several other respects, Catalonia cannot(yet) be considered as a (knowledge-based) innovation system. The existence of a mechanism forthe integration could not be indicated at the regional level.     

Overt and covert identification of fragmented objects inferred from performance and electrophysiological measures.

The authors investigated visual processing leading to object identification by manipulating the number of fragments and nature of the study. During the study, participants either named or drew objects in Experiment 1 and drew them all in Experiment 2. During the test, participants made an identification judgment at each of 6 different fragmentation levels for studied and new objects. Fewer fragments were needed to identify studied than unstudied objects. Reaction times (RTs) were faster for studied than unstudied objects both at identification and at the preceding level. Event-related brain potentials (ERPs) to unidentified objects were characterized by a late negativity in contrast to a positivity to identified objects. ERPs to studied but not to new objects contained a smaller and later version of the identification positivity at level just prior to identification, which was not due to differential response confidence. Much covert visual analysis and even object identification may precede overt identification, depending on the nature of prior experience. (PsycINFO Database Record (c) 2010 APA, all rights reserved)