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31.
G. Rocquelin J. P. Sergiel B. Martin J. Leclerc R. Cluzan 《Journal of the American Oil Chemists' Society》1971,48(11):728-732
Recent findings on the nutritive value of rapeseed oil (RSO) with high erucic acid content have been compared to those of
canbra oil (CO), an oil extracted from newly bred Canadian rapeseed with no erucic acid. Erucic acid in diets retards animal
growth even if food consumption is not altered. Growth performances of CO are as good as olive or peanut oil. The unbalanced
ratio of palmitic acid to monoethylenic acids of CO does not affect rat growth rate. Because of its glyceride structure and
high content of erucic acid, RSO has a lower digestibility (81%) than CO (96%) in the rat. Unabsorbed erucic acid is not preferentially
excreted as calcium soaps. Interesterification of RSO which converts 31.7% of the erucic chains to the 2 position improves
digestibility of erucic acid. 2-Monoerucin is more efficiently absorbed than the free acid. In vivo metabolic conversion of
erucic to oleic acid has been proved in the rat. β-oxidation of injected 14-14C labeled erucic acid proceeded at the same rate as oleic acid but the over-all yield of the reaction was lower. Fatty acid
composition of tissues in animals fed RSO or CO is influenced on one hand by erucic and gadoleic (C20∶1) acids of RSO, and on the other hand by the unbalanced ratio of palmitic-monoethylenic acids and the linolenic acid content
of both oils. Nonnegligible amounts of erucic acid are deposited in the body fats of rats, chickens, turkeys, lambs and found
in the milk of female rats fed RSO. Almost no erucic acid is incorporated in liver and testicles in the rat and it is not
recovered in chicken egg yolk. The effect of RSO on rat reproduction has been re-examined. Dietary lipid and vitamin levels
are of great importance in the results obtained. RSO induces myocarditis in several animal species. Similar lesions, although
less frequent and severe, have been observed also with CO in the rat. Some authors have reported that erucic acid of RSO was
responsible for the effect on heart muscle. Common fatty acid patterns to both RSO and CO have to be further investigated
to explain the persisting effect of CO.
One of 9 papers presented at the Symposium, “Cruciferous Oil-seeds,” ISF-AOCS World Congress, Chicago, September 1970. 相似文献
32.
Polyurethane prepared from tetramethylene glycol and diisocyanate was exposed in the form of films to small pressures of NO2 and to NO2 plus air. Tensile strength was measured as a function of exposure time and temperature with an apparatus especially constructed for the purpose of measuring mechanical properties in different environmental “atmospheres.” 相似文献
33.
G.A. Martin 《Journal of Catalysis》1979,60(3):345-355
The rate of hydrogenolysis of ethane over a Ni/SiO2 catalyst, studied over a large range of pressure and of temperature, is shown to be related to the degree of hydrogen coverage θH, by the equation: with K0 nearly equal to the number of ethane molecules colliding with the Ni surface, E0 = 14 ? 1 kcal/mole, Y = ?1 ? 2 and X = 15 ? 2. The rate-limiting step is believed to be the irreversible, dissociative adsorption of ethane on an ensemble of at least 12 adjacent Ni atoms, free from adsorbed hydrogen, resulting in the complete cracking of C2H6: C2H6 + 12Ni → 2 Irreversible adsorption of ethane is assumed to compete with the reversible adsorption of hydrogen. This mechanism, which is compared with those proposed earlier, is in good agreement with data on ethane adsorption studied by magnetic methods, and with a study of ethane hydrogenolysis over NiCu/SiO2 catalysts. 相似文献
34.
K. D. Bartle D. W. Jones T. G. Martin W. S. Wise 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1970,20(6):197-202
Tar resulting from fluidised-bed, low-temperature carbonisation of coal was treated to yield a neutral oil from which a series of six other samples was extracted. These were examined by proton magnetic resonance (p.m.r.) spectroscopy, low-ionising-voltage (11 eV) mass spectroscopy (m.s.), gel chromatography followed by fluorescent indicator analysis, and cryoscopy. Aliphatic fractions separated chromatographically were also examined by infra-red spectroscopy. Distributions of hydrogen between chemical types were found for the several fractions from 60 MHz p.m.r. spectra and presented in terms of average structural parameters. M.s. analysis indicated negligible cracking of paraffin components, and the average molecular weight of 197 agreed well with cryoscopic determinations. For the carbon ratio, fa, between aromatic and total, agreement between m.s. and p.m.r. depends on the p.m.r. structural analysis scheme adopted. P.m.r. and m.s. structural analyses of the aromatics emphasise the predominance of di- and tri-nuclears, with about 40% of available sites substituted, and the importance of acenes in lowtemperature carbonisation material. Gas and gel chromatography showed urea-adductable paraffins to be largely straight-chain C10-C26, much as for tars from carbonisation at higher temperature. 相似文献
35.
36.
Liu Xinke Kao Evan Haraldsson Henrik Ballweber Megan Martin Alastair Li Youxiang Wang Yuting Saloner David 《Magma (New York, N.Y.)》2021,34(5):659-666
Magnetic Resonance Materials in Physics, Biology and Medicine - To determine the intra-individual flow variation in serially acquired studies, and the influence of this variation on subsequent... 相似文献
37.
Corrosion of oil-fired domestic boilers Depending on the surface temperature of the flue gas side the corrosion of oil fired domestic boilers proceeds either mainly by acid corrosion or by oxygen corrosion:
- – At surface temperatures of 60°C and higher the corrosion mechanism of acid corrosion prevails and the corrosion rates amount to 0.1–0.3 mm/year (values referred to continuous burner operation). The corrosion products consist of soluble iron(II)- and iron(III)sulfates. Higher corrosion rates can be attributed to an appreciable catalytic formation of sulfur trioxide on the corrosion products formed on the convective heating surfaces.
- – At surface temperatures of 40°C the mechanism of oxygen corrosion already dominates and the corrosion rates are about ten times higher (1.5–3 mm/year, referred to continous burner operation). The high portion of ioron oxide hydrates, especially goethit (α-FeOOH), makes the corrosion products difficult to remove.
- – Distinctly reduced service lives are also expected for the so called reduced temperature boilers (“Niedertemperaturkessel”) and low temperature boiers (“Tieftemperaturkessel”): According to the manufacturers these boilers may be operated at boiler water temperatures well below 60°C, as they are equipped with constructive measures to enhance the surface temperature on the flue gas side. However, these measures are only fully effective under stationary conditions.
38.
The effects of heat treatments on the mechanical and fracture properties of continuous fiber Pitch 100 graphite/6061 aluminum
(P100 Gr/6061 Al) composite were evaluated by varying solution temperature and aging time. All heat treatments resulted in
decreased mechanical properties due to the reaction at the fiber/matrix interface during solution treatments. SEM analysis
of the fractured samples showed a large degree of fiber pullout, interface failure, and matrix cracking. 相似文献
39.
Programmers build large‐scale systems with multiple languages to leverage legacy code and languages best suited to their problems. For instance, the same program may use Java for ease of programming and C to interface with the operating system. These programs pose significant debugging challenges, because programmers need to understand and control code across languages, which often execute in different environments. Unfortunately, traditional multilingual debuggers require a single execution environment. This paper presents a novel composition approach to building portable mixed‐environment debuggers, in which an intermediate agent interposes on language transitions, controlling and reusing single‐environment debuggers. We implement debugger composition in Blink, a debugger for Java, C, and the Jeannie programming language. We show that Blink is (i) simple: it requires modest amounts of new code; (ii) portable: it supports multiple Java virtual machines, C compilers, operating systems, and component debuggers; and (iii) powerful: composition eases debugging, while supporting new mixed‐language expression evaluation and Java native interface bug diagnostics. To demonstrate the generality of interposition, we build prototypes and demonstrate debugger language transitions with C for five of six other languages (Caml, Common Lisp, C#, Perl 5, Python, and Ruby) without modifications to their debuggers. Using real‐world case studies, we show that diagnosing language interface errors require prior single‐environment debuggers to restart execution multiple times, whereas Blink directly diagnoses them with one execution. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
40.