Terrorism Communication: Characteristics and Emerging Perspectives in the Scientific Literature 2002–2011

This paper aims to clarify current knowledge on the contribution of communication to crisis management in the case of terrorism incidents. This is done by means of a systematic review of the scientific literature on terrorism communication over the last 10 years to identify the many challenges facing communication in such crises, and represents the first attempt of its kind. To date, within the literature on terrorism communication, much attention has been paid to chemical, biological, radiological or nuclear hazards. Terrorism crises are complex and challenging. Preparedness for such diverse low‐probability high‐impact crises can best be included in a wider educative approach. Terrorism crises call for fast information updates that, using a multi‐channel approach, can be tailored to fit different needs and (social) media habits.     

Effects of polyvinylchloride films and edible starch coatings on quality aspects of refrigerated Brussels sprouts

To extend shelf life, the effects of polyvinylchloride film (PVC) and edible coatings on quality aspects of refrigerated Brussels sprouts were studied. Starch-based coatings were formulated using glycerol (G), sorbitol (S) or glycerol plus sunflower oil (O). Sprouts so treated as well as uncoated ones were placed on expanded polystyrene trays. Combinations of PVC and coatings (treatments named G-PVC, S-PVC and O-PVC) were also tested. Uncovered trays were maintained as controls. All packages were stored at 0 °C for 42 days and samples were removed every 14 days to determine commercial acceptability, weight loss, surface colour (of sprouts’ heads and bases) and texture. Sprouts in all treatments maintained optimum quality conditions over the first 14 days. At the end of storage, browning of cut zones and losses in weight and firmness were minimised in PVC-packaged sprouts, particularly in G-PVC. Therefore, PVC and G-PVC treatments were selected to evaluate some nutritional quality components. Ascorbic acid and total flavonoid contents remained almost constant while radical scavenging activity increased after 42 days of storage. Thus, PVC and G-PVC treatments showed the best performance for long-term refrigerated storage of Brussels sprouts.     

Drop in Combined Sewer Manhole for Supercritical Flow

Manholes often contain small drops for various reasons, the most important being submergence. While this may be appropriate for subcritical flow, its effect was considered doubtful for supercritical flow. This note aims at investigating the effect of a manhole drop on the hydraulics of sewer flow. Based on systematic experimental observations, the flow pattern associated with a manhole drop was established. A distinction was also made between small and intermediate drops. Then, the main wave features were analyzed to result in expressions that contain both the upstream filling ratio and the Froude number of the approach flow. In addition, the discharge capacity was also investigated, and selected photographs show typical drop flow in combined sewer manholes. The result of the present study is evident, based on these observations, and recommendations towards future design of combined sewer manholes are also made.     

Crosslinkable micelles from diblock amphiphilic copolymers based on vinylbenzyl thymine and vinylbenzyl triethylammonium chloride

Polymeric micelles (PMs) composed of self‐assembled amphiphilic block copolymers were synthesized from vinylbenzyl thymine (VBT) and vinylbenzyl triethylammonium chloride (VBA) exhibiting improved physical stability. Three diblock copolymers of different chemical compositions and similar molecular weights (polydispersities below 1.5) were obtained via nitroxide mediated radical polymerization. Critical micelle concentration (CMC) was determined by dye micellization method, the shift of the absorption peak of the anionic (EY) due to the interactions with non‐assembled chains and auto‐assembled copolymers was followed. Polymeric systems exhibited good stability revealing that a higher proportion of cationic monomers in the diblock reduce the CMC. Furthermore, after the core of PMs was photocrosslinked by UV irradiation, the CMC decreases notably. Kinetic release studies using EY dye as probe demonstrated that both, higher VBA ratios in the polymer and higher UV‐irradiation, slow down the dye release. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41947.     

Catalysts for the Ethoxylation of Esters

The intermediates for the production of nonionic surfactants can be derived from petrochemicals and/or from renewable raw materials. In both, the role of catalysis is fundamental. In this paper the main results reported in the literature related with the catalysis for ethoxylation of fatty esters will be reviewed. The main open challenges for these technologies will be outlined.     

Evaluation of Pseudomonas spp. through O2 and CO2 headspace analysis

This article proposes an approach to determine the level of Pseudomonas spp. in milk, based on the evaluation of the content of oxygen and carbon dioxide produced in the headspace of sealed vials; the research was divided into two phases: model building and preliminary validation. Three different strains of Pseudomonas spp., Ps. putida (wild strain) and Ps. fluorescens (wild and collection isolates), were used as targets. Data of CO₂ and O₂ were modelled through a modified positive (CO₂) or a negative Gompertz equation (O₂) to estimate the Minimum Detection Time (MDT), defined as the time to attain 3% of CO₂ (MDT₁) or a decrease in the content of O₂ by 3% (MDT₂). Then, MDT₁ and MDT₂ were submitted to a linear regression procedure, using cell concentration as independent variable; the correlations ‘MDT₁/cell concentration’ and ‘MDT₂/cell concentration’ showed high determination coefficients (>0.983). Moreover, the regression procedure pointed out that both MDT₁ and MDT₂ decreased by ca. 3 h for an increase in cell count of 1 log cfu mL^?1. Preliminary validation in milk pointed out that the error associated with the regression line ‘MDT₂/cell concentration’ was below 5%.     

Stability of commercial formulations and aqueous solutions of ifosfamide: a reply

This study is a reply to a paper in this journal reporting on the chemical instability of ifosfamide (IF) (Drug Metab. Dispos. 23, 433-437, 1995). The authors describe chloroethylamine as a major degradation product of IF in both the powder and aqueous solutions. In the present study, we show that: i) IF powder remains pure up to 3-5 years after its expiration date; ii) solutions of IF at pH 7 are stable for at least 12 hr at 40 degrees C; and iii) solutions of IF at pH 4 or pH 10 are only slightly degraded (approximately 1%) after standing for 6 hr at 37 degrees C. We also demonstrate that the reported IF instability depends on the analytical procedure used. The trifluoroacetylation procedure used by the authors, which is conducted in dichloromethane, led to low derivatization yields and to the formation of several degradation compounds of IF, among them chloroethylamine. In contrast, when the trifluoroacetylation reaction is conducted in ethyl acetate, there is high yield of trifluoroacetylated IF, and degradation compounds are minor. In conclusion, we believe that the large amounts of chloroethylamine reported by the authors in both powder and aqueous solutions of IF stemmed from degradation linked to the method of derivatization. Because IF is not readily derivatized by trifluoroacetic anhydride in dichloromethane, the combination of heating with possible uncontrolled evaporation of solvent and the presence of trifluoroacetic acid in the medium lead to degradation of IF and formation of chloroethylamine.