Electroplating of cobalt from aqueous citrate baths

Electroplating of cobalt onto steel substrates from citrate baths has been investigated under different conditions of bath composition, current density, pH and temperature. A detailed study has been made of the influence of these variables on the potentiodynamic cathodic polarization curves, cathodic current efficiency and the throwing power as well as the throwing index of these baths. The optimum bath composition has been established and it contains: CoSO₄.7H₂O (0·36 mol dm⁻³) trisodium citrate (0·19 mol dm⁻³) and citric acid (0·1 mol dm⁻³) at pH 5·0. The microhardness of cobalt electrodeposited from citrate baths is high and it may be, under certain conditions, two or three times higher than that reported for cobalt electrodeposited from other different baths. The surface morphology of the as-plated cobalt was investigated by using scanning electron microscopy (SEM) while the structure was studied by using X-ray diffraction analysis and anodic stripping voltammetry (ASV) techniques. © 1998 Society of Chemical Industry     

Assessment of an active-cooling micro-channel heat sink device,using electro-osmotic flow

Non-uniform heat flux generated by microchips causes “hot spots” in very small areas on the microchip surface. These hot spots are generated by the logic blocks in the microchip bay; however, memory blocks generate lower heat flux on contrast. The goal of this research is to design, fabricate, and test an active cooling micro-channel heat sink device that can operate under atmospheric pressure while achieving high-heat dissipation rate with a reduced chip-backside volume, particularly for spot cooling applications. An experimental setup was assembled and electro-osmotic flow (EOF) was used thus eliminating high pressure pumping system. A flow rate of 82 μL/min was achieved at 400 V of applied EOF voltage. An increase in the cooling fluid (buffer) temperature of 9.6 °C, 29.9 °C, 54.3 °C, and 80.1 °C was achieved for 0.4 W, 1.2 W, 2.1 W, and 4 W of heating powers, respectively. The substrate temperature at the middle of the microchannel was below 80.5 °C for all input power values. The maximum increase in the cooling fluid temperature due to the joule heating was 4.5 °C for 400 V of applied EOF voltage. Numerical calculations of temperatures and flow were conducted and the results were compared to experimental data. Nusselt number (Nu) for the 4 W case reached a maximum of 5.48 at the channel entrance and decreased to reach 4.56 for the rest of the channel. Nu number for EOF was about 10% higher when compared to the pressure driven flow. It was found that using a shorter channel length and an EOF voltage in the range of 400–600 V allows application of a heat flux in the order of 10⁴ W/m², applicable to spot cooling. For elevated voltages, the velocity due to EOF increased, leading to an increase in total heat transfer for a fixed duration of time; however, the joule heating also got elevated with increase in voltage.     

Effect of Buoyancy Ratio on Double-Diffusive Natural Convection in a Porous Rhombic Annulus

This paper reports on the effect of buoyancy ratio due to both heat and mass transfer on natural convection in a porous enclosure between two isothermal concentric cylinders of rhombic cross sections. For negative values of the buoyancy ratio, buoyancy forces due to heat and mass transfer are in opposite directions (opposing mode), while for positive values they are in the same direction (aiding mode). Numerical results demonstrate that the flow strength increases as the absolute value of the buoyancy ratio increases. In the opposing mode, the eye of the vortex flow is located in the lower half of the enclosure, while in the aiding mode it is positioned in the upper part of the annulus. The average Nusselt and Sherwood number values increase as the absolute value of the buoyancy ratio moves away from 1, with values obtained in the aiding mode being higher than corresponding values achieved in the opposing mode. A comparison is also made between the computed average Nusselt and Sherwood number values and similar ones obtained in a circular annulus having the same inner and outer perimeters as the rhombic enclosure. Predictions indicate large percent difference in values, demonstrating that circular geometries cannot be exploited to accurately predict heat and mass transfer in complex geometries.     

Solar electric powered reverse osmosis water desalination system for the rural village,Al Maleh: design and simulation

Desalination of brackish water by using reverse osmosis (RO) system powered by solar PV has not been tried and examined in Palestine until now. This paper proposes rural village Al Maleh for erection and testing of the first PV-powered RO system. Al Maleh is highly qualified for testing of such systems since it has a lot of mineral hot water springs of about 3400?ppm salinity. Based on the climate conditions in Al Maleh, the paper presents the design of the PV-powered RO water desalination system. The obtained design results can be used for an economic feasibility study of this technology [Mahmoud, M. Techno-economic feasibility of PV-powered water desalination in Palestine. Special Case: Al Maleh Village (to be published).]. The performance of the designed system is investigated by software simulation. The obtained results show that a daily production of 1?m³ from the brackish water in Al Maleh would require about 820 peak watt of PV generator.     

Optimization of stress wave propagation in a multilayered elastic/viscoelastic hybrid composite based on carbon fibers/carbon nanotubes

The hypothesis of incorporating carbon nanotubes (CNTs) into the interfacial layers of fiber‐reinforced polymer composites fiber‐reinforced Polymers (FRPs) to enhance their mechanical properties and mitigate the stress wave propagation during a blast event is investigated. A numerical model is developed to simulate the stress wave propagation in a laminated elastic/viscoelastic FRP. Coupled with multiobjective optimization paradigms, the optimal CNTs contents in the interfacial layers are determined to minimize the stress‐to‐strength ratio in each layer. A case study demonstrating the design of a five‐layered FRP subjected to a blast event is presented. The simulation revealed that the viscoelastic properties of the matrix material contribute significantly to the energy dissipation during stress wave propagation. It is shown that addition of 0.69% CNTs by volume to the epoxy interface significantly enhances the ability of composite to resist blast loading. Results were compared with a standard model that assumes only elastic behavior. POLYM. COMPOS., 2012. © 2011 Society of Plastics Engineers     

Behavior of Beams Strengthened with Novel Self-Anchored Near-Surface-Mounted CFRP Bars

A commonly observed failure mode in laboratory tests involving surface bonded fiber-reinforced polymer (FRP) laminates or near-surface-mounted (NSM) bars is premature delamination, that is, the separation of the FRP from the substrate well before the FRP reaches its ultimate strain capacity. To delay the onset of delamination and to ensure that the NSM FRP reinforcement continues to contribute to member strength after partial delamination, a new self-anchored carbon fiber-reinforced polymer (CFRP) bar was developed and tested for this investigation. This bar is made with a series of monolithic spikes that can be anchored deep inside the concrete. In addition to cutting grooves into the concrete cover for the placement of the primary reinforcing bar, holes are drilled deep into the concrete to insert the spikes. To test the performance of this bar, six large, simply supported, reinforced, concrete beams were retrofitted with NSM bars and tested in four-point bending. Two beams were strengthened with NSM bars without anchors or spikes but were otherwise similar to the self-anchored bar and served as control specimens (Series?B1). Two beams were strengthened in flexure with the new self-anchored NSM bars (Series?B2), and the remaining two beams (Series?B3) were strengthened in flexure and shear by using the self-anchored NSM bars as partial shear reinforcement. The effect of the proposed strengthening system on the beams’ strength, failure mode, deformability, and ductility are discussed on the basis of the experimental results. The anchors delayed delamination and enabled the NSM bar to experience at least a 77% higher strain at failure than the companion bar without anchors. The anchors also increased beam displacement ductility and energy ductility at a 20% strength degradation by at least 34% and 42%, respectively.     

Maximum Stress Triaxiality Ratio Criterion for Mixed Mode Crack Initiation in Anisotropic Materials

The maximum stress triaxiality ratio criterion, originally proposed for mixed mode crack initiation in isotropic materials, is adapted for anisotropic materials using an anisotropic yield function.     

Hydrogen storage in lithium,sodium and magnesium-decorated on tetragonal silicon carbide

Motivated by the widespread application and fascinating properties of various silicon-carbon nanomaterials, we have extensively investigated the properties of tetragonal silicon carbides (t-SiC) monolayer as a novel 2D material for hydrogen storage.Using calculations of the density functional theory comprising van der Waals interactions of type vdW-DF2-C09_x, the structural stability, electronic properties and hydrogen molecules adsorption energies on the surface of pure t-SiC were investigated.The results show that adsorption energies of H₂ molecules in this system are stronger than that of graphene. We also found that the decoration with alkali (Li, Na) and alkaline-earth (Mg) metals atoms increases the stability of hydrogen compared to the pure system. The studied system decorated with 8 elements of Li/Na/Mg is able to adsorb up 24 molecules of hydrogen and reaches a gravimetric capacity of 6.50, 5.54 and 5.48 wt%, respectively. The desorption temperatures found are significantly high compared to other 2D systems.     

A multiple multilayer perceptron neural network with an adaptive learning algorithm for thyroid disease diagnosis in the internet of medical things

The Journal of Supercomputing - Medical information systems such as Internet of Medical Things (IoMT) are gained special attention over recent years. X-ray and MRI images are important sources of...     

Special cause management: A knowledge-based approach to statistical process control

In this paper we discuss a set of software tools developed to support the tasks associated with managing special causes of variation in a manufacturing process. These tasks include the detection of significant changes in process variables, a diagnosis of the causes of those changes, the discovery of new causes, the management of performance data, and the reporting of results. The software tools include automatic recognition of out-of-control features in critical process variables, rule-based diagnosis of special causes, a model-based search for symptoms where a diagnosis is not possible, and automated reporting aids. It is hoped that these tools will enhance the efficiency of special cause management.