Surface structure and metathesis activity of photoreduced allyl‐based Mo/SiO2 catalysts

XPS and metathesis activity studies were performed on oxidic allylbased Mo/SiO₂ catalysts (0.5 wt% Mo) and the oxidic catalyst following photoreduction to various extents. XPS results and average oxidation state measurements from the amount of CO₂ formed during photoreduction, indicated that controlled photoreduction of the oxidic catalyst, in CO atmosphere, produces a mixture of Mo⁶⁺ and Mo⁴⁺ oxidation states with Mo⁴⁺ in abundances ranging from 0 to 100%. Propene metathesis activity studies were performed on the oxidic and photoreduced allylbased Mo/SiO₂ catalysts. The results indicated that metathesis activity appears on photoreduction and increases linearly with increasing abundance of Mo⁴⁺ present on the catalyst. The linear relationship between the % propene conversion and the % Mo⁴⁺ present on the catalyst is consistent with the proposed uniformity of the Mo species and with the hypothesis that the active site (or active site precursor) is associated with Mo⁴⁺.     

Analysis of the historical collapse of an abandoned underground chalk mine in 1961 in Clamart (Paris,France)

In chalk mines, the method of room and pillar mining has been widely used in France. Yet, many large collapses have occurred during or after their exploitation, with the collapse of Clamart (south of Paris, France) being well known as one of the most catastrophic. Today, 50 years after the collapse, the main causes of the event are still not well understood. This paper presents a back-analysis of the case study, using both an empirical approach and a numerical approach. Based on a set of hypotheses, an empirical approach and 3D numerical modeling have indicated a plausible scenario that may explain the collapse: The large collapse may have been caused by a lack of bearing capacity of the pillars and the sudden rupture of a hard limestone bed on which the load would have accumulated until overload occurred. The bed weakness between the two mine levels may also have had an influence on the mine’s general lack of stability. Moreover, under the given hypothesis, the study shows a very low influence of the water table due to flooding of the mine.

     

Traffic-aware auto-configuration protocol for service oriented low-power and lossy networks in IoT

Wireless Networks - Many diversified services can be offered by smart objects, referred to herein by nodes, in low-power and lossy networks (LLNs) contributing to the Internet of Things (IoT). A...     

A Reference Benchmark Solution for Free Convection in A Square Cavity Filled with A Heterogeneous Porous Medium

The Fourier-Galerkin (FG) method is used to produce a highly accurate solution for free convection in a square cavity filled with heterogeneous porous medium. To this end, the governing equations are reformulated in terms of the temperature and the stream function. These unknowns are then expanded in infinite Fourier series truncated at given orders. The accuracy of the FG solution is investigated for different truncation orders and compared to the results of an advanced finite-element numerical model using fine-mesh discretization. The obtained results represent a set of high-quality data that can be used for benchmarking numerical models.     

The physiological effects of pallidal deep brain stimulation in dystonia.

Dystonia is an involuntary movement disorder characterized by muscle contractions causing abnormal postures and spasms, affecting part or all of the body. Dystonia may be primary where an abnormal gene, most commonly DYT1, may be identified, or secondary to structural brain lesions or heredodegenerative disorders. The underlying defect is believed to be abnormal basal ganglia modulation of cortical motor pathways, and various motor and sensory physiological abnormalities have been demonstrated. The failure of medical treatment in many patients with the more severe and generalized forms of dystonia has led to renewed interest in neurosurgical treatment approaches. In recent years, deep brain stimulation (DBS) of globus pallidus internus (GPi) has emerged as an effective treatment for dystonia, particularly patients with primary generalized dystonia, where remarkable improvement may occur. In contrast to Parkinson's disease, the beneficial effects of DBS in dystonia are not immediate but progressive over weeks to months. Physiological and imaging studies in dystonia patients with GPi DBS have demonstrated both short and long-term effects of GPi DBS on motor cortex and subcortical circuits including progressive normalization of spinal and brainstem excitability after GPi DBS which correlate with clinical improvement. These effects, in light of existing physiological data in dystonia, suggest that GPi DBS acts primarily by major modification of basal ganglia output to brainstem, thalamus, and cortex resulting in neural reorganization, which may explain the characteristic progressive improvement in dystonia after GPi DBS.     

Magnesium vacancies and hydrogen doping in MgH2 for improving gravimetric capacity and desorption temperature

Performing an ab initio analysis, we inspect the effect of magnesium vacancies and hydrogen doping on the magnesium hydride (MgH₂). The Korringa – Kohn – Rostoker method integrated with the coherent potential approximation is used to perform our calculations. In particular, we find that the gravimetric capacity of MgH₂ increases from 7.658 to 9.816 wt% when the concentrations of magnesium vacancies and hydrogen dopant atoms increase from 0 to 10%. Concretely, the results reveal that the magnesium vacancies and the hydrogen doping have a beneficial effect on the hydrogen storage properties of the hydride by decreasing its desorption temperature and stability. This decrease can be explained on the one hand by the diminution of the number of Mg atoms that establish strong bonds with H atoms, and on the other hand by using the density of states, which indicates that when the concentrations increase, the Mg and H states shift to the conduction band. We also obtain that the value of the desorption temperature can be controlled by varying the concentrations of magnesium vacancies and hydrogen dopant atoms from 4.2 to 5.8% in order to reach the optimum range 289–393 K for the practical use of fuel cell vehicles.     

Applications of aeromagnetic data to detect the Basement Tectonics of Eastern Yemen region

The present study aims to throw light on the tectonic implications concerned with the distribution of the sedimentary sequence belts and the related basement complex zones, as well as to differentiate between the causative sources (contacts, dykes and faults) of Eastern Yemen region. The total intensity aeromagnetic map of the study area was first corrected by the application of the Reduction To the magnetic pole (for low latitude areas). The visual inspection of the RTP magnetic map defines a rapid change in the subsurface geologic conditions in the form of lithologic characters and tectonic inferences. On the other hand, this map showed different anomalies of varying frequencies and amplitudes that revealed various causative sources, as well as varying compositions and depths. At the interpretation stage, various techniques and software tools are available for extracting the geologic information from the data concerned. The magnetic fields of shallow sources can be separated from those of deeper causatives, using two processes known as power spectrum transformation and matched band pass filtering. Three methods for locating magnetic sources (Magnitude of Horizontal Gradients (HGM), the analytical signals (AS) and the local wavenumbers (LW)) in three dimensions and identifying the properties of their sources indicated that, the area was affected by some intrusions at various depths in sill or dyke forms, almost oriented in the NW–SE, NE–SW, E–W and N–S trends. Tectonically, the area is highly affected by the tectonics related to the Arabian Sea, Gulf of Aden and Red Sea. It is affecting both the basement and sedimentary rocks, dividing the study area into several faulted blocks.     

Compact low-power time-based conversion with noise immunity similar to digital conversion

An analog signal representation based on the inter-pulse-interval (IPI) time is presented. Voltage-to-IPI and IPI-to-voltage conversion circuits based on the representation are described. The circuits have been fabricated using a 0.35 μm mixed-signal CMOS process. Simulation and test results agree with the theory. Voltage-to-IPI conversion needs significantly less area and power than ADC and is significantly more immune to noise and other problems than using analog voltage/current signals.     

New approach to gas pressure profile prediction for high temperature AA5083 sheet forming

A new theoretical approach to the prediction of gas pressure profiles that vary smoothly with time in high temperature forming of fine-grained AA5083 sheet is presented. The required pressure-flow stress relationship, which couples the gas pressure profile and the material constitutive model, was implemented in ABAQUS implicit. Forming of a rectangular pan in a die with variable entry radii was simulated with a single creep mechanism model that accounts for hardening/softening in AA5083. Predicted sheet thickness and thinning in a die entry radius region at the end of forming are examined in detail. Results are compared with those from two additional gas pressure schemes. One of these is taken directly from experiments and the other is based upon an algorithm that is internal to ABAQUS. The effect of friction on forming time is explored in the absence of a stability criterion for necking.