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11.
Eddy characteristics on mass transfer close to free interface 总被引:1,自引:0,他引:1
The velocity fluctuations in the immediate vicinity of a free interface were measured with a hot film anemometer. And mass
transfer rates and eddy exposure times were analyzed by using the method of deterministic approach. These mass transfer rates
were compared with the mass transfer rates by means of concentration measurements in the air-water system.
The eddy exposure time distributions obtained from velocity data were skewed toward the lower time value. The contribution
of eddies wi:h small exposure time was increased as the liquid became more turbulent. The mass transfer rates were mainly
contributed by the Prandtl size eddies and even larger eddies. The mass transfer predictions by the single eddy model employing
a deterministic method were in good agreement with the experimental results by independent measurements of concentration. 相似文献
12.
ABA-type “tapered” block polymers were prepared from styrene (monomer A) and butadiene or isoprene, using an initiator of sec-butyllithium complexed with two molecules of ethyl ether. The stress–strain curves of polymers containing about 20–50% styrene show the usual resemblance to curves of crosslinked elastomers. The SBS polymers had higher tensile strengths than the SIS polymers. They also had slightly higher tensile strengths than comparable SBS polymers made with sec-butyllithium. The SIS polymers, however, had generally lower tensile strengths than those made with sec-butyllithium. This is probably caused by higher styrene content of the isoprene block, brought about by increased randomization of the styrene–isoprene copolymerization due to the presence of the ether. The A and B blocks become more compatible, producing loss of strength in the polymer. Infrared analyses of polydienes made with the sec-C4H9Li·2(C2H5)2O initiator showed a 6% to 8% increase in 1,2-content (for polybutadiene) or 3,4-content (for polyisoprene), compared to polymers made with sec-butyllithium. The polymer microstructures still have high (>80%) total 1,4-content, however. Thus, this amount of ether can be tolerated in the polymerization system without great loss of rubbery properties or block structure in the resultant polymers. 相似文献
13.
The reactions of a variety of activated vinyl compounds with cotton cellulose fabric containing quaternary ammonium hydroxide substituents were explored. Each reaction, catalyzed by the basic groups in the cellulose, was followed to or near the point of leveling off. The results are analyzed and discussed in terms of accessibility of the cellulosic compositions and in terms of the efficiency of the quaternary ammonium substituents as catalysts for the addition reactions. Estimates of relative forward rate constants (kf) and equilibrium constants (K) for the reactions were made. The values of kf for reactions of the vinyl compounds with the quaternary ammonium celluloses show a relative order which is similar to that for the reactions of the vinyl compounds with simple alcohols. Evidence is presented to indicate that, in some cases, the addition of vinyl compounds is accompanied by anionic-catalyzed graft polymerization. 相似文献
14.
Taking advantage of the unique characteristics of an ambipolar carbon nanotube field effect transistor (CNTFET), a ‘p-n junction’ is simulated along the single-walled carbon nanotube channel using two separate gates close to the source and drain of the CNTFET, respectively. The current-voltage characteristics of the double-gated CNTFET are calculated using a semiclassical method based on the Schottky barrier field effect transistor mechanism. The calculation results show a good rectification performance of the p-n junction. 相似文献
15.
Christilin D. M. Annie Brighty Mary Dr M. Safish 《Multimedia Tools and Applications》2021,80(13):19441-19457
Multimedia Tools and Applications - While denoising 3D MRI, structural preservation is a very critical process in the medical region. However, Rician noise in MRI has affected the image quality... 相似文献
16.
J. P. Carmo M. F. Silva J. F. Ribeiro R. F. Wolffenbuttel P. Alpuim J. G. Rocha L. M. Gon?alves J. H. Correia 《Microsystem Technologies》2011,17(8):1283-1291
This paper presents an approach for generating a well-defined cooling pattern over an area of tissue. An array of solid-state
microcoolers is used, which could be included in a probe that provides local cooling. This medical instrument can be used
for removal of scar tissue in the eye or for the rapid stopping of bleeding due to micro-cuts, which makes it a useful tool
to medical doctors and could make surgery more secure to the patient. The array of microcoolers is composed of 64 independent
thermo-electric elements, each controlled using an integrated circuit designed in CMOS. The independent control allows the
flexible programming of the surface temperature profile. This type of control is very suitable in case abrupt temperature
steps should be avoided. Cooling by lateral heat flow was selected in order to minimize the influence of heat by dissipation
from the electronic circuits. Moreover, a thermo-electric component with lateral heat allows fabrication of the cooling elements
using planar thin-film technology, lithography and wet etching on top of the silicon wafer. This approach is potentially CMOS
compatible, which would allow for the fabrication of the thermo-electric elements on top of a pre-fabricated CMOS wafer as
a post-process step. Each pixel is composed of thin-films of n-type bismuth telluride, Bi2Te3 and p-type antimony telluride, Sb2Te3, which are electrically interconnected as thermocouple. These materials have excellent thermoelectric characteristics, such
as thermoelectric figures-of-merit, ZT, at room temperatures of 0.84 and 0.5, respectively, which is equivalent to power-factors, PF, of 3.62 × 10−3 W K−1 m−2 and 2.81 × 10−3 W K−1 m−2, respectively. The theoretical study presented here demonstrates a cooling capability of 15°C at room temperature (300 K ≈ 27°C).
This cooling performance is sufficient to maintain a local tissue temperature at 25°C, which makes it suitable for the intended
application. A first prototype was successfully fabricated to demonstrate the concept. 相似文献
17.
Michael E. Sigman Mary R. Williams Joseph A. Castelbuono Joseph G. Colca C. Douglas Clark 《仪器科学与技术》2013,41(4):375-393
Abstract The mass spectra calculated by summing the intensities of each nominal mass over all chromatographic times, the summed ion spectra, were calculated for a set of 440 commercially available ignitable liquids that had been analyzed by gas chromatography–mass spectrometry. Each ignitable liquid is generally comprised of a mixture of chemicals, and the mixtures may be very complex in some cases, e.g., petroleum distillates, gasoline, etc. The summed ion spectra were evaluated to determine if they contained sufficient information content to allow their use for rapid and accurate identification of the ignitable liquid in a database or library. The summed ion nominal mass spectra were encoded in one bit per channel at 1% transition intensity and a set of 96,580 unique pairwise comparisons were made between spectra, resulting in an average of approximately 50 differing channels per comparison. A subset of 62 summed ion spectra were further compared by a similarity metric and found by cluster analysis to group closely along the ASTM ignitable liquid classification scheme. Receiver operator characteristic analysis of the use of the similarity index in combination with the summed ion spectra was shown to provide 99% probability of correct liquid identification and 95% probability of correct ASTM classification by primary and sub-class. Interlaboratory tests found 95% probability of correct liquid identification and 85% probability of correct ASTM classification at the primary class level. These results demonstrate the use of the summed ion spectrum as a first step in the rapid identification of an ignitable liquid by database or library searching. 相似文献
18.
Approximately 75% of the PAF present in saliva is recovered on extraction of whole saliva (0.8 vol) with chloroform/methanol/water
(2∶2∶1 v/v/v). PAF levels, determined by our recently developed radioimmunoassay, in saliva extracts ranged from 0.5–21 ng/mL
with 59% between 2–6 ng/mL. These figures, for apparently healthy subjects, are higher than previously reported levels obtained
by platelet assays. The validity of our radioimmunoassay results was checked by isolating and quantitating the PAF fraction
from whole saliva. In addition, when we examined our saliva samples by platelet aggregation, low levels of PAF, comparable
with the values found in the literature, were detected. Investigations revealed the presence of a substance(s) which inhibited
PAF-induced platelet aggregation but which did not affect the radioimmunoassay. 相似文献
19.
Dynamic deformation behavior of ultrafine-grained low-carbon steels fabricated by equal-channel angular pressing 总被引:1,自引:0,他引:1
Byoungchul Hwang Yang Gon Kim Han Sang Lee Sunghak Lee Byoung Doo Ahn Dong Hyuk Shin Chang Gil Lee 《Metallurgical and Materials Transactions A》2005,36(2):389-397
The dynamic deformation behavior of ultrafine-grained low-carbon steels fabricated by equal-channel angular pressing (ECAP)
was investigated in this study. Dynamic torsional tests, using a torsional Kolsky bar, were conducted on four steel specimens,
two of which were annealed at 480 °C after ECAP, and then the test data were compared in terms of microstructures, tensile
properties, and adiabatic shear-band formation. The equal-channel angular pressed specimen consisted of very fine, equiaxed
grains of 0.2 to 0.3 μm in size, which were slightly coarsened after annealing. The dynamic torsional test results indicated that maximum shear
stress decreased with increasing annealing time, whereas fracture shear strain increased. Some adiabatic shear bands were
observed at the gage center of the dynamically deformed torsional specimen. Their width was smaller in the equal-channel angular
pressed specimen than in the 1-hour-annealed specimen, but they were not found in the 24-hour-annealed specimen. Ultrafine,
equiaxed grains of 0.05 to 0.2 μm in size were formed inside the adiabatic shear band, and their boundaries had characteristics of high-angle grain boundaries.
These phenomena were explained by dynamic recrystallization due to a highly localized plastic strain and temperature rise
during dynamic deformation. 相似文献
20.
This study examines the role of the decision environment in how well business intelligence (BI) capabilities are leveraged to achieve BI success. We examine the decision environment in terms of the types of decisions made and the information processing needs of the organization. Our findings suggest that technological capabilities such as data quality, user access and the integration of BI with other systems are necessary for BI success, regardless of the decision environment. However, the decision environment does influence the relationship between BI success and capabilities, such as the extent to which BI supports flexibility and risk in decision making. 相似文献