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51.
T. Ahmadi A. Monshi V. Mortazavi M.H. Fathi S. Sharifi B. Hashemi Beni A. Moghare Abed M. Kheradmandfard A. Sharifnabi 《Ceramics International》2014
Nanosized hydroxyapatite (HA) powders exhibit a greater surface area than coarser crystals and are expected to show an improved bioactivity. In addition, properties of HA can be tailored over a wide range by incorporating different ions into HA lattice. The aim of this study was to prepare and characterize silicon and magnesium co-doped fluorapatite (Si–Mg–FA) with a chemical composition of Ca9.5Mg0.5 (PO4)5.5(SiO4)0.5F2 by the high-energy ball milling method. Characterization techniques such as X-ray diffraction analysis (XRD), Fourier transformed infrared spectroscopy (FTIR), energy dispersive X-ray spectroscopy (EDX) and transmission electron microscopy (TEM) were utilized to investigate the structural properties of the obtained powders. Dissolution behavior was evaluated in simulated body fluid (SBF) and physiological normal saline solution at 37 °C for up to 28 days. The results of XRD and FTIR showed that nanocrystalline single-phase Si–Mg–FA powders were synthesized after 12 h of milling. In addition, incorporation of magnesium and silicon into fluorapatite lattice decreased the crystallite size from 53 nm to 40 nm and increased the lattice strain from 0.220% to 0.296%. Dissolution studies revealed that Si–Mg–FA in comparison to fluorapatite (FA), releases more Ca, P and Mg ions into SBF during immersion. 175 ppm Ca, 33.5 ppm P and 48 ppm Mg were detected in the SBF containing Si–Mg–FA after 7days of immersion, while for FA, it was 75 ppm Ca, 21.5 ppm P and 29 ppm Mg. Release of these ions could improve the bioactivity of the obtained nanopowder. It could be concluded that the prepared nanopowders have structural properties such as crystallite size (~40 nm), crystallinity degree (~40%) and chemical composition similar to biological apatite. Therefore, prepared Si–Mg–FA nanopowders are expected to be appropriate candidates for bone substitution materials and also as a phase in polymer or ceramic-based composites for bone regeneration in tissue engineering applications. 相似文献
52.
Schiff base complex of copper-functionalized MCM-41 (Cu-complex@MCM-41) was synthesized and used as an efficient and novel heterogeneous catalyst for the oxidative coupling of thiols into corresponding disulfides and oxidation of sulfides to sulfoxides using hydrogen peroxide (H2O2) as the oxidant. An aliphatic and aromatic series of sulfides and thiols including various functional groups were successfully converted into corresponding products. The all products were obtained in good to excellent yields. The mesoporous catalyst is characterized by FT-IR spectroscopy, BET, XRD, SEM, EDS and TGA. Recovery of the catalyst is easily achieved by simple filtration and reused for several consecutive runs without significant loss of its catalytic efficiency. 相似文献
53.
Nayereh Soltani Elias Saion Mohd Zobir Hussein Maryam Erfani Alam Abedini Ghazaleh Bahmanrokh Manizheh Navasery Parisa Vaziri 《International journal of molecular sciences》2012,13(10):12242-12258
ZnS and CdS nanoparticles were prepared by a simple microwave irradiation method under mild conditions. The obtained nanoparticles were characterized by XRD, TEM and EDX. The results indicated that high purity of nanosized ZnS and CdS was successfully obtained with cubic and hexagonal crystalline structures, respectively. The band gap energies of ZnS and CdS nanoparticles were estimated using UV-visible absorption spectra to be about 4.22 and 2.64 eV, respectively. Photocatalytic degradation of methylene blue was carried out using physical mixtures of ZnS and CdS nanoparticles under a 500-W halogen lamp of visible light irradiation. The residual concentration of methylene blue solution was monitored using UV-visible absorption spectrometry. From the study of the variation in composition of ZnS:CdS, a composition of 1:4 (by weight) was found to be very efficient for degradation of methylene blue. In this case the degradation efficiency of the photocatalyst nanoparticles after 6 h irradiation time was about 73% with a reaction rate of 3.61 × 10−3 min−1. Higher degradation efficiency and reaction rate were achieved by increasing the amount of photocatalyst and initial pH of the solution. 相似文献
54.
Data from comprehensive thermomechanical tests of poly(L-lactide-co-ε-caprolactone) biodegradable shape memory polymer (SMP)
reinforced with pristine and functionalized multiwalled carbon nanotubes (MWCNTs) are reported. The SMP specimens tested up
to 500% strain and between 25 °C and 70 °C temperatures. The incorporation of functionalized MWCNTs leads to the best overall
reinforcing effect in tensile modulus, yield stress, tensile strength and elongation at failure. Thermo mechanical experiments
resulted that the functionalized MWCNTs increased the glass transition range of composites and changed the melting point of
composites slightly. The crystallinity of composites was increased with increment of MWCNTs in composites. The shape fixity
and shape recovery of composites increased slightly, while the recovery stress increased 46%. It is found that the functionalized
MWCNTs prepare an effective physical cross linking and switching segments in polymer composites. 相似文献
55.
Propane dehydrogenation on a commercial Pt-Sn/Al2O3 catalyst in a Pd-Ag membrane reactor is considered. A mathematical model is developed to evaluate the performance of the catalytic membrane reactor for the process of propane dehydrogenation. Design and operating conditions are systematically evaluated for key performance metrics such as propane conversion, propylene selectivity, hydrogen selectivity, and hydrogen recovery under different operating conditions. The results confirm that the high performance of the membrane reactor is related to the continuous removal of hydrogen from the reaction zone to shift the reaction equilibrium towards the formation of more propylene and hydrogen. 相似文献
56.
A new, efficient and recoverable heterogeneous catalyst was successfully synthesized by functionalization of mesoporous silica FSM-16. The FSM-16/CPTMS-Rh- 相似文献
57.
Seyed Mohammadreza Miraboutalebi Mohammad Peydayesh Maryam Bagheri Toraj Mohammadi 《化学工程与技术》2020,43(6):1214-1223
The potential of a novel α-Fe2O3/polyacrylonitrile (PAN) hybrid composite adsorbent to eliminate methylene blue (MB) from aqueous solution was evaluated. PAN was selected as the base composite. The presence of α-Fe2O3 as nanophotocatalyst on the surface of PAN introduced an efficient photocatalytic hybrid composite adsorbent for degrading MB. Effects of α-Fe2O3 nanopowder loading, pH, temperature, MB initial concentration, solar light, and contact time were investigated. Langmuir, Freundlich, and Temkin isotherms were applied to analyze the adsorption behavior. The Freundlich equation provided the best correlation with experimental data. Pseudo-first-order, pseudo-second-order, and intraparticle models were employed. Thermodynamic studies indicated an endotherm and spontaneous adsorption process in a defined temperature range. 相似文献
58.
59.
Maryam Ferdousi Mohammad Pazouki Fereydoun Alikhani Hessari Mahmood Kazemzad 《Journal of Porous Materials》2016,23(2):453-463
Mesoporous silica materials are attractive materials for immobilizing enzymes because of their well-ordered structures, large surface area are pore volume. Diffusion of large enzyme molecules such as porcine pancreatic lipase (PPL) through the lengthy channels of MPS takes place too slowly. Therefore, the squat of the enzyme at the pore mouth entrance, actually makes the rest of the channel useless. In this study, to overcome this problem, synthesis parameters of SBA-15 were changed, since along with pore diameter increasing, the mesochannel length becomes shorter. The main point to obtain a well-ordered 2D hexagonal pore structure was the pre-hydrolysis of tetraethyl orthosilicate (TEOS) before the addition of 1,3,5-trimethyl benzene as a micelle swelling agent. Due to the strong effect of zirconium in changing the morphology of SBA-15 particles, we modified SBA-15 in the presence of a small amount of ZrOCl2 in the synthesis solution under acidic conditions. As a result, mesochannel length of SBA-15-Zr was shortened from 600 to <200 nm. The morphology of mesoporous silica was also changed from rod-like to platelet, because of the accelerating effect of Zr(IV) on the self-assembly rate of P123 and TEOS condensation. Characteristic results conducted by low angle XRD, high resolution transmission electron microscopy and nitrogen adsorption, confirmed tuning effect of Zr(IV) in SBA-15. Furthermore, it was shown that the number of pore entrances increases with decreasing the length of SBA-15 mesochannels, leading to obvious improvement of enzyme uptake. PPL has been successfully immobilized in the mesoporous channels of SBA-15-Zr. The total amount of lipase adsorbed on the mesoporous SBA-15-Zr was measured by thermal gravimetric analysis. The largest PPL adsorption capacity was 784 mg/g belonging to the SBA-15-Zr with the length of 150 nm and the mean pore size diameter of 9.22 nm. 相似文献
60.
Salehi Maryam Zavarian Ali Asghar Arman Ali Hafezi Fatemeh Rad Ghasem Amraee Mardani Mohsen Hamze Kooros Luna Carlos Naderi Sirvan Ahmadpourian Azin 《SILICON》2018,10(6):2743-2749
Silicon - The characterization of ion beam current density distribution and beam uniformity is crucial for improving broad-beam ion source technologies. The design of the broad ion beam extraction... 相似文献