Silicon Application Enhances the Photosynthetic Pigments and Phenolic/Flavonoid Content by Modulating the Phenylpropanoid Pathway in Common Buckwheat under Aluminium Stress

Silicon - Silicon (Si) is very effective in the amelioration of heavy metal (HM) stress in different crop plants. This investigation was conducted to assess the protective role of Si in modulating...     

Microscopic Evaluation of Strain Distribution in Granular Materials during Shear

The evolution of local strains during shear of particles of a granular material is presented in this paper. A cylindrical specimen composed of 6.5-mm spherical plastic particles was loaded under an axisymmetric triaxial loading condition. Computed tomography (CT) was used to acquire three-dimensional images of the specimen at three shearing stages. The high-resolution CT images were used to identify the 3D coordinates of 400 particles. Nine strain components (normal, shear, and rotation), rotation angles, and local dilatancy angles for particle groups were calculated, and their frequency distribution histograms are presented and discussed. It was found that there is no preferred shear direction, and the standard deviation values for shear strain components (εxy, εxz, and εyz) were almost equal for the specific test shearing stage. Shear strains as high as 25.6% were recorded for some particle groups. Furthermore, granular particle groups rotated in the 3D space with almost equal amounts of rotation strains when loaded under axisymmetric triaxial condition. Rotation strain values are very close to the corresponding shear strains. Compared to particle sliding, rotation plays a major role in the shearing resistance of granular materials. The cumulative vertical rotation angles can be as high as 38° and the horizontal rotation angles have values as high as 60°. The statistical distributions of the local dilatancy angle (ψ1) of particle groups were calculated and found to be increasing as shearing continues. The “global” dilatancy angle value is very close to the mean local ψ1 during the first stage of shearing (i.e, when global εz = ?7.3%)     

Performance of PAM/PEI gel system for water shut‐off in high temperature reservoirs: Laboratory study

A polymer gel is one of the common remediate methods to either reduce or totally block excessive water production in oilfields. Some systems demonstrated an excellent performance in treating the problem like polyacrylamide tert‐butyl acrylate (PAtBA)/polyethylenimine (PEI). In this study, polyacrylamide (PAM) was introduced as a cheap alternative to PAtBA that can tolerate high salinity reservoirs. The thermal stability of the PAM/PEI polymeric gel in saline water was examined at 150°C (302F). Samples prepared in sea water showed better stability compared with distilled and field water. Dynamic rheology and core‐flooding experiments were used to evaluate the PAM / PEI gel system at high temperatures. NaCl and NH₄Cl were evaluated as a possible retarders for delaying the gelation time in order to achieve a successful placement. NH₄Cl was found to be more effective retarder. Core‐flooding tests were conducted in sandstone and carbonate cores. The subject polymer gel was injected at rates typical of those in field applications. The injectivity of PAM/PEI was tested in Berea sandstone cores with initial permeability of ～45 mD. The post‐treatment of the system showed a permeability reduction of ～94% for a period of two weeks. The injectivity in low permeability carbonate cores required more retardation compared with the injectivity in sandstone cores. The gel reduced the permeability to brine in Indiana limestone core by 99.8% for more than 5 months. Rheology of cured gel samples indicated that the gel strength needs about one day of curing in the core for the strength to stabilize. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41869.     

Nonlinear transient analysis of reinforced concrete slabs subjected to blast loading and retrofitted with CFRP composites

Computational models using the finite element method for nonlinear transient analysis of reinforced concrete (RC) two-way slabs subjected to blast loading are presented. Both as-built and retrofitted slabs with carbon fiber reinforced polymer (CFRP) composite strips are analyzed. The models are used to investigate different parameters including (a) loading duration, and (b) effect of CFRP retrofit on damage accumulation. In this study, damage is globally quantified by the amount of reduction of the first two vibrational frequencies of the slabs. Local representation of damage in terms of reinforcing steel strains is also discussed. The computational models for both the as-built and the retrofitted slabs are verified using experimental results. In these experiments, a slowly increasing uniform pressure is applied to the bottom surface of large-scale RC slab specimens using high-pressure water bag. Experimental results showed that an increase up to 200% in the load carrying capacity is achieved when using the CFRP composite retrofit system. Transient nonlinear analysis results proved the efficiency of the CFRP composite retrofit in improving the slab behavior under blast loading for different loading durations, i.e. for small, medium, and large charge weights at the same applied maximum pressure. In particular, less than 50% reduction of the fundamental frequency due to concrete damage is obtained for the retrofitted slab compared to more than 85% reduction for the as-built slab. Moreover, the maximum displacement is reduced by 40–70% with the CFRP retrofit compared to the as-built slab. As for reinforcing steel strains, the application of CFRP retrofit significantly limited the spread of yielding in time and space. The improved slab behavior with CFRP is best when retrofitting is applied to both sides of the slab.     

Preparation of high pure α-Al2O3 nanoparticles at low temperatures using Pechini method

A Pechini process was successfully used to synthesize alpha-alumina (98.95% mass fraction) at relatively low calcination temperature (925 °C). The synthesis of these nanoparticles was carried out using a polymer prepared from citric acid and ethylene glycol by the melt blending method. This polymer worked as a chelating agent for aluminum cations. The final products were produced after a dual-stages thermal treatment. The resulting α-alumina consisted of nanoparticles of 8–16 nm in diameters with a surface area (～8 m² g^?1). The mass fraction of α-alumina was dependent on the concentration of aluminum salt and polymer precursor's solutions, while the surface area of the final product was dependent on the mass fraction of θ-alumina.     

Service based communication for MPSoC platform-SegBus

MPSoC platforms offer solutions to deal with communication limitations for multiple cores on single chip, but many new issues arise within the context. The SegBus platform is one of the solutions for application deployment on multi-core applications. There are many applications where identical data is transferred from the same source towards different destinations. Multicast services may come as a performance improving factor for the interconnection platform, together with interrupt service.In this paper, the task is to analyze, how different services can be designed for the SegBus platform and observe the improvement in system performance. The designer can select the services according to the requirements. The running example is represented by the H.264 encoder. The SegBus platform architecture, the communication mechanism, the allocation of processing elements on the platform, the communication services and their implementation are the main topics elaborated here.     

Microstructural evolution during friction surfacing of tool steel H13

Coatings of AISI H13 tool steel were made on low carbon steel by friction surfacing. Detailed microstructural studies and microhardness tests were carried out on the coatings. Studies revealed defect-free coatings and sound metallurgical bonding between the coating and the substrate. In addition, mechanical interlocking on a very fine scale was observed to occur between the coating and the substrate. Coatings exhibited martensitic microstructure with fine grain size and with no carbide particles. Coatings in as-deposited condition showed very high hardness (58 HRC) compared to the mechtrode material in annealed condition (20 HRC). Based on these findings, microstructural evolution during friction surfacing of H13 tool steel is discussed. The current work shows that friction surfaced tool steel coatings are suitable for use in as-deposited condition. Further improvements in coating microstructure and properties are possible with appropriate post-surfacing heat treatment.     

Stress Generated on Aluminum During Anodization as a Function of Current Density and pH

Anodic oxidation is accompanied by stressgeneration during the growth of the oxide. The presentstudy focuses on the stress-generation mechanism onaluminum as a function of the applied current density in acidic solutions of sulfuric acid ofdifferent strengths giving variable pH. Abeam-deflection technique was utilized for thedetermination of the magnitude and direction of stressesgenerated during the anodic oxidation process. Generally,thickness of the oxide determines whether the stress iscompressive or tensile in nature. The results have beeninterpreted in terms of the formation and annihilation of anion (O^2-) and cation(Al³⁺) vacancies. A reduction in thealuminum-ion vacancy concentration (V Al ³ ) results in a compressive stressdeflection, whereas tensile-stress deflection isintroduced by an increase in the oxygen vacancy(Vo²⁺) concentration. The mechanism isfurther elucidated by current-density jump/dropexperiments. The results show that stress in this caseis affected by the dissolution of the oxide at the oxide-electrolyteinterface.     

Low-Temperature Preparation and Magnetic Properties of V-Doped SnO2 Nanoparticles

A solid solution of vanadium (V)-doped tin oxide (SnO₂) particles of average diameter 2 nm and V content of 19 at.% was prepared at normal pressure and low temperature (100°C) by mixing wet SnO₂ gel SnO₂· x H₂O with a boiling solution of vanadium oxide (V₂O₅). Experimental characterizations using X-ray, electron diffraction, and transmission electron microscope show evidence of a pure single phase. The nanoparticles exhibit a mixed magnetic behavior, namely paramagnetic and ferromagnetic. Their thermal stability is also investigated. At higher temperature, 850°C, some amount of Fe precipitates from the solid solution.