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941.
942.
    
Biological strategies for bottom-up synthesis of inorganic crystalline and amorphous materials within topographic templates have recently become an attractive approach for fabricating complex synthetic structures. Inspired by these strategies, herein the synthesis of multi-layered, hierarchical inverse colloidal crystal films formed directly on topographically patterned substrates via evaporative deposition, or \"co-assembly\", of polymeric spheres with a silicate sol-gel precursor solution and subsequent removal of the colloidal template, is described. The response of this growing composite colloid-silica system to artificially imposed 3D spatial constraints of various geometries is systematically studied, and compared with that of direct colloidal crystal assembly on the same template. Substrates designed with arrays of rectangular, triangular, and hexagonal prisms and cylinders are shown to control crystallographic domain nucleation and orientation of the direct and inverse opals. With this bottom-up topographical approach, it is demonstrated that the system can be manipulated to either form large patterned single crystals, or crystals with a fine-tuned extent of disorder, and to nucleate distinct colloidal domains of a defined size, location, and orientation in a wide range of length-scales. The resulting ordered, quasi-ordered, and disordered colloidal crystal films show distinct optical properties. Therefore, this method provides a means of controlling bottom-up synthesis of complex, hierarchical direct and inverse opal structures designed for altering optical properties and increased functionality.  相似文献   
943.
    
In process-based restoration, the objective is not to create a complex river form directly; instead, interventions are intended to “prompt” the natural processes to restore such forms. The improvements in ecological conditions are actually made over time by flowing water during floods (using the stream’s energy), and by the growth of riparian vegetation (using incoming solar energy). On the Aire River in Geneva, ecological function was restored to a formerly canalized river by providing the river with an espace de liberté. A grid of channels cut into the valley bottom allowed the river to freely flood, erode its bed and banks, and deposit bars, creating complex surfaces on which riparian vegetation established to support the food web of the riverine ecosystem. The diamond-shaped bits of land left between these channels (“lozenges”) gradually erode and evolve as the river migrates, creating complex channel forms. The Isar River in Munich restoration involved adding coarse sediment load, creating erodible bed and banks in place of formerly rigid boundaries, expanding process space for river migration, erosion, and deposition, and increased human access to the river over 8 km. Since restoration, natural transport of sediment has resulted in deposition of gravel bars, whose forms evolve during floods, supporting diverse habitats. The Isar and Aire Rivers provide compelling examples of processbased restoration meeting 4 criteria for process-based restoration: space, energy, materials, and time. They demonstrate the possibilities of urban river restoration to achieve both ecological and social goals through restoration of fluvial process.  相似文献   
944.
945.
The novel nanostructures are fabricated by the spatial chemical modification of nanowires within the anodic aluminum oxide (AAO) template. To make the nanowires better dispersion in the aqueous solution, the copper is first deposited to fill the dendrite structure at the bottom of template. During the process of self-assembly, the dithiol compound was used as the connector between the nanowires and nanoparticles by a self-assembly method. The nanostructures of the nano cigars and structure which is containing particles junction are characterized by transmission electron microscopy (TEM). These kinds of novel nanostructure will be the building blocks for nanoelectronic and nanophotonic devices.   相似文献   
946.
The aim of this study was to test mechanically a new flexible fixation system for the lumbar spine. This device incorporates loops of polyester braid which are secured by a crimped titanium sleeve. In tensile tests, all loops failed, by slippage through the crimped sleeve, at 434 +/- 25 N (mean +/- standard deviation from five loops) for a single crimp and 415 +/- 15 N (from five loops) for two crimps. The intact system was then tested according to the ASTM standard. In a static test, all five specimens failed by slippage of the braid through the sleeve. Initial slippage occurred between 600 and 700 N, but the mean maximum load sustained was 1090 +/- 140 N. Dynamic tests were performed on ten constructs at a frequency of 5 Hz, under a range of loading conditions. The maximum load applied in any of the tests was 825 N. Two constructs did not complete the required 5 x 10(6) test cycles because of fracture of their spinous process hooks. However, other tests, under the same conditions, showed no signs of failure. Fracture occurred as a result of fretting damage from the recommended stainless steel roll pins.  相似文献   
947.
Biolubricants and triboreactive materials for automotive applications   总被引:1,自引:0,他引:1  
The research institution TEKNIKER has coordinated the EUROPEAN Project EREBIO, were different biodegradable lubricants have been formulated by FUCHS and BAM for heavy duty engines (GUASCOR), and passenger cars (RENAULT). In the frame of this article, it has been summarised the results obtained when developing biodegradable passenger car lubricants in combination with triboreactive materials.Replacing hydrocarbon-based oils with biodegradable products is one of the ways to reduce adverse effects on the ecosystem caused by the use of lubricants. The application of low or no sulphur, ash and phosphorous (lowSAP) ester- or polyglycol-based oils, intended for passenger car engine lubricants as substitutes for hydrocarbon-based oils, required the preparation of a composition of lubricants with comparable tribological and functional properties.The study is focussed on passenger car motor oils (PCMO) with reduced metal-organic additives. This is necessary in order to reduce the ash build-up in the after treatment system and therefore improve its efficiency and lifetime. High fuel efficiency and long drain intervals are requested, as well. To follow a line in a consequent way, these oils have to be biodegradable and non-toxic to the aqueous environment according to the directive EC/1999/45, coherent with other international standard. In a modern diesel or gasoline engine, the engine oils has to fulfil quite a number of different functions, such as lubricating and cooling the system, wear protection, soot and particle handling with less deposit tendency and so on.In the paper a study of the biodegradability, toxicity and the tribological properties has been carried out for new developed prototype engine bio-oils. Also, some different plasma sprayed triboreactive coatings have been deposited on cast iron piston rings, being studied also their tribological properties. Finally, the behaviour of the new bio-oils selected and plasma sprayed triboreactive coatings on piston rings have been screened in a real engine.  相似文献   
948.
Modelling of metal forming processes is an essential task of production engineering. Due to the latest technological developments, a huge variety of models is already available and extending continuously. Thus, it is important to find a suitable model. This paper gives an overview on the common classification and characterization of modelling and models in metal forming, as well as introduces a model selection procedure. Based on this classification, various relevant process limits for metal forming are investigated regarding existing models. The conclusion of the paper shows open topics as well as upcoming challenges in modelling process limits in metal forming.  相似文献   
949.
This work presents a framework for automatic feature extraction from images using stochastic geometry. Features in images are modeled as realizations of a spatial point process of geometrical shapes. This framework allows the incorporation of a priori knowledge on the spatial repartition of features. More specifically, we present a model based on the superposition of a process of segments and a process of rectangles. The former is dedicated to the detection of linear networks of discontinuities, while the latter aims at segmenting homogeneous areas. An energy is defined, favoring connections of segments, alignments of rectangles, as well as a relevant interaction between both types of objects. The estimation is performed by minimizing the energy using a simulated annealing algorithm.The proposed model is applied to the analysis of Digital Elevation Models (DEMs). These images are raster data representing the altimetry of a dense urban area. We present results on real data provided by the IGN (French National Geographic Institute) consisting in low quality DEMs of various types.  相似文献   
950.
An Artificial Bee Colony algorithm was presented by Sonmez (Struct Multidisc Optim 43:85–97, 2011) for solving discrete truss design problems. It was numerically tested on four benchmark examples and concluded to be robust and efficient. We compare the Artificial Bee Colony algorithm numerically to three alternative heuristics on the same benchmark examples. The most advanced heuristics presented herein find equally good, or better, designs compared to those presented in Sonmez (Struct Multidisc Optim 43:85–97, 2011). However, for the largest benchmark example, we use four orders of magnitude fewer function evaluations.  相似文献   
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