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991.
Ruopei Xu Yue Qiu Siyi Tang Cheng Yang Yu Dai Dajie Zhang Yue Gao Kexiong Gao Longbo Luo Xiangyang Liu 《大分子材料与工程》2021,306(5):2000814
High performance fibers with high strength and toughness have great potential in composites, but contradiction between tensile strength and elongation at break makes the preparation to become a current challenge. Herein, an asymmetric structure of more flexible diamine, 3,4′-diaminodiphenyl ether (3,4′-ODA), is introduced into heterocyclic aramid (PBIA) fibers to replace rigid symmetric p-phenylenediamine (PDA). By studying the properties of copolymer (mPEBA) fibers with different ratios of diamine, it is found that the mPEBA fiber reached the optimal mechanical properties with the 30% content of 3,4′-ODA. Compared with homopolymerized heterocyclic aramid fibers, the tensile strength and elongation at break of mPEBA fiber are improved by 26.2% and 38.7%, respectively. Results of X-ray diffraction show that the introduction of 3,4′-ODA structure can increase stretchability of mPEBA fibers, improving the orientation degree during hot-drawing. Molecular dynamics simulations confirm that 3,4′-ODA structure undergoes a conformation transformation to form a straightened chain during hot-drawing, while symmetrical 4,4′-diaminodiphenyl ether (4,4′-ODA) cannot form the same conformation. The misplaced-nunchaku structure is formed based on the special meta-para position of 3,4′-ODA, achieving the synergy of high strength and high toughness. 相似文献
992.
Fiber-based hygroresponsive torsional actuators provide desirable merits, such as light weight and shapeability, for developing smart systems to harvest energy from moisture which is a ubiquitous natural resource. A key challenge in this development is to realize moisture-triggered actuation combining large actuation and rapid responses. Here, a multiscale design strategy is explored to create high-performance hygroresponsive torsional actuators consisting of chitosan and multiwalled carbon nanotubes (MWCNTs). The superior actuation performance arises from the synergism of contributing factors at different scales, including 1) MWNCTs accelerate the water transport in primary twisted fibers (PTFs), fostering the rotation of PTFs upon moisture stimuli; 2) in situ-formed hierarchically-assembled twists realize cascade amplification of moisture-triggered actuation. Specifically, PTFs are self-twisted to generate secondary helical yarns, that are subsequently over-twisted to yield tertiary coiled yarn. The resultant yarn actuator can reach a maximum rotation speed of 11 400 rpm in 5 s, output gravitational potential energy of 2.4 J kg−1 and gravitational potential power of 0.053 W kg−1 during contraction. This work represents the first design of fiber-based actuators by virtue of moisture-triggered in situ formation of yarns. The established principles of multiscale design will enable high-performance fiber-based hygroresponsive actuators toward advanced intelligent textile and soft robotics. 相似文献
993.
Qianyu Yang Chen Gao Xuemei Zhang Chihui Tsou Xingyu Zhao Manuel Reyes De Guzman Zejun Pu Xinyue Li Yue Lu Chunyan Zeng Li Yuan Yiqing Xia Yuping Sheng Yiqing Fu 《大分子材料与工程》2021,306(7):2100093
Hydrogels with excellent stiffness, toughness, anti-fatigue, and self-recovery properties are regarded as promising water-containing materials. In this work, a dual physically cross-linked (DPC) sodium alginate (SA)/poly[acrylamide (AAm)-acrylic acid (AAc)-octadecyl methacrylate (OMA)]-Fe3+ hydrogel is reported, which is constructed by hydrophobic association (HA) and ionic coordination (IC). The optimal DPC hydrogel demonstrates excellent mechanical performance: tensile modulus of 0.65 MPa, tensile strength of 3.31 MPa, elongation at break of 1547%, and toughness of 27.8 MJ m–3. SA/P(AAm-AAc-OMA)-Fe3+ DPC hydrogels also exhibit prominent anti-fatigue and self-recovery performance (99.1–109.7% modulus recovery and 90.4–108.9% dissipated energy recovery after resting for 5 min without additional stimuli at ambient temperature) through the reconstruction of reversible physical cross-linking. Some of the SA/P(AAm-AAc-OMA)-Fe3+ DPC hydrogels even exhibit a stretching-induced strengthening effect, which is similar to the performance of muscle—“the more training, the more strength.” Hence, the combination of HA and IC will provide an effective approach to design DPC hydrogels with desirable mechanical performances and a longer service life for wider applications of soft materials. 相似文献
994.
Jihao Wang Yufen Han Zhiyang Xu Xiaozhen Yang Seeram Ramakrishna Yong Liu 《大分子材料与工程》2021,306(4):2000724
Polymer systems have typical multiscale characteristics, both in space and time. The mesoscopic properties of polymers are difficult to describe through traditional experimental approaches. Dissipative particle dynamics (DPD) is a simulation method used for solving mesoscale problems of complex fluids and soft matter. The mesoscopic properties of polymer systems, such as conformation, dynamics, and transport properties, have been studied extensively using DPD. This paper briefly summarizes the application of DPD to research involving microchannel flow, electrospinning, free-radical polymerization, polymer self-assembly processes, polymer electrolyte fuel cells, and biomedical materials. The main features and possible development avenues of DPD are described as well. 相似文献
995.
996.
Shishan Xue Guanfei Liu Jingjuan Lai Peng An Yang Liu Yuanpeng Wu Yu Wang Zhiyong Ye Qiao Tang Hongwei Zhou 《大分子材料与工程》2021,306(11):2100415
Self-healing hydrogels often possess poor mechanical properties which largely limits their applications in many fields. In this work, boron nitride nanosheets are introduced into a network of the poly(vinyl alcohol)/borax (PVA/borax) hydrogels to enhance the mechanical properties of the hydrogel without compromising the self-healing abilities. The obtained hydrogels exhibit excellent mechanical properties with a tensile strength of 0.410 ± 0.007 MPa, an elongation at break of 1712%, a Young's Modulus of 0.860 ± 0.023 MPa, and a toughness of 3.860 ± 0.075 MJ m−3. In addition, the self-healing efficiency of the hydrogels is higher than 90% within 10 min at room temperature. Benefiting from the excellent self-healing properties, the shapeability of the hydrogel fragments is observed using different molds. In addition, the hydrogels display rapid pH-driven shape memory effects and can recover to their original shape within 260 s. Overall, this work provides a new approach to hydrogels with integrated excellent mechanical properties, self-healing abilities, and rapid pH-driven shape memory effects. 相似文献
997.
Zhiqiang Wu Qiang Guo Yang Liu Huihui Zhou Hua Zheng Xingfeng Lei Lei Gong Yanhui Chen Zhenguo Liu Qiuyu Zhang 《大分子材料与工程》2021,306(11):2100456
In order to meet the requirements of polymer dielectric materials for high thermal stability and excellent dielectric properties in the application of high-temperature film capacitors, a series of polyimide (PI) films are fabricated by introducing a self-synthesized aniline trimer (ACAT) with a conjugated structure in this work. Since the conjugated ACAT in the main chains of PI improves the electron polarization and carrier mobility of the PI molecular chains, the dielectric constant of the ACAT-PI films is greatly enhanced (4.4–7.4). Meanwhile, the dissipation factor does not increase apparently (0.002–0.013). The dielectric properties are stable even when the temperature is up to 200 °C, the thermal degradation temperature is as high as 450 °C, and the mechanical properties are also excellent (70–105 MPa). Among all the films, the PI film with 5 mol% ACAT exhibits the maximal energy density of 3.6 J cm−3 under the field of 426 kV mm−1, the high tensile strength (90 MPa) and the excellent thermal stability (Td5 = 515 °C). The work paves the way to prepare high-temperature polymer dielectric film materials with high energy storage density. 相似文献
998.
999.
Yang Zhu Xiangli Meng Qiang Zhang Liansheng Yan Hong Cui 《International Journal of Applied Ceramic Technology》2021,18(4):1330-1341
A 3D architecture carbon fiber preform, specifically fine-woven cloth and punctured felt preform, is used to manufacture a novel advanced Cf/C-SiC-ZrC composite. The composite matrix is produced by chemical vapor infiltration (CVI) plus precursor infiltration and pyrolysis (PIP) process and finalized by using a chemical vapor deposition (CVD) of SiC coating to make the final density of the material reach 1.95 g/cm3. The organic precursors of SiC and ZrC have a weight ratio of 4:1 in a xylene solute. The composite mechanical properties, such as tensile, compression, bending, shear, and Z-direction load bearing, are introduced under analysis to find possible applications for the composite. What is more, scanning electron microscope (SEM) images are employed to illustrate the failure behavior of the ceramic composite. The results showed that the punctured filament tows will be beneficial, not only for the composite to withstand compression force up to 308.6 MPa and shear strength to 18.14 MPa but also for the alternatively stacked weave piles and short fiber layers to support the punctured bundles, as well as to hold the composite structure under mechanical forces from different orientations, which is believed to reinforce the ceramic matrix for some high pressure and severe ablation applications. 相似文献
1000.
Sajjad Muhammad Asif Sana Ullah Guan Linlin Jiao Yangjing Jiang Yuhan Zhang Linlin Wen Jia Zhang Shuyu Lin Yuting Zhang Shuangshuang Ding Zhiwei Ren Yang Zhou Xiaowei Hu Wanbiao Liu Zhu 《Journal of Inorganic and Organometallic Polymers and Materials》2021,31(11):4440-4441
Journal of Inorganic and Organometallic Polymers and Materials - The original version of this article unfortunately contained mistakes. In line 9 of the abstract, 5% should read as 2%. The... 相似文献