Use of optimization methods to solve heat convection problems with unknown wall boundary conditions

In convection heat transfer problems, it is convenient to solve the governing differential equations by using straightforward marching techniques for numerical integration. However, the boundary layer equations in these heat transfer problems are not of the initial value type even though they are parabolic equations. Consequently marching techniques are not successful until correct initial values are known. A means of determining these initial values is presented herein. Selected optimization methods are utilized in conjunction with marching integration techniques to solve third- and fourth-order ordinary differential equations which have three unknown initial boundary conditions. Two optimization methods, one deterministic and the other non-deterministic in nature, are used both independently and in combination as determined by the particular circumstances. Two applications are used to demonstrate the technique and comparison is made with existing solutions.     

The structural efficiency of orthotropic stalks,stems and tubes

An optimised structure is one which uses the smallest quantity of the best material to perform its function, with adequate safety factor or margin for error. Structural optimisation occurs not only in mechanical engineering, but also in nature: plants with hollow stems or stalks gain a height advantage, and are thus more efficient, by approaching the optimum shape. Here we consider the optimisation of orthotropic tubes, typifying, in a mechanical sense, stalk and stem. The stiffness and strength of orthotropic tubes of initially circular section are reviewed, and diagrams are proposed which allow the optimum section shape to be selected.     

Suppression of the zero-order diffracted beam from a pixelated spatial light modulator by phase compression

Phase compression is used to suppress the on-axis zero-order diffracted (ZOD) beam from a pixelated phase-only spatial light modulator (SLM) by a simple modification to the computer generated hologram (CGH) loaded onto the SLM. After CGH design, the phase of each SLM element is identically compressed by multiplying by a constant scale factor and rotated on the complex unit-circle to produce a cancellation beam that destructively interferes with the ZOD beam. Experiments achieved a factor of 3 reduction of the ZOD beam using two different liquid-crystal SLMs. Numerical simulation analyzed the reconstructed image quality and diffraction efficiency versus degree of phase compression and showed that phase compression resulted in little image degradation or power loss.     

Effective cleaning of hexagonal boron nitride for graphene devices

Hexagonal boron nitride (h-BN) films have attracted considerable interest as substrates for graphene. ( Dean, C. R. et al. Nat. Nanotechnol. 2010 , 5 , 722 - 6 ; Wang, H. et al. Electron Device Lett. 2011 , 32 , 1209 - 1211 ; Sanchez-Yamagishi, J. et al. Phys. Rev. Lett. 2012 , 108 , 1 - 5 .) We study the presence of organic contaminants introduced by standard lithography and substrate transfer processing on h-BN films exfoliated on silicon oxide substrates. Exposure to photoresist processing adds a large broad luminescence peak to the Raman spectrum of the h-BN flake. This signal persists through typical furnace annealing recipes (Ar/H(2)). A recipe that successfully removes organic contaminants and results in clean h-BN flakes involves treatment in Ar/O(2) at 500 °C.     

Object-oriented analysis-synthesis coding based on moving two-dimensional objects

An object-oriented analysis-synthesis coder is presented which encodes arbitrarily shaped objects instead of rectangular blocks. The objects are described by three parameter sets defining their motion, shape and colour. Throughout this contribution, the colour parameters denote the luminance and chrominance values of the object surface. The parameter sets of each object are obtained by image analysis based on source models of moving 2D-objects and coded by an object-dependent parameter coding. Using the coded parameter sets an image can be reconstructed by model-based image synthesis. In order to cut down the generated bit-rate of the parameter coding, the colour updating of an object is suppressed if the modelling of the object by the source model is sufficiently exact, i.e., if only a relatively small colour update information would be needed for an errorless image synthesis. Omitting colour update information, small position errors of objects denoted as geometrical distortions are allowed for image synthesis instead of quantization error distortions. Tolerating geometrical distortions, the image area to be updated by colour coding can be decreased to 4% of the image size without introducing annoying distortions. As motion and shape parameters can efficiently be coded, about 1 bit per pel remains for colour updating in a 64 kbit/s coder compared to about 0.1 bit per pel in the standard reference coder (RM8) of the CCITT. Experimental results concerning the efficient coding of motion and shape parameters are given and discussed. The coding of the colour information will be dealt with in further research.     

Simulating Single Event Transients in VDSM ICs for Ground Level Radiation

This work considers a SET (single event transient) fault simulation technique to evaluate the probability that a transient pulse, born in the combinational logic, may be latched in a storage cell. Fault injection procedures and a fast fault simulation algorithm for transient faults were implemented around an event driven simulator. A statistical analysis was implemented to organize data sampled from simulations. The benchmarks show that the proposed algorithm is capable of injecting and simulating a large number of transient faults in complex designs. Also specific optimizations have been carried out, thus greatly reducing the simulation time compared to a sequential fault simulation approach.     

Thermal behaviour of hydroxides, hydroxysalts and hydrotalcites

Mass spectrometric analysis of gases evolved during thermal decomposition of divalent metal hydroxides, hydroxysalts and hydrotalcites show that all these compounds undergo dehydration in the temperature range 30 <T < 220°C followed by decomposition at temperatures above 250°C. The latter step involves simultaneous deanation and dehydroxylation of the layers. Our observations conclusively prove that alternative mechanisms which envisage CO₂ evolution due to deanation at lower temperatures proposed by Kanezaki to be wrong.     

Spatially resolved electronic and vibronic properties of single diamondoid molecules

Diamondoids are a unique form of carbon nanostructure best described as hydrogen-terminated diamond molecules. Their diamond-cage structures and tetrahedral sp3 hybrid bonding create new possibilities for tuning electronic bandgaps, optical properties, thermal transport and mechanical strength at the nanoscale. The recently discovered higher diamondoids have thus generated much excitement in regards to their potential versatility as nanoscale devices. Despite this excitement, however, very little is known about the properties of isolated diamondoids on metal surfaces, a very relevant system for molecular electronics. For example, it is unclear how the microscopic characteristics of molecular orbitals and local electron-vibrational coupling affect electron conduction, emission and energy transfer in the diamondoids. Here, we report the first single-molecule study of tetramantane diamondoids on Au(111) using scanning tunnelling microscopy and spectroscopy. We find that the diamondoid electronic structure and electron-vibrational coupling exhibit unique and unexpected spatial correlations characterized by pronounced nodal structure across the molecular surfaces. Ab initio pseudopotential density functional calculations reveal that much of the observed electronic and vibronic properties of diamondoids are determined by surface hydrogen terminations, a feature having important implications for designing future diamondoid-based molecular devices.     

Amphiphilic four-helix bundle peptides designed for light-induced electron transfer across a soft interface

A family of four-helix bundle peptides were designed to be amphiphilic, possessing distinct hydrophilic and hydrophobic domains along the length of the bundle's exterior. This facilitates their vectorial insertion across a soft interface between polar and nonpolar media. Their design also now provides for selective incorporation of electron donor and acceptor cofactors within each domain. This allows translation of the designed intramolecular electron transfer along the bundle axis into a macroscopic charge separation across the interface.     

Grasshoppers (Orthoptera,Saltatoria) on alpine and dealpine riverbanks and their use as indicators for natural floodplain dynamics

Gravel banks with sparse vegetation are typical habitats of braided alpine and dealpine floodplains. They are not only habitats for semiaquatic or hygrophilous organisms, but include also xerophilous elements: 17 species of grasshoppers were recorded in the floodplain of the Upper Isar (Bavaria, FRG). In the alpine region, two species (Bryodema tuberculata, Chorthippus pullus) occur only in floodplains, colonizing young gravel banks with sparse vegetation. Population dynamics and habitat selection of Bryodema tuberculata, studied on the Upper Isar for several years, are characterized by small scale movements of marked individuals between neighbouring gravel banks and fluctuations of the abundance on different sections of the gravel banks. Furthermore, the periodic desiccation of small watercourses is important for the dispersal of the females by walking. Historically widespread, today its distribution corresponds to the few remaining inundation areas. The main causes of decrease and extinction in most localities are man-made changes in floodplain dynamics. The building of retention reservoirs and the diverting of streams for hydropower influenced succession in the downstream floodplains. Most of the gravel banks with sparse vegetation changed into willow thickets or pine forests. All remaining inundation areas should be protected. Bryodema tuberculata is a good indicator for the balance between progressing succession and the reorganization of gravel banks by floods.