Atomic layer deposition of calcium oxide and calcium hafnium oxide films using calcium cyclopentadienyl precursor

Calcium oxide and calcium hafnium oxide thin films were grown by atomic layer deposition on borosilicate glass and silicon substrates in the temperature range of 205–300 °C. The calcium oxide films were grown from novel calcium cyclopentadienyl precursor and water. Calcium oxide films possessed refractive index 1.75–1.80. Calcium oxide films grown without Al₂O₃ capping layer occurred hygroscopic and converted to Ca(OH)₂ after exposure to air. As-deposited CaO films were (200)-oriented. CaO covered with Al₂O₃ capping layers contained relatively low amounts of hydrogen and re-oriented into (111) direction upon annealing at 900 °C. In order to examine the application of CaO in high-permittivity dielectric layers, mixtures of Ca and Hf oxides were grown by alternate CaO and HfO₂ growth cycles at 230 and 300 °C. HfCl₄ was used as a hafnium precursor. When grown at 230 °C, the films were amorphous with equal amounts of Ca and Hf constituents (15 at.%). These films crystallized upon annealing at 750 °C, showing X-ray diffraction peaks characteristic of hafnium-rich phases such as Ca₂Hf₇O₁₆ or Ca₆Hf₁₉O₄₄. At 300 °C, the relative Ca content remained below 8 at.%. The crystallized phase well matched with rhombohedral Ca₂Hf₇O₁₆. The dielectric films grown on Si(100) substrates possessed effective permittivity values in the range of 12.8–14.2.     

Identifying software project risks in Nigeria: an International Comparative Study

We report a study where software project risk factors were solicited in Nigeria. The study repeats a research design, which has been used in a Delphi study in the U.S., Finland, and Hong Kong to rank software development risks. The study produces a rank-order list of software risk factors and compares results with the earlier study, showing significant differences. Obtained rankings signal the importance of the infrastructure related and socio-economic software risks in developing countries like Nigeria. This demonstrates the importance of understanding the broader socio-economic context in identifying and managing software risks. The study also shows that some risks in Nigeria are located on a different scale. The choice of contingent mitigation strategies of project managers play a less important role, because the risks are so deeply engrained with the poor quality of basic infrastructure services.     

Weight initialization with reference patterns

The problem of weight initialization in multilayer perceptron networks is considered. A new computationally simple weight initialization method based on the usage of reference patterns is presented. A reference pattern is a vector which is used to represent data points that fall in its vicinity in the data space. On one hand, the proposed method aims to set the initial weight values to be such that inputs to network nodes are within the active region (in other words, nodes are not saturated). On the other hand, the goal is to distribute the discriminant functions formed by the hidden units evenly into the input space area where training data is located. The proposed method is tested with the widely used two-spirals classification benchmark problem and channel equalization problem where several alternatives for obtaining suitable reference patterns are investigated. Also, the effect of the initialization is studied when two commonly used cost functions are used in the training phase. These are the mean square error and relative entropy cost functions. A comparison with the conventional random initialization shows that significant improvement in convergence can be achieved with the proposed method. In addition, the computational cost of the initialization was found to be negligible compared with the cost of training.     

化学分离法分析大型纸浆发电厂废渣中生物质底灰和飞灰成分(英文)

采用三步分离法,其中第一步用水,第二步用乙酸铵,第三步用盐酸,提取纸浆发电厂生物质飞灰和底灰的组分,以评估这些残渣的浸出行为。除了Mo、S、Na以及那些浓度低于检测范围的元素外,在这两种灰份中,对于其他元素这三种浸出剂的浸出能力从弱到强的顺序为:水、乙酸铵和盐酸。采用三步分离法处理的废渣中元素浓度比前期用BCR连续提取法得到的低。     

Strategies for software-based hybrid business models

The open source approach to software development has been used by software organizations in tandem with their existing business models, which are based on proprietary software licensing. This led to the creation of hybrid business models that merge open source and proprietary paradigms. This paper explores the practices used by software product vendors using hybrid business models and proposes strategies emerging out of these practices using interpretive, single case study research design.     

Multi-channel energy detection under phase noise: analysis and mitigation

For the development of highly integrated, flexible and low-cost cognitive radio (CR) devices, simple transceiver architectures, like direct-conversion receiver, are expected to be deployed and provide viable radio frequency (RF) spectrum sensing solutions for practical implementation. Yet, this can be very challenging task especially if spectrum sensing and down-conversion are conducted over multiple RF channels simultaneously for improved efficiency in channel scans. Then, the so-called dirty RF problem that degrades link performance of traditional transmission systems starts to be influential from spectrum sensing perspective as well. The unavoidable RF impairments, e.g., oscillator phase noise in direct-conversion receiver, could generate crosstalk between multiple channels that are down-converted simultaneously, and thus considerably limit the spectrum sensing capabilities. Most of the existing spectrum sensing studies in literature assume an ideal RF receiver and have not considered such practical RF hardware problem. In this article, we study the impact of oscillator phase noise on energy detection (ED) based spectrum sensing in multi-channel direct-conversion receiver scenario. With complex Gaussian primary user (PU) signal models, we first derive the detection and false alarm probabilities in closed-form expression. The analytical results, verified through extensive simulations, show that the wideband multi-channel sensing receiver is very sensitive to the neighboring channel crosstalk induced by oscillator phase noise. More specifically, it is shown that the false alarm probability of multi-channel energy detection increases significantly, compared to the ideal RF receiver case. The exact performance degradation depends on the power of neighboring channels as well as statistical characteristics of the phase noise in the deployed receiver. In order to prevent such performance degradation in spectrum identification, an enhanced energy detection technique is proposed. The proposed technique calculates the leakage power from neighboring channels for each channel and improves the sample energy statistics by subtracting this leakage power from the raw values. An analytical expression is derived for the leakage power which is shown to be a function of power spectral levels of neighboring channels and 3-dB bandwidth of phase noise process. Practical schemes for estimating these two quantities are discussed. Extensive computer simulations show that the proposed enhanced detection yields false alarm rates that are very close to those of an ideal RF receiver and hence clearly outperforms classical energy detection.     

The Effects of KCl,NaCl and K<Subscript>2</Subscript>CO<Subscript>3</Subscript> on the High-Temperature Oxidation Onset of Sanicro 28 Steel

The present study investigates the early stages in the oxidation process of Sanicro 28 (Fe31Cr27Ni) stainless steel when exposed to an alkali salt (KCl, NaCl or K₂CO₃) for 2 h at 450 and 535 °C. After the exposure, the oxidized samples were analyzed with a combinatory method (CA, XPS and SEM–EDX). It was found that all three salts were corrosive, and the overall oxidation reaction rate was much higher at 535 °C than at 450 °C. There were clear differences in terms of the impact of cations (Na⁺, K⁺) and anions (Cl^?, CO₃ ^2?) on the initial corrosion process at both temperatures. When focusing on the cations, the presence of potassium ions resulted in a higher rate of chromate formation than in the presence of sodium ions. When studying the effect of anions, the oxidation of iron and chromium occurred at higher rates in the presence of both chloride salts than in the presence of the carbonate salt, and chloride salts seemed to possess higher diffusion rate in the gas phase and along the surface than carbonate salts. Moreover, at the higher temperature of 535 °C, the formed chromate reacted further to chromium oxide, and an ongoing oxidation process of iron and chromium was identified with a significantly higher reaction rate than at 450 °C.