Photoswitchable Superabsorbency Based on Nanocellulose Aerogels

Chemical vapor deposition of a thin titanium dioxide (TiO₂) film on lightweight native nanocellulose aerogels offers a novel type of functional material that shows photoswitching between water‐superabsorbent and water‐repellent states. Cellulose nanofibrils (diameters in the range of 5–20 nm) with native crystalline internal structures are topical due to their attractive mechanical properties, and they have become relevant for applications due to the recent progress in the methods of their preparation. Highly porous, nanocellulose aerogels are here first formed by freeze‐drying from the corresponding aqueous gels. Well‐defined, nearly conformal TiO₂ coatings with thicknesses of about 7 nm are prepared by chemical vapor deposition on the aerogel skeleton. Weighing shows that such TiO₂‐coated aerogel specimens essentially do not absorb water upon immersion, which is also evidenced by a high contact angle for water of 140° on the surface. Upon UV illumination, they absorb water 16 times their own weight and show a vanishing contact angle on the surface, allowing them to be denoted as superabsorbents. Recovery of the original absorption and wetting properties occurs upon storage in the dark. That the cellulose nanofibrils spontaneously aggregate into porous sheets of different length scales during freeze‐drying is relevant: in the water‐repellent state they may stabilize air pockets, as evidenced by a high contact angle, in the superabsorbent state they facilitate rapid water‐spreading into the aerogel cavities by capillary effects. The TiO₂‐coated nanocellulose aerogels also show photo‐oxidative decomposition, i.e., photocatalytic activity, which, in combination with the porous structure, is interesting for applications such as water purification. It is expected that the present dynamic, externally controlled, organic/inorganic aerogels will open technically relevant approaches for various applications.     

Advances in Digital Front-End and Software RF Processing:Part I

One of the biggest technology trends in wirelessbroadband, radar, sonar, and broadcasting systems issoftware radio frequency processing and digitalfront-end. This trend encompasses a broad range oftopics, from circuit design and signal processing to systemintegration. It includes digital up-conversion (DUC) and     

High-precision diode-laser-based temperature measurement for air refractive index compensation

We present a laser-based system to measure the refractive index of air over a long path length. In optical distance measurements, it is essential to know the refractive index of air with high accuracy. Commonly, the refractive index of air is calculated from the properties of the ambient air using either Ciddor or Edlén equations, where the dominant uncertainty component is in most cases the air temperature. The method developed in this work utilizes direct absorption spectroscopy of oxygen to measure the average temperature of air and of water vapor to measure relative humidity. The method allows measurement of temperature and humidity over the same beam path as in optical distance measurement, providing spatially well-matching data. Indoor and outdoor measurements demonstrate the effectiveness of the method. In particular, we demonstrate an effective compensation of the refractive index of air in an interferometric length measurement at a time-variant and spatially nonhomogeneous temperature over a long time period. Further, we were able to demonstrate 7 mK RMS noise over a 67 m path length using a 120 s sample time. To our knowledge, this is the best temperature precision reported for a spectroscopic temperature measurement.     

Dynamical modelling of peak-current-mode-controlled converter in continuous conduction mode

Peak-current-mode (PCM) control has been a popular control method of switched-mode converters since its publication in late 1970s due to the inherent features it provides especially in buck derived converters such as high input-noise attenuation, first-order control dynamics as well as cycle-by-cycle current limiting. Its main disadvantages are considered to be the limited duty ratio, increased output impedance, and noise sensitivity due to the fast feedback-current loop. The observed peculiar dynamical behaviour associate to the PCM control has attracted the researchers for tens of years yielding multitude of dynamical modelling approaches. Application of sampling effect as the basis for the modelling has been considered to producing most accurate dynamical models as well as explanations for the observed phenomena. A consistent and easy-to-apply modelling approach is presented in this paper, which explains the observed dynamical phenomena, provides accurate dynamical power-stage models as well as comply with the other methods proposing the existence of an infinite small-signal duty-ratio gain leading to the observed behaviour. Experimental evidence is provided based on second and fourth-order buck converters.     

The electrical conductivities of poly(3.6-pyridazine) and poly(3.6-pyridazine sulphide)

Summary We have chemically synthesized poly(3.6-pyridazine),(PPd), and poly(3.6-pyridazine sulphide), (PPdS), and studied the electrical conductivities of these polymers.     

Momentum and recoil-flux anisotropies in collision-cascades: Influence on sputtered particle angular distributions

The anisotropy in the spatial distributions of recoil-flux and recoil-momentum have been studied by Monte Carlo simulation for the specific case of amorphous germanium bombarded with Ar⁺ ions. For all the energies investigated, (1.25 to 320 keV) both the recoil-flux and momentum-flux distributions are strongly backwards directed at the surface, becoming forwards directed at greater depths. Further the angular distributions are (relatively) insensitive to the choice of interatomic potential. The calculations show that the backwards-directedness of sputtered particle angular distributions may be completely explained by the anisotropy in the recoil flux. It is also demonstrated that the adoption of more realistic surface models, than the usual infinite target approximation does not lead to significant changes in the angular distribution of recoil-, momentum- and sputtered particle-fluxes.     

MR volumetric analysis of the human entorhinal, perirhinal, and temporopolar cortices

Cell-adhesion molecules (CAMs) are thought to play crucial roles in development and plasticity in the nervous system. This study tested for a role for cell adhesion and in particular, the recognition of two glycosyl epitopes (HNK-1 and oligomannoside) in the activity-driven sharpening of the retinotopic map formed by the regenerating retinal fibers of goldfish. HNK-1 is a prominent glycosyl epitope on many CAMs and extracellular matrix (ECM) molecules, including NCAM, L1, ependymin, and integrins, which have all been implicated in synaptic plasticity. To test for a role of HNK-1 in the sharpening process, we used osmotic minipumps to infuse HNK-1 antibodies for 7-21 days into the tectal ventricle starting at 18 days after optic nerve crush. Retinotopic maps recorded at 76-86 days postcrush showed a lack of sharpening similar to that seen previously with two antibodies to ependymin, an HNK-1-positive ECM component present in cerebrospinal fluid. The multiunit receptive fields at each point averaged 26 degrees versus 11-12 degrees in regenerates infused with control antibodies or Ringer's alone. The HNK-1 epitope also binds to the G2 domain of laminin to mediate neuron-ECM adhesion. To test for a role for laminin, a polyclonal antibody was similarly infused and also prevented sharpening to approximately the same degree. The results support a role for the HNK-1 epitope and laminin in retinotectal sharpening. The oligomannoside epitope (recognized by monoclonal antibody L3) on the CAM L1 interacts with NCAM on the same cell to promote stronger L1 homophilic interactions between cells. Both an L1-like molecule and NCAM are prominently reexpressed in the regenerating retinotectal system of fish. Infusion of oligomannosidic glycopeptides resulted in decreased sharpening, with multiunit receptive fields that averaged 22.7 degrees. Infusions of mannose-poor glycopeptides less prominently disrupted sharpening, with average multiunit receptive fields of 18 degrees. Thus, oligomannosidic glycans in particular may play a role in retinotopic sharpening. Blocking glycan-mediated interactions between CAMs and ECM molecules could decrease the extent of exploratory growth of retinal axon collaterals, preventing them from finding their retinotopic sites, or could interfere with L1 or NCAM and laminin binding at the synaptic densities preventing stabilization of retinotopically appropriate synapses. Together, these results support a prominent role for cell adhesion and glycan epitopes in visual synaptic plasticity.     

Design and implementation of efficient IIR notch filters withquantization error feedback

Straightforward methods for the design of digital notch filters are presented. The design method is based on setting a zero of the filter at a notch frequency and placing a pole in its neighborhood such that the notch width is narrow enough while keeping the group delay of the filter sufficiently flat. A technique for efficient and well-behaved implementation with fixed-point signal processors is advanced, based on the use of quantization error feedback for roundoff noise reduction. The design approach is illustrated with numerical examples, and an assembly-language program for the family of TMS320 signal processors is provided     

Highly compatible wood thermoplastic composites from lignocellulosic material modified in ionic liquids: Preparation and thermal properties

A study of converting chemically modified wood into thermoplastic materials was undertaken to develop a new technology platform for the effective utilization of wood‐based lignocellulosic materials. Highly substituted benzoylated spruce thermomechanical pulp (TMP) and lauroylated spruce TMP were used as components for thermoplastic composites of poly(styrene) and poly(propylene). Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and dynamic mechanical thermal analysis (DMTA) were used to characterize the interfacial morphology and thermal properties of the resultant composite filaments. The coupling of the interfacial morphology effort and that of torque analysis applied during processing indicated that the thorough modification of wood fibers by benzoylation and/or lauroylation reactions can improve the compatibility between the wood‐based lignocellulosic materials and poly(styrene) and poly(propylene). Thermal analysis showed that, with the addition of wood derivatives into poly(styrene) and poly(propylene) matrices, a slight decrease in their T_gs was observed. Furthermore, all of the prepared composites showed improved thermal stability, as revealed by TGA. The resultant thermoplastic wood composites exhibited good melting properties and were readily extruded into filaments or sheets. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009