Simultaneous measurement of the surface temperature and the release of atomic sodium from a burning black liquor droplet

Simultaneous measurement of the concentration of released atomic sodium, swelling, surface and internal temperature of a burning black liquor droplet under a fuel lean and rich condition has been demonstrated. Two-dimensional two-colour optical pyrometry was employed to determine the distribution of surface temperature and swelling of a burning black liquor droplet while planar laser-induced fluorescence (PLIF) was used to assess the temporal release of atomic sodium. The key findings of these studies are: (i) the concentration of atomic sodium released during the drying and devolatilisation stages was found to be correlated with the external surface area; and (ii) the insignificant presence of atomic sodium during the char consumption stage shows that sodium release is suppressed by the lower temperature and by the high CO₂ content in and around the particle.     

Friction and a Tribochemical Reaction between Ice and Hexagonal Boron Nitride: A Theoretical Study

Friction between ice-Ih and hexagonal boron nitride (h-BN) has been determined by periodic ab initio calculations. Surfaces of ice-Ih and h-BN were brought into sliding contact, and the interaction energies were calculated as a function of interplanar distance and lateral displacement of the surfaces. The friction between the surfaces was calculated from the interaction energies, producing a friction coefficient of 0.140. Friction is further influenced at high loads by a tribochemical reaction between ice-Ih and h-BN.     

Characterization of biodegradable core–clad borosilicate glass fibers with round and rectangular cross-section

Here, we report on core–clad bioactive borosilicate fibers, that we have prepared both with round and rectangular cross-section profile. The exposed approach, which relies on the stacking and drawing of glass slabs, demonstrates our ability to develop bioactive-based glass fibers with tailored cross-section profiles. Tens-of-meters-long fibers were successfully drawn, although suffering from elevated losses in the case of the rectangular ones. The response of the fibers in simulated body fluid was studied for both geometries. We found that a round cladding can act as protective layer, tempering effects of the corrosion. We also noticed that rectangular fibers are more prone to degradation, the enhanced corrosion beginning from their sharp corners as they accumulated residual tensile stress during drawing. To the best of our knowledge, this is the first report on the effect of residual tensile stresses from surface tension deformations applied to the corrosion of rectangular fibers. As geometry plays a critical role on the biodegradation behavior of the fiberglass, we believe the enclosed results could lead to the design of fiber devices with tailored cross-section profile in order to tune their rate of degradation on solely based geometrical effects.     

Environmental Control of Triplet Emission in Donor–Bridge–Acceptor Organometallics

Carbene‐metal‐amides (CMAs) are a promising family of donor–bridge–acceptor molecular charge‐transfer (CT) emitters for organic light‐emitting diodes. A universal approach is demonstrated to tune the energy of their CT emission. A blueshift of up to 210 meV is achievable in solid state via dilution in a polar host matrix. The origin of this shift has two components: constraint of thermally‐activated triplet diffusion, and electrostatic interactions between guest and polar host. This allows the emission of mid‐green CMA archetypes to be tuned to sky blue without chemical modifications. Monte‐Carlo simulations based on a Marcus‐type transfer integral successfully reproduce the concentration‐ and temperature‐dependent triplet diffusion process, revealing a substantial shift in the ensemble density of states in polar hosts. In gold‐bridged CMAs, this shift does not lead to a significant change in luminescence lifetime, thermal activation energy, reorganization energy, or intersystem crossing rate. These discoveries offer new insight into coupling between the singlet and triplet manifolds in CMA materials, revealing a dominant interaction between states of CT character. The same approach is employed using materials which have been chemically modified to alter the energy of their CT state directly, shifting the emission of sky‐blue chromophores into the practical blue range.     

A 14b 100-MS/s Time-Interleaved A/D Converter

This article presents a 14-bit, 100-MS/s time-interleaved pipeline ADC, which samples input signal from 210-MHz IF-band. Digital self-calibration is employed to compensate gain mismatch and offset between time-interleaved channels as well as mismatches arise from a single ADC channel. A timing skew-insensitive parallel S/H circuit is utilized in order to avoid timing skew between parallel ADC channels. The ADC, fabricated in a 0.35-μm BiCMOS (SiGe) takes an area of 10.2 mm², reaches an ENOB of 11.4 bits with a 79.9-dB SFDR at 192.5-MHz input and draws 1.4 W from a 3.0-V supply.     

Atomic layer deposition growth of zirconium doped In2O3 films

Zirconium doped indium oxide thin films were deposited by the atomic layer deposition technique at 500 °C using InCl₃, ZrCl₄ and water as precursors. The films were characterised by X-ray diffraction, energy dispersive X-ray analysis and by optical and electrical measurements. The films had polycrystalline In₂O₃ structure. High transparency and resistivity of 3.7×10⁻⁴ Ω cm were obtained.     

Radio frequency technology for automated manufacturing and logistics control. Part 2: RFID antenna utilisation in industrial applications

The trend in industrial automation is to move towards fast and real-time identification, further improving the high-level of accuracy that is needed to enable continuous identification and monitoring. The interest in adopting radio frequency identification (RFID) technology for use in automation systems with minimal manual involvement is increasing rapidly. RFID systems are capable of providing real-time object visibility with high accuracy enabling continuous identification and location of all items and thereby providing accurate real-time data management instead of simple snapshots. In this paper, the use of multiple reader antennas is examined against collision and interference avoidance. Also, antenna operation is studied in typical industrial environments containing metallic objects or other conducting surfaces. In addition, this paper reviews different tag antennas and their characteristics for particular item identification cases. These cases include items made of specific materials that obstruct or prevent radio wave propagation by either absorbing or reflecting them. The results given in this paper are fully applicable with practical RFID solutions.     

Blends of poly(ε‐caprolactone‐b‐lactic acid) and poly(lactic acid) for hot‐melt applications

The condensation reaction product of poly(lactic acid) (PLA) and a hydroxyl‐terminated four‐armed poly(ε‐caprolactone) (PCL) was studied by size‐exclusion chromatography, DSC, and NMR. The use of both L ‐lactic acid (LLA) and rac‐lactic acid (rac‐LA) was studied and the use of two different catalysts, stannous 2‐ethylhexanoate [Sn(Oct)₂] and ferrous acetate [Fe(OAc)₂], was also investigated. The thermal stability and adhesive properties were also measured for the different formulations. The characterization results suggested the formation of a blend of PLA and a block‐copolyester of PLA and PCL. The results further indicated partial miscibility in the amorphous phase of the blend showing only one glass‐transition temperature in most cases, although no randomized structures could be detected in the block‐copolymers. The polymerization in the Fe(OAc)₂‐catalyzed experiments proceeded slower than in the Sn(Oct)₂‐catalyzed experiments. The discoloring of the polymer was minor when Fe(OAc)₂ was used as catalyst, but significant when Sn(Oct)₂ was used. The ferrous catalyst also caused a slower thermal degradation. Differences in the morphology and in the adhesive properties could be related to the stereochemistry of the poly(lactic acid). © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 196–204, 2004     

Guidelines for improving the contextual relevance of field surveys: the case of information security policy violations

The information systems (IS) field continues to debate the relative importance of rigor and relevance in its research. While the pursuit of rigor in research is important, we argue that further effort is needed to improve practical relevance, not only in terms of topics, but also by ensuring contextual relevance. While content validity is often performed rigorously, validated survey instruments may still lack contextual relevance and be out of touch with practice. We argue that IS behavioral research can improve its practical relevance without loss of rigor by carefully addressing a number of contextual issues in instrumentation design. In this opinion article, we outline five guidelines – relating to both rigor and relevance – designed to increase the contextual relevance of field survey research, using case examples from the area of IS security. They are: (1) inform study respondents that a behavior is an ISP violation, (2) measure specific examples of ISP violations, (3) ensure that ISP violations are important ISP problems in practice, (4) ensure the applicability of IS security violations to the organizational context, and (5) consider the appropriate level of specificity and generalizability for instrumentation. We review previous behavioral research on IS security and show that no existing study meets more than three of these five guidelines. By applying these guidelines where applicable, IS scholars can increase the contextual relevance of their instrumentation, yielding results more likely to address important problems in practice.