MobileNAT: A New Technique for Mobility Across Heterogeneous Address Spaces

We propose a new network layer mobility architecture called Mobile NAT to efficiently support micro and macro-mobility in and across heterogeneous address spaces common in emerging public networks. The key ideas in this architecture are as follows: (1) Use of two IP addresses – an invariant virtual IP address for host identification at the application layer and an actual routable address at the network layer that changes due to mobility. Since physical address has routing significance only within a domain, it can be a private address and therefore, does not deplete the public IP address resource. (2) New DHCP enhancements to distribute the two addresses. (3) A new signaling element called Mobility Manager (MM) that uses Middlebox Communication (MIDCOM) framework to signal the changes in packet processing rules to the Network Address Translators (NATs) in the event of node mobility. Our proposal does not require any modifications to the access networks and can seamlessly co-exist with the existing Mobile IP mechanisms and therefore, can be used to provide seamless mobility across heterogeneous wireline and wireless networks. We report implementation details of a subset of our ideas in a testbed with Windows XP clients and Linux based NATs. Milind M. Buddhikot is a Member of Technical Staff in the Center for Networking Research at Lucent Bell Labs, Holmdel, NJ. Milind holds a Doctor of Science (D. Sc.) in computer science (July 1998) from Washington University in St. Louis, and a Master of Technology (M.Tech.) in communication engineering (December 1988) from the Indian Institute of Technology (I.I.T), Bombay. His current research interests are in the areas of systems and protocols for integrated public wireless networks, authentication and dynamic key exchange protocols, Voice-over-IP (VOIP) networks, and sensor and ad-hoc networks. He has authored over 26 research papers and 9 patent submissions in the areas of design of multimedia systems and protocols, layer-4 packet classification, MPLS path routing, authentication and dynamic key exchange, and 802.11/3G integration. Milind currently serves as the Associate Editor of the IEEE/ACM Transactions on Networking. He also served as a co-guest-editor of IEEE Network magazine’s March 2001 Special issue on Fast IP Packet forwarding and Classification for Next Generation Internet Services. He has served in the capacity of a tutorial chair for IEEE LCN 94, 95, as a publicity chair for NOSSDAV97, and as a program committee member for MMCN 2001, 2003, IEEE ICNP2002, 2003 and IEEE LCN 93-2000 conferences. Adiseshu Hari received a Doctorate in Computer Science from Washington University in St. Louis in 1999, and has since been at Bell Labs, Lucent Technologies, where he’s worked on projects related to network design and optimization. He’s currently looking at design issues in large scale SIP based VoIP networks. Kundan N. Singh received a B.E.(Hons) degree in Computer Science from Birla Institute of Technology and Science in India, M.S. in Computer Science from Columbia University, and is continuing his studies towards Ph.D. degree in the same field at Columbia University in New York City. As a research assistant in the Internet Real-Time Lab at Columbia University, he is doing research on Internet telephony, SIP-H.323 signaling gateway, unified messaging systems and multimedia conferencing. Scott Miller is the Director of the High Speed Mobile Data Research department at Bell Labs in Holmdel, New Jersey. He has B.S. and M.S. degrees in electrical engineering from Cooper Union in New York City. His current research involves the integration of 802.11 and 3G wireless data service and the related mobile networking issues concerning seamless mobility, authentication, security, roaming, and accounting. Prior to his work on 802.11/3G integration, Scott has led several systems research efforts in wireless applications, implementing novel systems for wireless messaging, speech-driven directory services, wireless instant messaging, carrier-based content billing, and multi-media content adaptation.This revised version was published online in August 2005 with a corrected cover date.     

Sequencing and Scheduling in Robotic Cells: Recent Developments

A great deal of work has been done to analyze the problem of robot move sequencing and part scheduling in robotic flowshop cells. We examine the recent developments in this literature. A robotic flowshop cell consists of a number of processing stages served by one or more robots. Each stage has one or more machines that perform that stage’s processing. Types of robotic cells are differentiated from one another by certain characteristics, including robot type, robot travel-time, number of robots, types of parts processed, and use of parallel machines within stages. We focus on cyclic production of parts. A cycle is specified by a repeatable sequence of robot moves designed to transfer a set of parts between the machines for their processing.We start by providing a classification scheme for robotic cell scheduling problems that is based on three characteristics: machine environment, processing restrictions, and objective function, and discuss the influence of these characteristics on the methods of analysis employed. In addition to reporting recent results on classical robotic cell scheduling problems, we include results on robotic cells with advanced features such as dual gripper robots, parallel machines, and multiple robots. Next, we examine implementation issues that have been addressed in the practice-oriented literature and detail the optimal policies to use under various combinations of conditions. We conclude by describing some important open problems in the field.     

Post-spinning modification of electrospun nanofiber nanocomposite from Bombyx mori silk and carbon nanotubes

Electrospinning is an effective procedure for fabricating submicron to nanoscale fibers from synthetic polymer as well as natural proteins. We successfully electrospun regenerated silk protein from cocoons of Bombyx mori to produce random as well as aligned fibers with diameter less than 100 nm. The fibers were characterized using field emission environmental scanning electron microscope (ESEM), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy and wide angle X-ray diffraction (WAXD) studies. Post-spinning treatment with methanol and/or stretching and co-electrospinning with single walled carbon nanotubes (CNT) were carried out to alter the strength, toughness, crystallinity and conductivity of silk nanofibers. Addition of just 1% CNT along with post-spinning treatments resulted in 7-fold increase in the strength and 35-fold increase in the modulus of silk nanofibers. Raman spectroscopy confirmed that CNTs were incorporated in the silk fibers. FT-IR spectroscopy and WAXD studies proved that silk-CNT nanofibers had more crystallinity compared to silk nanofibers without CNT. Four-probe method demonstrated that silk-CNT nanofibers had 4 times higher electrical conductivity compared to silk nanofibers without CNT.     

Studies on effect of nanoclay on the properties of thermally sprayable EVA and EVAI coatings

Dispersion of nanoclay (NC) in polymer blend system is governed by the sequence of addition of different ingredients. In the present work nanoclay was added in different sequences to blend composition such as ethylene vinyl acetate (EVA)/low density polyethylene (LDPE) and ethylene vinyl alcohol (EVAl)/LDPE in internal mixer to get nanocomposite. It was found that sequential addition of individual polymers and nanoclay influenced mechanical properties of resulting composites. Blending sequence of PE/NC/EVA and PE/NC/EVAl gave best mechanical properties. After optimization of addition sequence, concentration of nanoclay was varied from 1 to 8% by weight in the polymer blend. The resulting composites were evaluated in terms of their mechanical properties, dispersion characteristics (XRD), water vapor transmission rate (WVTR) and water absorption (Wa). Nanocomposite containing EVA/LDPE blend with 4% nanoclay showed optimum properties. The optimized composition was applied on grit blasted mild steel specimens by flame spray technique. The coated specimens were evaluated for adhesion strength, abrasion resistance and resistance to corrosion properties.     

Bacterial synthesis of copper/copper oxide nanoparticles

A bacterial mediated synthesis of copper/copper oxide nanoparticle composite is reported. A Gram-negative bacterium belonging to the genus Serratia was isolated from the midgut of Stibara sp., an insect of the Cerambycidae family of beetles found in the Northwestern Ghats of India. This is a unique bacterium that is quite specific for the synthesis of copper oxide nanoparticles as several other strains isolated from the same insect and common Indian mosquitoes did not result in nanoparticle formation. By following the reaction systematically, we could delineate that the nanoparticle formation occurs intracellularly. However, the process results in the killing of bacterial cells. Subsequently the nanoparticles leak out as the cell wall disintegrates. The nanoparticles formed are thoroughly characterized by UV-Vis, TEM, XRD, XPS and FTIR studies.     

Effects of nano size mischmetal and its oxide on improving the hydrogen sorption behaviour of MgH2

This paper reports the catalytic effects of mischmetal (Mm) and mischmetal oxide (Mm-oxide) on improving the dehydrogenation and rehydrogenation behaviour of magnesium hydride (MgH₂). It has been found that 5 wt.% is the optimum catalyst (Mm/Mm-oxide) concentration for MgH₂. The Mm and Mm-oxide catalyzed MgH₂ exhibits hydrogen desorption at significantly lower temperature and also fast rehydrogenation kinetics compared to ball-milled MgH₂ under identical conditions of temperature and pressure. The onset desorption temperature for MgH₂ catalyzed with Mm and Mm-oxide are 323 °C and 305 °C, respectively. Whereas the onset desorption temperature for the ball-milled MgH₂ is 381 °C. Thus, there is a lowering of onset desorption temperature by 58 °C for Mm and by 76 °C for Mm-oxide. The dehydrogenation activation energy of Mm-oxide catalyzed MgH₂ is 66 kJ/mol. It is 35 kJ/mol lower than ball-milled MgH₂. Additionally, the Mm-oxide catalyzed dehydrogenated Mg exhibits faster rehydrogenation kinetics. It has been noticed that in the first 10 min, the Mm-oxide catalyzed Mg (dehydrogenated MgH₂) has absorbed up to 4.75 wt.% H₂ at 315 °C under 15 atmosphere hydrogen pressure. The activation energy determined for the rehydrogenation of Mm-oxide catalyzed Mg is ∼62 kJ/mol, whereas that for the ball-milled Mg alone is ∼91 kJ/mol. Thus, there is a decrease in absorption activation energy by ∼29 kJ/mol for the Mm-oxide catalyzed Mg. In addition, Mm-oxide is the native mixture of CeO₂ and La₂O₃ which makes the duo a better catalyst than CeO₂, which is known to be an effective catalyst for MgH₂. This takes place due to the synergistic effect of CeO₂ and La₂O₃. It can thus be said that Mm-oxide is an effective catalyst for improving the hydrogen sorption behaviour of MgH₂.     

Synthesis and characterization of nonlinear optical side-chain polyimides containing the thiadiazole chromophores

Thermally stable second-order nonlinear optical (NLO) polyimides were synthesized using a standard condensation polymerization technique. The polyimides were prepared from 4,4′-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and pyromellitic dianhydride (PMDA) with two aromatic azo- and diazo-diamine derivatives as the NLO chromophores. The resulting polyimides were characterized by FTIR, ¹H-NMR, UV-vis spectroscopies, differential scanning calorimetry, thermogravimetric analysis, and gel permeation chromatography. The weight-average molecular weights of polyimides determined by gel permeation chromatography (GPC) were in the range of 32,100 to 39,300 (M_w/M_n = 1.58–1.74). All the polyimides exhibited an excellent solubility in many of the aprotic polar organic solvents, manifesting that these polyimides offer good processability. The glass transition temperature for the resulting polyimides was in the range of 152 to 194°C and most of them showed high thermal stability. Particularly, the polyimides containing diazo group and PMDA backbone showed an enhanced thermal stability and glass transition temperature. The second harmonic generation (SHG) coefficients (d₃₃) of the poled polyimide films range from 43.71 to 80.49 pm/V at 532 nm. Further, it is noticed that there was no SHG decay below 180°C because of the partial main-chain character of the polyimide structure, which is acceptable for nonlinear optical device applications. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Collective cell guidance by cooperative intercellular forces

Cells comprising a tissue migrate as part of a collective. How collective processes are coordinated over large multi-cellular assemblies has remained unclear, however, because mechanical stresses exerted at cell-cell junctions have not been accessible experimentally. We report here maps of these stresses within and between cells comprising a monolayer. Within the cell sheet there arise unanticipated fluctuations of mechanical stress that are severe, emerge spontaneously, and ripple across the monolayer. Within that stress landscape, local cellular migrations follow local orientations of maximal principal stress. Migrations of both endothelial and epithelial monolayers conform to this behaviour, as do breast cancer cell lines before but not after the epithelial-mesenchymal transition. Collective migration in these diverse systems is seen to be governed by a simple but unifying physiological principle: neighbouring cells join forces to transmit appreciable normal stress across the cell-cell junction, but migrate along orientations of minimal intercellular shear stress.     

Nanocrystalline zinc indium vanadate: a novel photocatalyst for hydrogen generation

Hydrogen is a future fuel and hence production of cheap hydrogen is an important area of research. Recently, the photocatalysts were used to generate hydrogen from water and hydrogen sulfide splitting under solar light. Hence, we designed Zinc Indium Vanadate, a novel visible light active photocatalyst and used for the generation of hydrogen by using solar light. We have demonstrated the synthesis of ZnIn2V2O9 (ZIV) catalyst by sonochemical route using NH4VO3, In (NO3)3 and Zn(CH3COO)2 as a precursors and PVP as a capping agent. The obtained product was further characterized by XRD, UV-DRS and FESEM. The XRD pattern reveals the existence of monoclinic crystal structure and broader peaks indicating the nanocrystalline nature of the material. The particle size was observed in the range of 50-70 nm. The optical study showed the absorption edge cut off at 520 nm with estimated band gap about 2.3 eV. Considering the band gap in visible range, ZnIn2V2O9 was used as a photocatalyst for photodecomposition of H2S under visible light irradiation to produce hydrogen. We observed excellent photocatalytic activity for the hydrogen generation by using this photocatalyst.