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991.
Jeremy Gustin Brian Freeman James Stone Mohammad Mahinfalah Amin Salehi‐Khojin 《应用聚合物科学杂志》2005,96(6):2309-2315
Nanocomposites are more widely studied today because of higher stiffness, decreased permeability, thermal stability, and many other properties superior to those of regular polymers. However, manufacturers are concerned about implementing nanocomposites because of their lower impact properties with respect to the base polymer. This study focused on low‐velocity impact tests of a thermoplastic olefin by itself and with 5 wt % nanoclay. The impact tests were conducted at ?40, 23.9, and 65.6°C until the polymer and nanocomposite plates experienced complete striker penetration. The force–time and force–deflection responses obtained from the impact testing provided a means of comparing the impact performances of the two materials. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 2309–2315, 2005 相似文献
992.
993.
In drug delivery systems that use silicone elastomers as a diffusion matrix for the active drug, it is common to crosslink the material by the hydrosilylation reaction. In this platinum‐catalyzed reaction, vinyl groups on a polymer add to the methyl siloxane hydride (MHS) groups on a low molecular mass crosslinker. With an excess of crosslinker, a fast curing is achieved and a fully crosslinked material is formed. Unreacted MHS groups were shown to remain in the elastomer after curing because of the excess crosslinker. In this work, a simple procedure was developed to eliminate the unreacted MHS groups from the final product. We found that storage of the product at +40°C and 75% relative humidity for a few weeks will effectively destroy the residual MHS groups in the elastomer. The effects of varying levels of humidity, oxygen, and temperature on this postcuring procedure were studied. The amount of MHS groups was measured with NMR and IR spectroscopy. We also found that the hardness of the material increased by approximately 25% as a consequence of this postcuring treatment. This increase is probably due to a secondary crosslinking reaction between MHS and silanol groups. Heat treatment at higher temperatures led to an even further increase in the hardness and compression modulus. Because no MHS groups remained in the elastomer when this heat treatment was started, it is apparent that another secondary crosslinking reaction is occurring, probably silanol condensation. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 2254–2264, 2002 相似文献
994.
The widespread uptake of mobile technologies has witnessed a re‐structuring of the mobile market with major shifts in the predominance of particular firms and the emergence of new business models. These sociotechnical trends are significant in the ways that they are influencing and shaping the working lives of software professionals. Building on prior research investigating the persistent problems and practices of systems development, this paper examines mobile applications development and distribution. A qualitative study of 60 developers based in Sweden, the UK and the USA was analysed around the interrelated problems of diversity, knowledge and structure. The analysis revealed how platform‐based development in an evolving mobile market represents significant changes at the business environment level. These changes ripple through and accentuate ongoing trends and developments, intensifying the persistent problems and challenges facing software developers. 相似文献
995.
996.
System Modularity has positive effects on software maintainability, reusability, and understandability. One factor that can affect system modularity is code tangling due to code clones. Code tangling can have serious cross-cutting effects on the source code and thereby affect maintainability and reusability of the code. In this research we have developed an algorithmic approach to convert code clones to aspects in order to improve modularity and aid maintainability. Firstly, we use an existing code-clone detection tool to identify code clones in a source code. Secondly, we design algorithms to convert the code clones into aspects and do aspect composition with the original source code. Thirdly, we implement a prototype based on the algorithms. Fourthly, we carry out a performance analysis on the aspects composed source code and our analysis shows that the aspect composed code performs as well as the original code and even better in terms of execution times. 相似文献
997.
Jen‐Taut Yeh Chin‐Lai Chen K. S. Huang Y. H. Nien J. L. Chen P. Z. Huang 《应用聚合物科学杂志》2006,101(2):885-891
The purpose of this study was to research the compatibility and application of polyvinylpyrrolidone (PVP)/chitosan blended polymers. The polymers were synthesized at different weight ratios and tested using techniques such as Fourier transform infrared spectroscopy, differential scanning calorimetry, and thermogravimetric analysis to evaluate the compatibility of the blended materials. Incompatibility occurred when the quantity of chitosan exceeded 75%. The addition of PVP was beneficial for the thermal stability of chitosan, but resulted in inferior strength performance. Furthermore, the blended polymers did not show a color‐enhancement effect, but did show elevated water absorption, chlorine resistance, and colorfastness. In addition, the treated fabrics with a higher chitosan ratio in the blended polymer had antimicrobial properties. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 885–891, 2006 相似文献
998.
The clay is treated with a reducing agent and an acid so as to obtain a clay containing various metal components with a variable‐valence state. Then, the clay is coprecipitated with natural rubber (NR) latex to prepare a vulcanized NR/clay composite. The degradation process of the NR/clay composite under hot air condition was studied dynamically by using a Fourier transform infrared spectrometer attaching an in situ sample cell and was also investigated using the TGA method. The test result obtained from the infrared spectrometry indicated that under low decomposition temperature, the decomposition products of the test samples mainly are ethylene, low molecular olefinic hydrocarbon, and carbonyl compounds. As the decomposition temperature rises, the low molecular olefinic hydrocarbon content decreases, the olefine with longer chain is formed, and a lot of alkane decomposition products are formed at the same time. When the content of the metal components with a variable‐valence state in clay such as Cu, Mn, Co, and Fe increases, the oxidation products containing the carbonyl group, the olefinic hydrocarbon, and CO2 in the decomposition product of the test sample also increase. The TGA result clearly shows a shoulder peak that appears by the side of the main peak on the DTG curve of NR/clay composite. With the increase in the content of metal components with variable‐valence state in clay, the initial degradation temperature of the test sample (T0), the degradation peak temperature (Tp1), and the final degradation temperature (Tf1) in first‐stage reaction, as well as the degradation peak temperature (Tp2) and the last final degradation temperature (Tf) in second‐stage reaction of all the test samples more or less shift to the direction of low temperature; besides, the activation energy (E) of the reaction of the test samples more or less decreases. This means that the metal components with variable‐valence state promote the oxidative degradation of the clay–rubber masterbatch. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3809–3815, 2006 相似文献
999.
1000.
化工企业对环境的影响较大,其制造的化工产品严重威胁着人们的健康。近年来,随着化工企业的规模越来越大,其带来的环境污染问题也越来越严峻。就工业喷漆对环境污染的状况和治理措施进行了分析、探究。 相似文献