The sorption behavior of acid dyes onto cetyltrimethylammonium bromide (CTAB)-modified silica as a function of pH in the aqueous medium was studied. Single-and multi-solute sorption equilibria of orange Ⅱ(OR), phenol red (PR) and Eriochrome Black T (EBT) were studied at pH 3, unbuffered water pH and pH 11. Sorption behavior of EBT could not be conducted at pH3 due to its aggregation in acidic medium. All the reaction conditions, experimental protocols and techniques remained the same throughout the sorption process. Sorption isotherms for single-solute system were fitted by the Langmuir model, while Langmuir competitive model (LCM) and the ideal adsorbed solution theory (IAST) coupled with Langmuir model (IAST/Langmuir) were used for the prediction of multisolute competitive sorption. Sorption affinities influenced by the factors like physical interactive forces between the molecules of CTA on silica and sorbate, structural limitations of the dyes based on their geometrical arrangement were investigated. Sorption affinity of OR was found to be higher than that of EBT and PR at all the pH values investigated. Magnitude of the sorption capacities was observed to be higher in acidic medium but lower in alkaline medium. Trends of the sorption affinities in multisolute system were simlar to those in single-solute system but magnitude of the sorption capacities was significantly reduced due to the prevailing competition among the sorbates. 相似文献
This study was aimed to assess the effects of reinforcement nanoparticles content, on the microstructural features, mechanical properties, and corrosion-related properties of Ni-Co-Cr2O3 nanocomposite coatings. Scanning electron microscope (SEM), energy dispersive X-ray spectrometer (EDS), and X-ray diffraction (XRD) analysis were employed in order to evaluate the microstructural features and chemical composition of the nanocomposites. Moreover, the microhardness tester and electrochemical impedance spectra (EIS) tests coupled with potentiodynamic polarization measurements were used to investigate the mechanical and corrosion-related properties, respectively. Results demonstrate that albeit the volume fraction of cobalt in coating, average particle size, Cr2O3 nanoparticle content in coating, and microstructural features are of prime significance in determining the mentioned properties of the nanocomposite coatings, Co content is more important. Actually, Cr2O3 nanoparticles serve as suitable nucleation sites for Co particles deposition throughout the microstructure. Thus, combined actions of Cr2O3 nanoparticles incorporation and their optimal content ensures the nucleation of high population of Co particles, which significantly contributes to the improvement in the properties. The Ni-Co-8.9 wt%Cr2O3 nanocomposite coating exhibits the superior mechanical and corrosion-related properties. 相似文献
Piles are widely applied to substructures of various infrastructural buildings. Soil has a complex nature; thus, a variety of empirical models have been proposed for the prediction of the bearing capacity of piles. The aim of this study is to propose a novel artificial intelligent approach to predict vertical load capacity of driven piles in cohesionless soils using support vector regression (SVR) optimized by genetic algorithm (GA). To the best of our knowledge, no research has been developed the GA-SVR model to predict vertical load capacity of driven piles in different timescales as of yet, and the novelty of this study is to develop a new hybrid intelligent approach in this field. To investigate the efficacy of GA-SVR model, two other models, i.e., SVR and linear regression models, are also used for a comparative study. According to the obtained results, GA-SVR model clearly outperformed the SVR and linear regression models by achieving less root mean square error (RMSE) and higher coefficient of determination (R2). In other words, GA-SVR with RMSE of 0.017 and R2 of 0.980 has higher performance than SVR with RMSE of 0.035 and R2 of 0.912, and linear regression model with RMSE of 0.079 and R2 of 0.625.
Silicon - Silicon (Si) is very effective in the amelioration of heavy metal (HM) stress in different crop plants. This investigation was conducted to assess the protective role of Si in modulating... 相似文献
Advances in cell biology have been dramatic over the past two decades. One phenomenon now well established is that the mechanical loading of cells has a profound influence on their function. This phenomenon is particularly important for bones, because they alter their density and geometry in response to mechanical loading. In an attempt to understand and ultimately control the underlying biological mechanisms of this bone adaptation, researchers are now mechanically probing whole bones, bone cell cultures, and individual cells using a variety of microscale technologies. There is, however, a substantial need for improved technology. The overall goal of this review is to encourage the participation of the microscale engineering community in this new field of research. Specifically, we describe here possible clinical applications, introduce some basic concepts of bone and cell biology, describe the current microscale technology used in this field, and critically review experiment results. This should provide a basis for the entry of interested microscale engineers into this field. 相似文献
Cloud computing is becoming popular technology due to its functional properties and variety of customer-oriented services over the Internet. The design of reliable and high-quality cloud applications requires a strong Quality of Service QoS parameter metric. In a hyperconverged cloud ecosystem environment, building high-reliability cloud applications is a challenging job. The selection of cloud services is based on the QoS parameters that play essential roles in optimizing and improving cloud rankings. The emergence of cloud computing is significantly reshaping the digital ecosystem, and the numerous services offered by cloud service providers are playing a vital role in this transformation. Hyperconverged software-based unified utilities combine storage virtualization, compute virtualization, and network virtualization. The availability of the latter has also raised the demand for QoS. Due to the diversity of services, the respective quality parameters are also in abundance and need a carefully designed mechanism to compare and identify the critical, common, and impactful parameters. It is also necessary to reconsider the market needs in terms of service requirements and the QoS provided by various CSPs. This research provides a machine learning-based mechanism to monitor the QoS in a hyperconverged environment with three core service parameters: service quality, downtime of servers, and outage of cloud services. 相似文献
Aluminophosphate zeolite is an artificial material which shows strange hydrophilicity. We have been investigating the reason by quantum mechanics, and found that the hydrophilicity of this zeolite depended on the local geometric deformation, and speculated that the site-specific hydrophilicity might be explained by differences in the stiffness of the local deformation determined by the location with the pore structure. In order to test these ideas, we construct a reliable force field based on the new MS-Q approach developed by Demiralp, Cagin, and Goddard. Our force field well reproduces the experimental structure of VPI-5. 相似文献