Landslide susceptibility maps using different probabilistic and bivariate statistical models and comparison of their performance at Wadi Itwad Basin,Asir Region,Saudi Arabia

The purpose of the current study is to produce landslide susceptibility maps using different probabilistic and bivariate statistical approaches; namely, frequency ratio (FR), weights-of-evidence (WofE), index-of-entropy (IofE), and Dempster–Shafer (DS) models, at Wadi Itwad, Asir region, in the southwestern part of Saudi Arabia. Landslide locations were identified and mapped from interpretation of high-resolution satellite images, historical records, and extensive field surveys. In total, 326 landslide locations were mapped using ArcGIS and divided into two groups; 75 % and 25 % of landslide locations were used for training and validation of models, respectively. Twelve layers of landslide-related factors were prepared, including altitude, slope degree, slope length, topography wetness index, curvature, slope aspect, distance from lineaments, distance from roads, distance from streams, lithology, rainfall, and normalized difference vegetation index. The relationships between the landslide-related factors and the landslide inventory map were calculated using different statistical models (FR, WofE, IofE, and DS). The model results were verified with landslide locations, which were not used during the model training. In addition, receiver operating characteristic curves were applied, and area under the curve (AUC) was calculated for the different susceptibility maps using the success (training data) and prediction (validation data) rate curves. The results showed that the AUC for success rates are 0.813, 0.815, 0.800, and 0.777, while the prediction rates are 0.95, 0.952, 0.946, and 0.934 for FR, WofE, IofE, and DS models, respectively. Subsequently, landslide susceptibility maps were divided into five susceptibility classes, including very low, low, moderate, high, and very high. Additionally, the percentage of training and validating landslides locations in high and very high landslide susceptibility classes in each map were calculated. The results revealed that the FR, WofE, IofE, and DS models produced reasonable accuracy. The outcomes will be useful for future general planned development activities and environmental protection.     

Studies on mechanical and biodegradability properties of PVA/lignin blend films

The mechanical and biodegradation properties of polyvinyl alcohol/lignin blended films have been studied. The biodegradable composite films were developed by mechanical mixing followed by film casting method using poly (vinyl alcohol) (PVA), with lignin in different compositions. The progress of biodegradation was evidenced by means of the soil burial test. There was also an evaluation of the weight loss of the samples at the end of the biodegradation process. Blending the PVA with lignin improves tensile strength and the modulus of elasticity and causes a slight decrease in the elongation at break. The best tensile mechanical properties of a PVA/lignin blend were at ratio 2:30 where the tensile strength was 38 MPa, elastic modulus 83.22 MPa and elongation at break 213.9%. Blends of various PVA/lignin ratios have shown transparency, flexibility and good mechanical properties. Film composites also showed good biodegradability. The addition of lignin to the PVA matrix increases the degradation rate of the blends. The weight loss is affected by the composition of the blend, and by the nature of the microorganisms in the soil. PVA/lignin film may be potentially suitable as eco-friendly packaging materials.     

Experimental analysis of the influence of the voltage waveform on ozone generation efficiency

Although the dielectric barrier discharge (DBD) has been widely considered and studied for ozone generation, only a few studies have examined the influence of the alternating voltage waveform on the ozone rate production. This paper analyses the influence of the voltage shape on the ozone concentration and the energy efficiency of a DBD cylindrical ozone generator. Three voltage signals were studied using a high-voltage amplifier: sinusoidal, triangular and rectangular signals with voltage values up to 8 kV and frequencies up to 1.1 kHz. The obtained results showed that the efficiency of the ozone generator depends strongly on the type of the voltage waveform. The maximum values of the energy efficiency and the ozone concentration were obtained with the triangular voltage signal. This wave shape configuration has been successfully used for discolouration of water contaminated by textile dye.     

Degradation of bromoxynil and trifluralin in natural water by direct photolysis and UV plus H2O2 advanced oxidation process

The degradation of two pesticides, bromoxynil and trifluralin, was investigated in ultrapure and natural water solutions under ultraviolet (UV) light and a combination of UV and hydrogen peroxide (H₂O₂). The effect of pH on the photooxidation of the pesticides was also studied. The results indicated that under direct photolysis with monochromatic light at 253.7 nm and different conditions, the photochemical rates followed first-order kinetics, with fluence-based rate constants ranging from 9.15 × 10⁻⁴ to 6.37 × 10⁻³ cm² mJ⁻¹ and 7.63 × 10⁻³ to 1.47 × 10⁻² cm² mJ⁻¹ for bromoxynil and trifluralin, respectively. Quantum yields, in the range of 0.08-0.25 for bromoxynil and 0.12-0.72 for trifluralin, were observed in experiments using ultrapure water. The study also found that the UV/H₂O₂ process enhanced the oxidation rate in comparison to direct photolysis. A 90% degradation with UV dose of 333 and 188 mJ cm⁻² was achieved for bromoxynil and trifluralin, respectively, in natural water, in presence of 8.8 × 10⁻⁴ M H₂O₂. To assess the aquatic toxicity, the Microtox^® 81.9% screening test protocol was used before and after treatment. The test results indicated a decrease in the acute toxicity of the samples after treatment for both pesticides.     

The economic utilisation of sulphonation process residues in the petroleum industry

Sulphonation process residues in the petroleum industry are not exploited in line with their scientific or economic potential. The traditional routes for disposal of these residues can contribute to pollution, whereas various chemical techniques can be used to produce valuable products with domestic and industrial applications. The present work deals with the utilisation of sulphonation process residues. It is found that economic utilisation of sulphonation process residues from the petroleum industry involves the following:

• 1 A comparative evaluation of the performance of the products obtained with other available products demonstrated their efficiency and value.
• 2 Production of highly paraffinic oils with low aromatic content, with potential for use as spray oils, and the utilisation of their residues in the preparation of oil‐soluble neutral and overbased calcium sulphonates, to be used as detergentdispersant additives for crankcase lubricating oils.
• 3 Regeneration of used lubricating oils and use of their residues in the preparation of water‐soluble sodium sulphonates for use as surfactants.
• 4 Reducing the aromatic and sulphur content of kerosene for eventual employment as a carrier solvent for household in secticide.

     

Confinement effect of stiffened and unstiffened concrete-filled stainless steel tubular stub columns

This paper presents a comparative study between stiffened and unstiffened concrete-filled stainless steel hollow tubular stub columns using the austenitic stainless steel grade EN 1.4301 (304). Finite element analysis of concrete-filled stainless steel unstiffened tubular stub columns is constructed herein based on the confined concrete model recently available in the literature. It is then compared with the experimental results of concrete-filled stainless steel stiffened tubular stub columns. The stiffened stainless steel tubular sections were fabricated by welding four lipped angles or two lipped channels at the lips. The longitudinal stiffener of the column plate was formed to avoid shrinkage of the concrete and to act as a continuous connector between the concrete core and the stainless steel tube. The behavior of the columns was investigated using two different nominal concrete cubic strengths of 30 and 60 MPa. The overall depth-to-width ratios (aspect ratio) varied from 1.0 to 1.8. The depth-to-plate thickness ratio of the tube sections varied from 60 to 90. The stiffened and unstiffened concrete-filled stainless steel tube specimens were subjected to uniform axial compression over the concrete and stainless steel tube to force the entire section to undergo the same deformations by blocking action. The ABAQUS 6.6 program, as a finite element package, is used in the current work. The results of the comparative study showed that the stainless steel tubes in stiffened concrete-filled columns offered a high average of increase in the confinement of the concrete core than that of the unstiffened concrete-filled columns.     

A comparison between CFD and Network models for predicting wind-driven ventilation in buildings

The aim of this paper is to compare the implementation of computational fluid dynamics (CFD) and Network models for airflow rate estimation in buildings. The CFD software used is Fluent 5.5. Comparison between the predicted and simulated airflow rate is suggested as a validation method of the implemented CFD code, while the common practice is to compare CFD outputs to wind tunnel or full-scale measurements. This could be useful for studies that have no access to laboratory or full-scale testing facilities. Results obtained from testing a number of cases have been compared and analysed, considering normal and oblique wind directions. The comparison held between mathematical and CFD results generally showed a good agreement, which seems to justify the use of CFD code for predicting natural ventilation in buildings.     

Study on transient heat transfer through multilayer thermal insulation: Numerical analysis and experimental investigation

This paper reports on a numerical and experimental study of heat transfer phenomena through two different multilayer fibrous insulations for building applications. The investigated samples were composed of different layers of fibrous materials and aluminium foils, placed between one or two air gaps in the vertical dimension. An experimental apparatus (a guarded hot box) has been used to measure heat transfer through the samples, while a finite volume numerical model combined radiation/conduction heat transfer was developed to predict the temperature distribution and heat transfer in such insulation systems comprised of the materials separated by multiple reflective foils. The model takes into account the coupling between the solid conduction of the fibrous system and the gaseous conduction and radiation. The radiation heat transfer through the insulation system has been modelled via the two flux approximation. The numerical results were compared with the experimental data from the guarded hot box for model validation, as well as to assess the effectiveness of the reflective foils in changing the resistance of the insulations. The comparative verification of the model showed that the numerical results were consistent with the experimental data through the environmental conditions under examination.     

Process modeling and analysis of palm oil mill effluent treatment in an up-flow anaerobic sludge fixed film bioreactor using response surface methodology (RSM)

In this study, the interactive effects of feed flow rate (QF) and up-flow velocity (V up) on the performance of an up-flow anaerobic sludge fixed film (UASFF) reactor treating palm oil mill effluent (POME) were investigated. Long-term performance of the UASFF reactor was first examined with raw POME at a hydraulic loading rate (HRT) of 3 d and an influent COD concentration of 44300 mg/l. Extreme reactor instability was observed after 25 d. Raw POME was then chemically pretreated and used as feed. Anaerobic digestion of pretreated POME was modeled and analyzed with two operating variables, i.e. feed flow rate and up-flow velocity. Experiments were conducted based on a central composite face-centered design (CCFD) and analyzed using response surface methodology (RSM). The region of exploration for digestion of the pretreated POME was taken as the area enclosed by the feed flow rate (1.01, 7.63 l/d) and up-flow velocity (0.2, 3 m/h) boundaries. Twelve dependent parameters were either directly measured or calculated as response. These parameters were total COD (TCOD) removal, soluble COD (SCOD) removal, effluent pH, effluent total volatile fatty acid (TVFA), effluent bicarbonate alkalinity (BA), effluent total suspended solids (TSS), CH4 percentage in biogas, methane yield (Y M), specific methanogenic activity (SMA), food-to-sludge ratio (F/M), sludge height in the UASB portion and solid retention time (SRT). The optimum conditions for POME treatment were found to be 2.45 l/d and 0.75 m/h for QF and V up, respectively (corresponding to HRT of 1.5 d and recycle ratio of 23.4:1). The present study provides valuable information about interrelations of quality and process parameters at different values of the operating variables.