A study on melt recycling of bio-based polypropylene/thermoplastic starch compound

The compulsion to use bioplastics has increased significantly today. One of the important aspects of plastics is their recyclability. Therefore, the important question of this research is that although bio-based compounds containing starch are sensitive to thermal-mechanical recycling processes, are such products thermally recyclable? To answer the question, polypropylene (PP)/thermoplastic starch (TPS) compound granules were extruded up to five times, and in the other part, single-extruded granules were blended at different ratios with virgin granules by extrusion. In order to characterize these samples, Fourier transform infrared spectroscopy, thermogravimetric analysis, differential scanning calorimetry, rotational disc rheometry, tensile properties, and appearance evaluation were used. The results showed that it is possible to recycle PP/TPS granules up to four times repetition of the extrusion operation and the fifth repetition also showed slight changes. There was also a blend of single-extruded granules with virgin material up to a 50:50% composition without significant variation.     

Chemical,thermal, and mechanical properties and ultraviolet transmittance of novel nano-hydroxyapatite/polyethylene terephthalate milk bottles

Polyethylene terephthalate (PET)/nano-hydroxyapatite (nHAp) composite granules were obtained using twin-screw extruder. Preforms were prepared by injection molding and then PET/nHAp bottles were produced by blow molding. For PET bottles with nHAp, the migration amounts of carboxylic acid (COOH), acetaldehyde (AA), diethylene glycol (DEG), and isophthalic acid (IPA); glass transition temperature (T_g); melting temperature (T_m); and the maximum crystallization temperature (T_cry) were measured. The load-carrying capacity, burst strength, stress cracking, and regional material distribution tests were carried out on the bottles. X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, differential scanning calorimetry, and ultraviolet transmittance analyses were conducted to explain the changes in mechanical, chemical, physical properties, and light transmission of bottles. It was found out that the COOH amount increased and the AA content decreased with increasing nHAp amount. On the other hand, no change was observed in the amounts of DEG and IPA. Although the mechanical properties such as load-carrying capacity and burst strength of the bottles have improved, it has been determined that the standard environmental stress crack resistance test procedure cannot be applied to such a composite. Experimental findings indicate that nHAp disrupts the chemical structure of PET and it isolates harmful chemicals such as AA by forming intermolecular bonds. Moreover, with the addition of up to 0.8% nHAp, PET bottles block the light transmission approximately 80% within 400–700 nm wave length zone. The study demonstrates that the PET/nHAp composite bottles can be used in the food industry, particularly in the packaging of milk and milk products which are vulnerable to light exposure.     

Preparation and characterization of poly(vinyl alcohol)/gum tragacanth/cellulose nanocomposite film

The effects of gum tragacanth obtained from two species of Astragalus Gossypinus (GT-G) and A. Parrowianus (GT-P) at two levels of 10% and 30% combined with cellulose nanofibers (CNF; 5%) on the physico-mechanical and structural properties of polyvinyl alcohol (PVA) nanocomposite film were investigated in this study. The water solubility and water vapor permeability of the films decreased with increasing the content of both gums, especially in the film containing 30% GT-P. The highest values of the tensile strength (39.3 MPa) and elongation at break (445%) belonged to the treatment containing 10% GT-P (90/10P/0). The FTIR and DSC analyses confirmed good interactions between GT and PVA in the 90/10P/0 treatment. SEM images indicated the dense structure of this film as the optimum treatment. Although the presence of CNF in the films containing GT-G improved some properties, especially the Young modulus, it impaired all the functional properties of nanocomposite GT-P film.     

Receptance coupling for end mills

Identification of chatter free cutting conditions, the chatter stability lobes, requires a measurement of the frequency response function (FRF) of each tool mounted on the spindle. This paper presents a method of assembling known dynamics of the spindle–tool holder with an analytically modeled end mill using the receptance coupling technique. The classical receptance technique is enhanced by proposing a method of identifying the end mill–spindle/tool holder joint dynamics, which include both translational and rotational degrees of freedom. The method requires measurement of FRFs with impact tests applied on the spindle–tool holder assembly and blank calibration cylinders attached to the spindle. The spindle and tool holder characteristics are completely identified from the two experiments, and used for the mathematical prediction of FRF for end mills with arbitrary dimensions. The proposed method is experimentally proven and verified in cutting tests.     

Oxidation and sulfidation behavior of Fe-20Cr-16Ni-4Al-1Y2O3 oxide-dispersion-strengthened alloy

High-temperature oxidation and sulfidation studies were conducted on an oxide-dispersion-strengthened alloy of composition Fe-20Cr-16Ni-4Al-1Y₂O₃. The oxidation studies were conducted in air and low-PO₂ environments over a temperature range of 650–1200°C. Results are also reported on the sulfidation resistance of preformed oxide scales and the influence of reoxidation of preformed sulfide scales. Detailed microstructural results and x-ray diffraction analysis data are presented to substantiate the corrosion behavior of the alloy over the wide range of conditions anticipated in fossil-energy systems. Data are also presented on the corrosion behavior of the alloy in oxygen/sulfur mixed gas atmospheres, and the results are used to compare the corrosion behavior of the present alloy with other chromia- and alumina-forming alloys.     

A GMM/HMM model for reconstruction of missing speech spectral components for continuous speech recognition

This paper presents a method for reconstructing unreliable spectral components of speech signals using the statistical distributions of the clean components. Our goal is to model the temporal patterns in speech signal and take advantage of correlations between speech features in both time and frequency domain simultaneously. In this approach, a hidden Markov model (HMM) is first trained on clean speech data to model the temporal patterns which appear in the sequences of the spectral components. Using this model and according to the probabilities of occurring noisy spectral component at each states, a probability distributions for noisy components are estimated. Then, by applying maximum a posteriori (MAP) estimation on the mentioned distributions, the final estimations of the unreliable spectral components are obtained. The proposed method is compared to a common missing feature method which is based on the probabilistic clustering of the feature vectors and also to a state of the art method based on sparse reconstruction. The experimental results exhibits significant improvement in recognition accuracy over a noise polluted Persian corpus.     

Adaptive image denoising using cuckoo algorithm

This paper presents a novel denoising approach based on smoothing linear and nonlinear filters combined with an optimization algorithm. The optimization algorithm used was cuckoo search algorithm and is employed to determine the optimal sequence of filters for each kind of noise. Noises that would be eliminated form images using the proposed approach including Gaussian, speckle, and salt and pepper noise. The denoising behaviour of nonlinear filters and wavelet shrinkage threshold methods have also been analysed and compared with the proposed approach. Results show the robustness of the proposed filter when compared with the state-of-the-art methods in terms of peak signal-to-noise ratio and image quality index. Furthermore, a comparative analysis is provided between the said optimization algorithm and the genetic algorithm.