Zur Chlorierung von N-Aryl-2,4-dimethyl-buta-1,3-dien-1,4-sultamen

About Chlorination of N-Aryl-2,4-dimethyl-buta-1,3-dien-1,4-sultames The sultames of structure 1 are easily chlorinated by sulfurylchloride, chlorine or tertbutylhypochlorite. The structure of the mono-( 2a-c,3a, d ), di-( 4a-d ), tri- ( 5c, d ) and pentachlorosultames ( 6a, b ) is determined by ¹³C-n.m.r. spectroscopy. Contrary to the bromination the chlorination (by SO₂Cl₂) starts with the substitution of the sultamring (formation of mono- and di-chlorosultames) followed of the substitution of the (C-4)-CH₃- group (formation of trichlorosultames). By 1,4-addition of an other molecule of chlorine to 5 the pentachlorosultames 6a, b are obtained. Already by recrystalisation of 6a, b in an alcohol the chlorine in 4-position is exchanged by the corresponding alkoxy group (CH₃O, C₂H₅O, n-C₃H₇O) and the compounds 7-9 are formed.     

Physicochemical,mineralogy,and thermo-kinetic characterisation of newly discovered Nigerian coals under pyrolysis and combustion conditions

In this study,the physicochemical,microstructural,mineralogical,thermal,and kinetic properties of three newly discovered coals from Akunza (AKZ),Ome (OME),and S...     

A maximum power point tracking for photovoltaic-SPE system using a maximum current controller

Processes to produce hydrogen from solar photovoltaic (PV)-powered water electrolysis using solid polymer electrolysis (SPE) are reported. An alternative control of maximum power point tracking (MPPT) in the PV-SPE system based on the maximum current searching methods has been designed and implemented.Based on the characteristics of voltage–current and theoretical analysis of SPE, it can be shown that the tracking of the maximum current output of DC–DC converter in SPE side will track the MPPT of photovoltaic panel simultaneously.This method uses a proportional integrator controller to control the duty factor of DC–DC converter with pulse-width modulator (PWM).The MPPT performance and hydrogen production performance of this method have been evaluated and discussed based on the results of the experiment.     

Transmission of medical messages of patient using control signal of cellular network

The healthcare system needs to track and monitor patients’ status and information. One of the most important requirements is that the patient is able to access the service anywhere at any time. Systems are being developed using the Internet to monitor patients’ status, and in some areas, especially rural areas and motorways, the Internet may not be available, even though the mobile network is available. In some cases, the network might be overloaded, so the patient information cannot be delivered to the hospital or medical centre. We propose a new method that uses the spare extension of the random access channel (RACH), which is carried by physical random access channel (PRACH) to send the patient information to the medical centre. We present the mathematical model of the channel and compare the results with another system from 3GPP to evaluate the results. The results show that the proposed method needs less time to transmit the patient’s information.     

Performance Analysis and Optimization Based on Adaptive Modulation and Chaotic Interleaving for Helicopter-Satellite Communications

Overcoming periodic blockage of the received signal and the carrier frequency fluctuations caused by rotor blades and Doppler shift, respectively, are considered the most challenging issues in helicopter-satellite communication systems. In this study, we propose an automatic frequency control method based on an adaptive modulation scheme. We employ a hybrid modulation not only depending on quadrature phase shift keying, but also based on binary phase shift keying for accurate cancellation of periodic blockage. On the other hand, we apply a chaotic interleaving scheme with a hybrid modulation scheme in order to achieve a better Bit Error Rate (BER) performance in LOS and NLOS environments. Finally, we validate the mathematical analysis of the proposed scheme through simulations. We evaluated the performance of the proposed scheme and performed a comparison with conventional schemes. Our results show that the proposed scheme is significantly capable of reducing the acquisition time and working with various velocities of helicopter blades in addition to providing a better BER performance in shadow fading environments.     

WSANFlow: An Interface Protocol Between SDN Controller and End Devices for SDN-Oriented WSAN

When dealing with a Wireless Sensor and Actuator Network (WSAN) structure, one of the challenging problems is lack of flexibility in such network operations as establishment, management, and configuration. Software-defined Networking (SDN) is a promising technology for a simpler, more flexible, and less overworked network structure. Integration of SDN as a solution into the existing WSAN structures seems to be a strong candidate of deployment solutions for next generation WSAN systems. In order to get enhanced performance results for WSAN systems, we proposed an interface protocol, referred to as WSANFlow, which is responsible for all the communications between SDN controller (SDNC) and SDN-oriented end devices. The SDNC in this approach has the network intelligence and is capable of handling all the control and management operations related to the network. Thus, advanced communication operations can be managed and efficiently optimized efficiently by the SDN controller and then, subsequently, corresponding instructions can be delivered to end devices using the proposed WSANFlow protocol. In the study, we analyzed the proposed framework performance, in terms of power consumption ratio, throughput, and end to end delay metrics. Then, we compared the results with those of a ZigBee-based counterpart for different workloads such as; light, heavy and heavier load which modelizes a video stream of mild parameters. The results show that not only has the overall performance of the existing WSAN system been enhanced, but also control and management operations have been simplified by the proposed model.     

Low-Complexity Equalization for SC-FDMA Uplink Systems Over Time and Frequency Selective Channels

Wireless Personal Communications - In this paper, we propose novel equalization schemes for compensating the adverse effects caused by carrier frequency offsets (CFOs), timing errors and doubly...     

An Evaluation of Routing Protocols for Vehicular Ad-Hoc Network Considering the Video Stream

Wireless Personal Communications - In promising application field such as Vehicular Ad hoc Networks, the ability of the driver to exchange video streams smoothly over the network regardless of his...     

Supporting inheritance hierarchy changes in model-based regression test selection

Software and Systems Modeling - Models can be used to ease and manage the development, evolution, and runtime adaptation of a software system. When models are adapted, the resulting models must be...     

The effect of traffic data source on deterioration rates of heavy-duty flexible pavements

The purpose of this study is to assess the effect of traffic data source (estimated vs. actual) on predicted progression rates of roughness and rutting for heavy-duty flexible pavements of rural freeways. Progression rates are predicted using calibrated HDM-4 models. The assessment is performed in terms of variations in maintenance intervention timing associated with the variations in progression rates. Time series pavement condition data (covering 3–5 years) have been collected for 7 sections of rural freeways for use in calibrating HDM-4 deterioration models. They range in length from 10 to 60.8 km and cover different traffic volumes, climate zones and subgrade soil types. For these sections, estimated annual average daily traffic (AADT), growth factors and assumed loading have been extracted from relevant database. Only six segments of these sections have Weigh-in-Motion (WIM) sites so relevant actual AADT, growth factors and axle load distributions have been extracted from WIM reports. The results of running the calibrated HDM-4 deterioration models using different traffic data show that actual traffic data from WIM sites result in higher rates of deterioration to that of estimated data for four sites, resulting in earlier intervention timing and higher present value agency cost. The other two sites have lower rates with actual data due to lower traffic loading than estimated.